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catalysis (4) 4
chemistry, organic (4) 4
palladium (4) 4
chemistry, inorganic & nuclear (3) 3
homogeneous catalysis (3) 3
alkynes (2) 2
allenes (2) 2
aromatic compounds (2) 2
asymmetric transfer hydrogenation (2) 2
benzyl amines (2) 2
chemical sciences (2) 2
chemistry (2) 2
chemistry, applied (2) 2
chemistry, multidisciplinary (2) 2
heck reaction (2) 2
hydrogenation (2) 2
iridium (2) 2
ketones (2) 2
ligands (2) 2
mechanism (2) 2
ruthenium (2) 2
ruthenium complexes (2) 2
transfer hydrogenation (2) 2
[ chim.cata ] chemical sciences/catalysis (1) 1
alkene (1) 1
alkenes (1) 1
allene (1) 1
alpha-olefins (1) 1
alternating copolymerization (1) 1
aromatic amines (1) 1
aryl chlorides (1) 1
asymmetry (1) 1
atactic polyketones (1) 1
atom (1) 1
auslaugen (1) 1
bacterial dehalogenases (1) 1
bidentate n-ligands (1) 1
bidentate nitrogen ligands (1) 1
bond-forming reactions (1) 1
c-c (1) 1
carbonyl-compounds (1) 1
catalysts (1) 1
catalytic asymmetric rearrangement (1) 1
catalyzed reactions (1) 1
characterization and evaluation of materials (1) 1
chemische reaktion (1) 1
chemistry, physical (1) 1
chiral allylic amines (1) 1
chiral ligands (1) 1
chloride substitution-reactions (1) 1
chlorohydrin (1) 1
co/p-methylstyrene copolymerization (1) 1
co/styrene copolymerization (1) 1
cobalt oxazoline palladacycles (1) 1
colloids (1) 1
colloids - chemistry (1) 1
complexes (1) 1
coordination (1) 1
coordination chemistry (1) 1
cross-coupling (1) 1
cross-linking reagents - chemistry (1) 1
cross‐coupling (1) 1
crystal structure (1) 1
crystals (1) 1
cyclometalation (1) 1
cycloruthenated (1) 1
diamine (1) 1
diimine pd complexes (1) 1
dynamic kinetic resolution (1) 1
efficient catalyst (1) 1
enantiomers (1) 1
enzymatic resolution (1) 1
enzymes (1) 1
epoxide (1) 1
haloalcohol dehalogenase (1) 1
heterocyclic compounds (1) 1
heterogeneous catalysis (1) 1
homogene katalyse (1) 1
hydride (1) 1
hydrierungen (1) 1
imine catalysts (1) 1
imines (1) 1
industrial chemistry/chemical engineering (1) 1
intramolecular-coordination compounds (1) 1
ion (1) 1
ions - chemistry (1) 1
katalyse. synthese palladium (1) 1
kolloid (1) 1
ligand bifunctional catalysis (1) 1
ligand-free palladium (1) 1
mechanismus (1) 1
membran (1) 1
membranes (1) 1
membranes nanoparticles (1) 1
membranreaktor (1) 1
metal nanoparticles - chemistry (1) 1
metal nanoparticles - ultrastructure (1) 1
metal-ammonia reduction (1) 1
metallacycle (1) 1
methyl phenylpropynoate (1) 1
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1. Full Text Ion- and atom-leaching mechanisms from palladium nanoparticles in cross-coupling reactions
by Gaikwad, A.V and Holuigue, A.F and Thathagar, M and ten Elshof, J.E and Rothenberg, G
Chemistry - A European Journal, ISSN 0947-6539, 2007, Volume 13, Issue 24, pp. S6908/1 - S6908/7
Leaching of palladium species from Pd nanoparticles under CC coupling conditions was observed for both Heck and Suzuki reactions by using a special membrane... 
