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Chemistry – A European Journal, ISSN 0947-6539, 11/2018, Volume 24, Issue 62, p. n/a
The introduction of electron‐withdrawing pentafluoroethyl groups into organosilicon, organogermanium and organotin compounds by the treatment of organo‐element... 
tin | silicon | germanium | electron-deficient compounds | pentafluoroethyl | fluorine | Silicon
Journal Article
Journal of Applied Polymer Science, ISSN 0021-8995, 11/2018, Volume 135, Issue 42, pp. 46765 - n/a
Journal Article
European Journal of Inorganic Chemistry, ISSN 1434-1948, 09/2019, Volume 2019, Issue 35, pp. 3904 - 3912
Electron‐withdrawing substituents R in complexes [Ln M(PR2)] influence the P–M bond length due to a decreased σ‐donation and enhanced π‐back‐bonding, leading... 
Fluorinated ligands | Palladium | Synthesis design | Bridging ligands | Structure elucidation | Phosphides | Catalysis | Coordination compounds | Crystallography | Electrons | Design optimization
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 10/2019, Volume 58, Issue 41, pp. 14633 - 14638
The reaction of a strongly basic phosphazene (Schwesinger base) with water afforded the corresponding metastable hydroxide trihydrate [OH(OH2)3]− salt. This is... 
phosphazene base | trifluoromethylation | hydroxide hydrate | weakly coordinating cations | Ruppert–Prakash reagent | Anion exchange | Anions | Salts | Vacuum | Fluoroform | Sodium | Reagents | Anion exchanging | Cations | Phosphazene | Sodium hydroxide | Communications | Communication
Journal Article
European Journal of Inorganic Chemistry, ISSN 1434-1948, 02/2018, Volume 2018, Issue 7, pp. 861 - 866
The reaction of the industrial product (C2F5)3PF2 with LiAlH4 in THF solution selectively furnished the hydridophosphate anion [P(C2F5)3F2H]–. The compound... 
Ionic liquids | Anions | Hydridophosphates | Fluorine | Hydride abstraction | PROTON SPONGE | COMPLEXES | WEAKLY COORDINATING ANIONS | HYDROLYSIS | ELECTROLYTES | CHEMISTRY, INORGANIC & NUCLEAR | ABSTRACTION | HEXAFLUOROPHOSPHATE | TEMPERATURE | TRIMETHYLAMINE | Amines | Metathesis | Ions | Cations | Lithium aluminum hydrides | Melting points
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 11/2018, Volume 24, Issue 62, pp. 16457 - 16471
In this contribution we present an account on pentafluoroethylated compounds of silicon, germanium and tin. The pronounced electron‐withdrawing effect of the... 
tin | silicon | germanium | electron-deficient compounds | pentafluoroethyl | fluorine | ORGANIC-SYNTHESIS | ANION | KEY INTERMEDIATE | COMPLEXES | CHEMISTRY, MULTIDISCIPLINARY | LIGAND-EXCHANGE REACTION | METAL ALKYLS | SPECTROSCOPIC CHARACTERIZATION | CHEMISTRY | DERIVATIVES | Hydrogen | Silicon
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 12/2019
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 06/2019, Volume 58, Issue 26, pp. 8938 - 8942
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 06/2019, Volume 58, Issue 26, p. 8938
Weakly coordinating anions (WCAs) are important for academic reasons as well as for technical applications. Tetrakis(pentafluoroethyl)gallate,... 
Hydrochloric acid | Pyrolysis | Hydroxides | Chemical tests and reagents | Nuclear magnetic resonance spectroscopy | Fluorides | Carbonates | Batteries | Mass spectrometry | Lithium compounds
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 03/2018, Volume 24, Issue 17, pp. 4336 - 4342
The tin–tin bond cleavage of hexaorganodistannanes by nucleophiles is a long‐known reaction and widely used for stannate formation or stannyl group transfer.... 
isolobal relationship | pseudohalides | NMR spectroscopy | distannanes | tristannates | Tin | Nuclear magnetic resonance--NMR | Nucleophiles | Iodine | Adducts | Low temperature
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 05/2018, Volume 24, Issue 27, pp. 6975 - 6982
Acetonitrile is deprotonated by a combination of the strong Lewis acid (C2F5)3PF2 and triethylamine. The resulting cyanomethyl function is bound to the... 
Lewis acids | nitriles | gas separation | hydroamination | phosphorus | Phosphates | Amines | Acetonitrile | Lewis acid | Silver | Gas separation | Salts | Metathesis | Triethylamine | Phosphorus | Copper
Journal Article
European Journal of Inorganic Chemistry, ISSN 1434-1948, 08/2019, Volume 2019, Issue 30, p. 3431
Invited for the cover of this issue is the group of Berthold Hoge from Universitat Bielefeld, Germany. The cover image shows a Gallic village besieged by Roman... 
Gallium compounds
Journal Article
Journal of Applied Polymer Science, ISSN 0021-8995, 01/2020, Volume 137, Issue 3, pp. 48235 - n/a
Journal Article
European Journal of Inorganic Chemistry, ISSN 1434-1948, 09/2019, Volume 2019, Issue 35, p. 3904
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 06/2017, Volume 23, Issue 34, pp. 8295 - 8303
For (pentafluoroethyl)phenylstannanes, (C2F5)4−n SnPhn (n=1–3), and dimethylbis(pentafluoroethyl)stannane, (C2F5)2SnMe2, a high yield synthesis was developed... 
stannanes | halogens | perfluoroalkyl | pentafluoroethyl | fluorine | Spectroscopy | Infrared spectroscopy | Correlation | Hydrogen | X-ray diffraction | Mass spectroscopy | Derivatives | Single crystals | Diffraction | Synthesis | Sodium | Halides | Chlorides | Tin | Coupling | Mass spectrometry | Hydrogen bromide
Journal Article
European Journal of Inorganic Chemistry, ISSN 1434-1948, 08/2019, Volume 2019, Issue 30, p. 3462
The reaction of [GaCl.sub.3(OEt.sub.2).sub.n] with LiC.sub.2F.sub.5 surprisingly leads to the formation of the anion [Ga(C.sub.2F.sub.5).sub.3Cl].sup.-. The... 
Nuclear magnetic resonance spectroscopy | Gallium compounds
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 02/2018, Volume 24, Issue 8, pp. 1740 - 1740
Gas‐free generation of pentafluoroethyllithium: Perfluoroalkylation reactions are often characterized by the tedious handling of gases which lead to the... 
lithium | gas-free | perfluoroalkylation | tin–lithium exchange | fluorine | Byproducts | Tin | Gases | Reagents
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 11/2016, Volume 22, Issue 46, pp. 16460 - 16466
This paper gives an account on hypervalent fluoro‐ and chloro(pentafluoroethyl)germanium compounds. The selective synthesis of the... 
Lewis acids | fluoride ion affinity | germanate | pentafluoroethyl | fluorine | Fluorides | Lewis acid | Salts | Fluoride | Quantum chemistry | Mathematical analysis | Germanium | Germanium compounds | Structural analysis
Journal Article
European Journal of Inorganic Chemistry, ISSN 1434-1948, 08/2019, Volume 2019, Issue 30, pp. 3431 - 3431
Invited for the cover of this issue is the group of Berthold Hoge from Universität Bielefeld, Germany. The cover image shows a Gallic village besieged by Roman... 
CHEMISTRY, INORGANIC & NUCLEAR | Layouts | Gallium
Journal Article
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