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Journal of the American Chemical Society, ISSN 0002-7863, 1900, Volume 137, Issue 23, pp. 7298 - 7301
A highly Lewis acidic diphosphonium dication [(C10H6)­(Ph2P)2]2+ (1), in combination with a Lewis basic phosphine, acts as a purely phosphorus-based frustrated... 
HYDROGEN | ACTIVATION | DIHYDROGEN | TRIS(PENTAFLUOROPHENYL)BORANE | HYDROSILYLATION | COMPOUND | COORDINATION-COMPLEXES | CLEAVAGE | SALTS | CHEMISTRY, MULTIDISCIPLINARY | CATIONS
Journal Article
Chemical Communications: Chem Comm, ISSN 1359-7345, 08/2014, Volume 50, Issue 70, pp. 10038 - 10040
Protocols for the FLP-mediated transformation of ethers are presented. Distinct reaction pathways involving either C-O or C-H bond activation occur depending... 
Lewis acid | Chemical bonds | Activation | Transformations | Pathways | Ethers
Journal Article
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, ISSN 1433-7851, 06/2014, Volume 53, Issue 25, pp. 6538 - 6541
The dicationic imidazolium-phosphonium salt [(SIMes) PFPh2][B(C6F5)(4)](2) has been prepared and shown to exhibit remarkable Lewis acidity in stoichiometric... 
CATALYSIS | ACTIVATION | hydrodefluorination | phosphonium salts | carbene ligands | COMPLEXES | Lewis acids | REACTIVITY | FRAGMENTATION | CHEMISTRY, MULTIDISCIPLINARY | CARBENES | BONDS | hydrosilylation | CARBONYL | B(C6F5)-CATALYZED HYDROSILYLATION
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 06/2015, Volume 137, Issue 23, p. 7298
Journal Article
Chemical Science, ISSN 2041-6520, 03/2015, Volume 6, Issue 3, pp. 2016 - 2021
Stepwise oxidation of 1,8-bis(diphenylphosphino)naphthalene and a series of (oligo) methylene-linked diphosphines with XeF2 followed by fluoride abstraction... 
CARBONYL DIFLUORIDE | PHOSPHONIUM SALTS | 1,8-BIS(DIPHENYLPHOSPHINO)NAPHTHALENE | PHOSPHINE | HYDROGENATION | NMR-SPECTRA | MOLECULAR-STRUCTURES | CO2 | BOND ACTIVATION | CHEMISTRY, MULTIDISCIPLINARY | CATIONS | Lewis acid | Proximity | Catalysts | Transformations | Oxidation | Fluorides | Catalysis | Phosphines
Journal Article
Dalton Transactions, ISSN 1477-9226, 03/2016, Volume 45, Issue 14, pp. 5949 - 5957
Using commercially available 2-pyridyldiphenylphosphine (o-NC sub(5)H sub(4))PPh sub(2), a family of electrophilic phosphonium cations [(o-NC sub(5)H... 
Lewis acid | Catalysts | Cations | Catalytic activity | Hydrosilylation | Catalysis | Dimerization
Journal Article
ISSN 1359-7345, 8/2014, Volume 5, Issue 7, pp. 138 - 14
Protocols for the FLP-mediated transformation of ethers are presented. Distinct reaction pathways involving either C-O or C-H bond activation occur depending... 
Journal Article
Dalton Transactions, ISSN 1477-9226, 09/2014, Volume 43, Issue 40, pp. 15201 - 15211
The phosphinimines R sub(3)PNSiMe sub(3) (R = t-Bu: 1a, R = Cy: 1b, R = Et: 1c, R = Ph: 1d) are reacted with a series of chloro and fluoroboranes (9Cl-9-BBN,... 
Exchange | Lewis acid | Diffraction | Molecular structure | Ion exchangers | X-rays | Electronics | Boranes
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 10/2009, Volume 131, Issue 40, pp. 14210 - 14211
The controlled activation of white phosphorus, P4, provides a key entry point into many aspects of phosphorus chemistry. The activation and functionalization... 