membranes | Heck reaction | catalysis | nanoparticles | cross‐coupling | Nanoparticles | Membranes | Cross-coupling | Catalysis | membranes nanoparticles | HETEROGENEOUS CATALYSIS | COLLOIDS | CHEMISTRY, MULTIDISCIPLINARY | LIGAND-FREE PALLADIUM | cross-coupling | C-C | HOMOGENEOUS CATALYSIS | TRANSITION-METAL NANOCLUSTERS | MICROPOROUS MEMBRANES | SIZE DISTRIBUTION | ARYL CHLORIDES | Colloids - chemistry | Microscopy, Electron, Transmission | Ions - chemistry | Cross-Linking Reagents - chemistry | Metal Nanoparticles - chemistry | Molecular Structure | Spectrophotometry | Palladium - chemistry | Metal Nanoparticles - ultrastructure
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2. Full Text Cyclometalated Complexes of Ruthenium, Rhodium and Iridium as Catalysts for Transfer Hydrogenation of Ketones and Imines
by Pannetier, Nicolas and Sortais, Jean‐Baptiste and Issenhuth, Jean‐Thomas and Barloy, Laurent and Sirlin, Claude and Holuigue, Alexandre and Lefort, Laurent and Panella, Lavinia and de Vries, Johannes G and Pfeffer, Michel
Advanced Synthesis & Catalysis, ISSN 1615-4150, 10/2011, Volume 353, Issue 14‐15, pp. 2844 - 2852
A library of organometallic compounds derived from primary and secondary amines cyclometalated by ruthenium(II), rhodium(III) and iridi‐ um(III) was tested in... 
iridium | ruthenium | imines | transfer hydrogenation | ketones | rhodium | ASYMMETRIC TRANSFER HYDROGENATION | BENZYL AMINES | MECHANISM | CHEMISTRY, ORGANIC | HYDRIDE | PROPAN-2-OL | EFFICIENT CATALYST | LIGANDS | REDUCTION | CHEMISTRY, APPLIED | DIAMINE | WATER | Reduction | Asymmetry | Catalysts | Imines | Ketones | Rhodium | Aromatic compounds | Catalysis | Chemical Sciences
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3. Full Text Cyclometalation of Primary Benzyl Amines by Ruthenium(II), Rhodium(III), and Iridium(III) Complexes
by Sortais, Jean-Baptiste and Pannetier, Nicolas and Holuigue, Alexandre and Barloy, Laurent and Sirlin, Claude and Pfeffer, Michel and Kyritsakas, Nathalie
Organometallics, ISSN 0276-7333, 04/2007, Volume 26, Issue 8, pp. 1856 - 1867
The cyclometalation of chiral and achiral primary amines occurred readily with Ru(II), Rh(III), and Ir(III) derivatives. Thus, the metalation of... 
CHLORIDE SUBSTITUTION-REACTIONS | STEREOGENIC METAL CENTERS | BOND-FORMING REACTIONS | CATALYTIC ASYMMETRIC REARRANGEMENT | CHIRAL ALLYLIC AMINES | CHEMISTRY, ORGANIC | TRANSFER HYDROGENATION | CYCLORUTHENATED (R)(C)-(+)-N,N-DIMETHYL-ALPHA-(2-NAPHTHYL) ETHYLAMINE | COBALT OXAZOLINE PALLADACYCLES | ORTHOMETALLATED PRIMARY AMINES | INTRAMOLECULAR-COORDINATION COMPOUNDS | CHEMISTRY, INORGANIC & NUCLEAR
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4. Full Text Subtle Balance of Steric and Electronic Effects for the Synthesis of Atactic Polyketones Catalyzed by Pd Complexes with Meta-Substituted Aryl-BIAN Ligands
by Scarel, Alessandro and Axet, M. Rosa and Amoroso, Francesco and Ragaini, Fabio and Elsevier, Cornelis J and Holuigue, Alexandre and Carfagna, Carla and Mosca, Luca and Milani, Barbara
Organometallics, ISSN 0276-7333, 04/2008, Volume 27, Issue 7, pp. 1486 - 1494
Both symmetric and nonsymmetric bis(aryl)acenaphthenequinonediimine ligands, featured by substituents in meta-positions of the aryl rings, have been applied... 
