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The Journal of Organic Chemistry, ISSN 0022-3263, 06/2018, Volume 83, Issue 12, pp. 6363 - 6372
Herein, a general and practical route to 2-(2-aminophenyl)- and 2-(2-alkoxyphenyl)-substituted benzazoles by nucleophilic aromatic substitution (SNAr) is... 
COMPLEX | METHODOLOGY | FLUORESCENCE | 2-ARYLBENZOTHIAZOLES | CHEMISTRY, ORGANIC | ARYL | RADICALS | ORTHO-ARYLATION | 2-ARYLBENZOXAZOLE DERIVATIVES | ACTIVATED PHOTOREDOX CATALYSIS | NUCLEOPHILIC AROMATIC-SUBSTITUTION
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 03/2019, Volume 58, Issue 11, pp. 3575 - 3578
An enantioselective C(sp3)−C(sp3) cross‐coupling of racemic α‐silylated alkyl iodides and alkylzinc reagents is reported. The reaction is catalyzed by... 
cross-coupling | radical reactions | nickel | silicon | synthetic methods | ALLYLIC SILANES | INSERTION | ASYMMETRIC-SYNTHESIS | CONJUGATE SILYL TRANSFER | HYDROSILYLATION | COMPLEXES | SI BOND FORMATION | SECONDARY | CHEMISTRY, MULTIDISCIPLINARY | ALKYL ELECTROPHILES | Silanes | Iodides | Reagents | Nickel | Coupling | Enantiomers | Nickel chloride | Carbon | Functional groups
Journal Article
Organic Letters, ISSN 1523-7060, 11/2012, Volume 14, Issue 21, pp. 5546 - 5549
A new method for C–C and C–N bond formation of heteroaromatics and C(sp3)–H alkanes was developed with high regioselectivity. The reaction occurred on C8 to... 
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 07/2014, Volume 20, Issue 28, pp. 8551 - 8555
A lanthanide‐catalyzed sequential insertion of CN and CC into an NH bond is presented. The convenient reaction, which proceeds under mild conditions, is an... 
propargylamines | nitriles | imidazoles | CC coupling | lanthanides | C-C coupling
Journal Article
Angewandte Chemie - International Edition, ISSN 1433-7851, 12/2018, Volume 57, Issue 49, pp. 16067 - 16071
The removal of C H and C H from C H streams is of great significance for feedstock purification to produce polyethylene and other commodity chemicals but the... 
selective adsorption | metal–organic frameworks | gas separation | electrostatic interactions | light hydrocarbons
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 11/2014, Volume 20, Issue 47, pp. 15605 - 15610
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 10/2018, Volume 57, Issue 43, pp. 14085 - 14089
Selective introduction of fluorine into molecules by the cleavage of inert C−H bonds is of central academic and synthetic interest, yet remains challenging.... 
fluorination | palladium | alcohols | C−H activation | synthetic methods | CATALYSIS | ACTIVATION | F BOND | ALPHA-AMINO-ACIDS | CARBON-HYDROGEN BONDS | REDUCTIVE ELIMINATION | CHEMISTRY, MULTIDISCIPLINARY | FLUORIDE | DIRECTING GROUPS | FUNCTIONALIZATION | C-H activation | C-H FLUORINATION | Organic chemistry | Hydrogen bonds | Fluorine | Alcohol | Fluorination | Alcohols | Acetone
Journal Article
Organic Letters, ISSN 1523-7060, 10/2016, Volume 18, Issue 19, pp. 4928 - 4931
An effective photoredox-mediated tandem phosphorylation/cyclization reaction of diphenylphosphine oxide with three types of radical acceptors leads to... 
H FUNCTIONALIZATION | DIARYLPHOSPHINE OXIDES | PHOSPHORESCENT IRIDIUM(III) COMPLEXES | PHENANTHRIDINE DERIVATIVES | DIALKYL PHOSPHITES | CHEMISTRY, ORGANIC | SECONDARY PHOSPHINE OXIDES | PHOTOPHYSICAL PROPERTIES | OXIDATIVE CYCLIZATION | METAL-FREE | PHOTOREDOX CATALYSIS
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 11/2010, Volume 16, Issue 43, pp. 12956 - 12961
The synthesis and characterization of novel cis‐1,2‐disilylenylethene [cis‐LSi{C(Ph)C(H)}SiL] (2; L=PhC(NtBu)2) and a singlet delocalized biradicaloid... 
density functional calculations | N ligands | silicon | radicals | silylene | SILABENZENE | ANALOG | COMPOUND | REACTIVITY | CHEMISTRY, MULTIDISCIPLINARY | VALENCE ISOMERIZATION | AR | AROMATICITY | BOND | Synthesis | Equivalence | Mathematical analysis | Toluene | X-rays | Ligands | NMR spectroscopy | Crystallography
Journal Article
The Journal of Organic Chemistry, ISSN 0022-3263, 03/2018, Volume 83, Issue 6, pp. 3200 - 3207
An anodic oxidation/cyclization of 2-arylbenzoic acids for the synthesis of dibenzopyranones has been developed. The reaction proceeds at room temperature with... 
DEHYDROGENATIVE LACTONIZATION | LACTONES | CATALYZED C(SP)-H | GREEN SYNTHESIS | CHEMISTRY, ORGANIC | BENZOXAZOLES | METAL | ELECTROOXIDATIVE CYCLIZATION | RADICAL REACTIONS | ELECTROCHEMICAL SYNTHESIS | CARBOXYLIC-ACIDS
Journal Article