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 06/2014, Volume 53, Issue 25, pp. 6538 - 6541
The dicationic imidazolium‐phosphonium salt [(SIMes)PFPh2][B(C6F5)4]2 has been prepared and shown to exhibit remarkable Lewis acidity in stoichiometric... 
hydrosilylation | Lewis acids | hydrodefluorination | phosphonium salts | carbene ligands
Journal Article
European Journal of Inorganic Chemistry, ISSN 1434-1948, 02/2016, Volume 2016, Issue 5, pp. 667 - 677
The controlled activation of white phosphorus, P4, provides a key entry point into many aspects of polyphosphorus chemistry. Herein, the reaction of... 
Insertion | Cage compounds | Phosphorus | Phosphenium cations | Phosphorus heterocycles | Nitrogen ­heterocycles | Nitrogen heterocycles | Organophosphorus compounds
Journal Article
Chemistry - A European Journal, ISSN 0947-6539, 01/2015, Volume 21, Issue 5, p. 2193
The reactivity of a series of carbodiimides RNi[pounds sterling]3/4Ci[pounds sterling]3/4NR (R=tBu (1a), iPr (1b), SiMe.sub.3 (1c), and Dipp... 
Isomerization | Hydrogenation | Borates
Journal Article
Inorganic Chemistry, ISSN 0020-1669, 03/2012, Volume 51, Issue 6, pp. 3374 - 3387
Fluorobenzene solutions of RPCl2 and a Lewis acid such as ECl3 (E = Al, Ga) in a 1:1 ratio are used as reactive sources of chlorophosphenium cations [RPCl](+),... 
PHOSPHORUS CATIONS | NMR-SPECTRA | P5X2+ X | CHEMISTRY | COORDINATION-COMPLEXES | SYSTEMS | PHOSPHENIUM | DICATIONS | CHLORIDE | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Chemistry: A European Journal, ISSN 0947-6539, 01/2015, Volume 21, Issue 5, pp. 2193 - 2199
The reactivity of a series of carbodiimides RN==C==NR (R=tBu (1a), iPr (1b), SiMe sub(3) (1c), and Dipp (2,6-di-iso-propylphenyl (1d)) with B(C sub(6)F sub(5))... 
Equivalence | Pathways | Transformations | Derivatives | Hydrogenation | Carbodiimides | Adducts | Cyanamides
Journal Article
Chemical Communications, ISSN 1359-7345, 09/2014, Volume 50, Issue 70, pp. 10038 - 10040
Protocols for the FLP-mediated transformation of ethers are presented. Distinct reaction pathways involving either C-O or C-H bond activation occur depending... 
BORATE | THF | CRYSTAL-STRUCTURE | RING | PHOSPHINES | COMPLEXES | B(C6F5) | TETRAHYDROFURAN | CATION | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
European Journal of Inorganic Chemistry, ISSN 1434-1948, 02/2016, Volume 2016, Issue 5, pp. 667 - 677
The controlled activation of white phosphorus, P sub(4), provides a key entry point into many aspects of polyphosphorus chemistry. Herein, the reaction of... 
Lewis acid | Cage | Insertion | Activation | Formations | Cations | Derivatives | Dipping
Journal Article
ISSN 1477-9226, 3/2016, Volume 45, Issue 14, pp. 5949 - 5957
Using commercially available 2-pyridyldiphenylphosphine ( o -NC 5 H 4 )PPh 2 , a family of electrophilic phosphonium cations [( o -NC 5 H 4 )PFPh 2 ] + ( 2 )... 
Journal Article
Chemical Science, ISSN 2041-6520, 10/2015, Volume 6, Issue 11, pp. 6367 - 6372
The cationic N sub(3)-species [(p-HC sub(6)F sub(4)) sub(3)PN sub(3)] super(+) (1) featuring a perfluoro-arene phosphonium group serves as a N sub(3)... 
Diffraction | Cationic | X-rays | Cations | Lewis base | Carbenes | Bonding | Phosphines
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 07/2015, Volume 54, Issue 28, pp. 8250 - 8254
Journal Article
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