PYRIDINE-IMIDAZOLINE LIGANDS | ALTERNATING COPOLYMERIZATION | ALPHA-OLEFINS | CO/P-METHYLSTYRENE COPOLYMERIZATION | CO/STYRENE COPOLYMERIZATION | MONOXIDE | PALLADIUM-CARBON BONDS | CHEMISTRY, ORGANIC | BIDENTATE NITROGEN LIGANDS | DIIMINE PD(II) COMPLEXES | METHYLPALLADIUM(II) COMPOUNDS | CHEMISTRY, INORGANIC & NUCLEAR | Chemical Sciences | Coordination chemistry | Catalysis
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5. Full Text Cycloruthenated Primary and Secondary Amines as Efficient Catalyst Precursors for Asymmetric Transfer Hydrogenation
by Sortais, Jean-Baptiste and Ritleng, Vincent and Voelklin, Adeline and Holuigue, Alexandre and Smail, Hakima and Barloy, Laurent and Sirlin, Claude and Verzijl, Gerard K. M and Boogers, Jeroen A. F and de Vries, André H. M and de Vries, Johannes G and Pfeffer, Michel
Organic Letters, ISSN 1523-7060, 03/2005, Volume 7, Issue 7, pp. 1247 - 1250
Ruthenacycles obtained by cyclometalation of enantiopure aromatic primary or secondary amines with [(η6-benzene)RuCl2]2 or with [(η6-p-cymene)RuCl2]2 are... 
LIGAND BIFUNCTIONAL CATALYSIS | RUTHENIUM(II) COMPLEXES | PALLADIUM | CHIRAL LIGANDS | PALLADACYCLES | CHEMISTRY, ORGANIC | CARBONYL-COMPOUNDS | HOMOGENEOUS CATALYSIS | HECK REACTION | IMINE CATALYSTS | PRIMARY BENZYLAMINES
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6. Full Text [Pd(Ar‐BIAN)(alkene)]‐Catalyzed Highly Chemo‐, Regio‐, and Stereoselective Semihydrogenation of 1,2‐Allenyl Phosphonates and Related Compounds
by Guo, Hao and Zheng, Zilong and Yu, Fei and Ma, Shengming and Holuigue, Alexandre and Tromp, Dorette S and Elsevier, Cornelis J and Yu, Yihua
Angewandte Chemie International Edition, ISSN 1433-7851, 07/2006, Volume 45, Issue 30, pp. 4997 - 5000
Often elusive, trisubstituted (Z)‐1‐alkenyl phosphonates can be prepared by the semihydrogenation of allenyl phosphonates in the presence of Pd complex 1. This... 
allenes | palladium | homogeneous catalysis | alkenes | hydrogenation | Allenes | Palladium | Alkenes | Hydrogenation | Homogeneous catalysis | METAL-AMMONIA REDUCTION | ORGANIC-SYNTHESIS | CATALYZED REACTIONS | ALKYNES | CHEMISTRY, MULTIDISCIPLINARY
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7. Full Text Ruthenacycles and Iridacycles as Catalysts for Asymmetric Transfer Hydrogenation and Racemisation
by Jerphagnon, Thomas and Haak, Robert and Berthiol, Florian and Gayet, Arnaud J. A and Ritleng, Vincent and Holuigue, Alexandre and Pannetier, Nicolas and Pfeffer, Michel and Voelklin, Adeline and Lefort, Laurent and Verzijl, Gerard and Tarabiono, Chiara and Janssen, Dick B and Minnaard, Adriaan J and Feringa, Ben L and de Vries, Johannes G
Topics in Catalysis, ISSN 1022-5528, 9/2010, Volume 53, Issue 15, pp. 1002 - 1008
Ruthenacycles, which are easily prepared in a single step by reaction between enantiopure aromatic amines and [Ru(arene)Cl2]2 in the presence of NaOH and KPF6,... 
Ruthenium | Dynamic kinetic resolution | Asymmetric transfer hydrogenation | Chlorohydrin | Chemistry | Physical Chemistry | Pharmacy | Epoxide | Characterization and Evaluation of Materials | Metallacycle | Catalysis | Iridium | Industrial Chemistry/Chemical Engineering | Haloalcohol dehalogenase | ROUTE | ENZYMATIC RESOLUTION | BENZYL AMINES | MECHANISM | CHEMISTRY, PHYSICAL | SECONDARY ALCOHOLS | CYCLOMETALATION | LIGANDS | RUTHENIUM COMPLEXES | CHEMISTRY, APPLIED | BACTERIAL DEHALOGENASES | Enzymes | Aromatic amines | Ketones | Heterocyclic compounds | Enantiomers | Hydrogenation
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8. Full Text Selective head-to-tail coupling of methyl phenylpropynoate providing palladacycles with bidentate N-ligands
by Holuigue, Alexandre and Sirlin, Claude and Pfeffer, Michel and Goubitz, Kees and Fraanje, Jan and Elsevier, Cornelis J
Inorganica Chimica Acta, ISSN 0020-1693, 2006, Volume 359, Issue 6, pp. 1773 - 1778
Unexpected, complete regioselectivity has been observed in the high-yield formation of palladacycles from methyl phenylpropynoate with Pd(dba) in the presence... 
Methyl phenylpropynoate | Palladacyclopentadiene | Regioselectivity | Bidentate N-ligands | Crystal structure | regioselectivity | PALLADIUM-CATALYZED CYCLOTRIMERIZATION | RINGS | COMPLEXES | REACTIVITY | COORDINATION | bidentate N-ligands | ALKYNES | CHEMISTRY, INORGANIC & NUCLEAR | palladacyclopentadiene | methyl phenylpropynoate | crystal structure | CHEMISTRY | NITROGEN LIGANDS | SCATTERING FACTORS | Structure | Aromatic compounds | Crystals
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9. Full Text [Pd(Ar-BIAN)(alkene)]-Catalyzed Highly Chemo-, Regio-, and Stereoselective Semihydrogenation of 1,2-Allenyl Phosphonates and Related Compounds
by Guo, Hao and Zheng, Zilong and Yu, Fei and Ma, Shengming and Holuigue, Alexandre and Tromp, Dorette S and Elsevier, Cornelis J and Yu, Yihua
Angewandte Chemie, ISSN 0044-8249, 07/2006, Volume 118, Issue 30, pp. 5119 - 5122
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10. Full Text [Pd(Ar‐BIAN)(alkene)]‐Catalyzed Highly Chemo‐, Regio‐, and Stereoselective Semihydrogenation of 1,2‐Allenyl Phosphonates and Related Compounds
by Guo, Hao and Zheng, Zilong and Yu, Fei and Ma, Shengming and Holuigue, Alexandre and Tromp, Dorette S and Elsevier, Cornelis J and Yu, Yihua
Angewandte Chemie, ISSN 0044-8249, 07/2006, Volume 118, Issue 30, pp. 5119 - 5122
Ansonsten schwer fassbare trisubstituierte (Z)‐1‐Alkenylphosphonate erhält man durch partielle Hydrierung von Allenylphosphonaten in Gegenwart des Pd‐Komplexes... 
Palladium | Alkene | Homogene Katalyse | Allene | Hydrierungen
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11. Palladacycles: synthesis and catalysis
by Holuigue, Alexandre
Proefschrift Universiteit van Amsterdam. Met samenvattingen in het Nederlands en Frans. 
Katalyse. Synthese (chemie) Palladium
Dissertation
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12. Full Text [Pd(Ar‐BIAN)(alkene)]‐Catalyzed Highly Chemo‐, Regio‐, and Stereoselective Semihydrogenation of 1,2‐Allenyl Phosphonates and Related Compounds
by Guo, Hao and Zheng, Zilong and Yu, Fei and Ma, Shengming and Holuigue, Alexandre and Tromp, Dorette S and Elsevier, Cornelis J and Yu, Yihua
ChemInform, ISSN 0931-7597, 12/2006, Volume 37, Issue 49, pp. no - no
ChemInform is a weekly ing Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform ,... 
allenes (acyclic compounds) | allenes (benzene compounds) | reduction, hydrogenation | organo‐phosphorus compounds
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