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1. Full Text Manganese‐Catalyzed Dehydrogenative [4+2] Annulation of NH Imines and Alkynes by CH/NH Activation
by He, Ruoyu and Huang, Zhi‐Tang and Zheng, Qi‐Yu and Wang, Congyang
Angewandte Chemie International Edition, ISSN 1433-7851, 05/2014, Volume 53, Issue 19, pp. 4950 - 4953
Described herein is a manganese‐catalyzed dehydrogenative [4+2] annulation of NH imines and alkynes, a reaction providing highly atom‐economical access to... 
CH activation | heterocycles | manganese | synthetic methods | alkynes | C-H activation | AROMATIC KETIMINES | ISOQUINOLINES | FUNCTIONALIZATIONS | CARBON-CARBON BONDS | COPPER | INTERNAL ALKYNES | CHEMISTRY, MULTIDISCIPLINARY | MOLECULES | CH activation | DERIVATIVES | ALKENYLATION | CYCLIZATION | Organic chemistry | Additives | Imines | Oxidants | Dehydrogenation | Byproducts | Activation | Catalysis | Alkynes
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2. Full Text Palladium-catalyzed oxidative carbonylation of benzylic C-H bonds via nondirected C(sp 3)-H activation
by Xie, Pan and Xie, Yinjun and Qian, Bo and Zhou, Han and Xia, Chungu and Huang, Hanmin
Journal of the American Chemical Society, ISSN 0002-7863, 06/2012, Volume 134, Issue 24, pp. 9902 - 9905
A new strategy for generating benzylpalladium reactive species from toluenes via nondirected C(sp(3))-H activation has been developed. This led to construction... 
HALIDES | PHENYLACETIC ACIDS | AMINATION | HYDROCARBONS | COUPLING REACTIONS | MONOXIDE | ARYL | CARBOXYLATION | CARBON-HYDROGEN BONDS | AROMATIC-COMPOUNDS | CHEMISTRY, MULTIDISCIPLINARY | Analysis | Carboxylation | Chemical bonds | Palladium | Chemical properties | Catalysis | Acetic acid | Structure
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3. Transition metal-catalyzed ketone-directed or mediated C-H functionalization
by Huang, Zhongxing and Lim, Hee Nam and Mo, Fanyang and Young, Michael C and Dong, Guangbin
Chemical Society Reviews, ISSN 0306-0012, 10/2015, Volume 44, Issue 21, pp. 7764 - 7786
Transition metal-catalyzed C-H functionalization has evolved into a prominent and indispensable tool in organic synthesis. While nitrogen, phosphorus and... 
Synthesis | Ketones | Categories | Olefins | Tools | Evolution | Activation | Alkynes
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4. Full Text Recent Advances in Radical C-H Activation/Radical Cross-Coupling
by Yi, Hong and Zhang, Guoting and Wang, Huamin and Huang, Zhiyuan and Wang, Jue and Singh, Atul K and Lei, Aiwen
Chemical Reviews, ISSN 0009-2665, 07/2017, Volume 117, Issue 13, pp. 9016 - 9085
Research and industrial interest in radical C-H activation/radical cross coupling chemistry has continuously grown over the past few decades. These reactions... 
C(SP)-H BOND FUNCTIONALIZATION | METAL-FREE CONDITIONS | FREE OXIDATIVE FUNCTIONALIZATION | ALPHA,ALPHA-DIARYL ALLYLIC ALCOHOLS | LIGHT PHOTOREDOX CATALYSIS | ALPHA-AMINOALKYL RADICALS | CARBON-CARBON BONDS | ELECTRON-DEFICIENT ALKENES | TERT-BUTYL HYDROPEROXIDE | CHEMISTRY, MULTIDISCIPLINARY | AROMATIC-SUBSTITUTION BHAS
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5. Full Text Electrocatalytic Oxidant‐Free Dehydrogenative C−H/S−H Cross‐Coupling
by Wang, Pan and Tang, Shan and Huang, Pengfei and Lei, Aiwen
Angewandte Chemie International Edition, ISSN 1433-7851, 03/2017, Volume 56, Issue 11, pp. 3009 - 3013
An environmentally friendly electrocatalytic protocol has been developed for dehydrogenative C−H/S−H cross‐coupling. This method enabled C−S bond formation... 
C−H functionalization | dehydrogenation | electrochemistry | radical cations | C−S bond formation | HALIDES | C-S bond formation | CATALYST | C-H functionalization | CHEMISTRY, MULTIDISCIPLINARY | HIGHLY EFFICIENT | DISULFIDES | THIOLS | S BOND FORMATION | BIOLOGICAL EVALUATION | ARYL IODIDES | INHIBITORS | Electrochemistry | Thiols | Electrolysis | Dehydrogenation | Cross coupling | Transformation | Aromatic compounds | Intermediates
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6. Full Text Iron‐Catalyzed Oxidative CH/CH Cross‐Coupling: An Efficient Route to α‐Quaternary α‐Amino Acid Derivatives
by Li, Kaizhi and Tan, Guangying and Huang, Jingsheng and Song, Feijie and You, Jingsong
Angewandte Chemie International Edition, ISSN 1433-7851, 12/2013, Volume 52, Issue 49, pp. 12942 - 12945
Fully loaded : A coordinating activation strategy has been developed to furnish α‐quaternary α‐amino acids through the iron(III)‐catalyzed oxidative... 
iron | homogeneous catalysis | cross‐coupling | α‐quaternary α‐amino acids | coordinating activation | cross-coupling | α-quaternary α-amino acids | DIRECTING GROUP | CONSTRAINED PEPTIDES | C(SP)-H BONDS | CARBONYL-COMPOUNDS | METABOTROPIC GLUTAMATE RECEPTORS | CHEMISTRY, MULTIDISCIPLINARY | BIDENTATE-CHELATION ASSISTANCE | UNACTIVATED C(SP)-H BONDS | AROMATIC AMIDES | alpha-quaternary alpha-amino acids | GLYCINE DERIVATIVES | TUNICATE DENDRODOA-GROSSULARIA | Oxidation-Reduction | Esters - chemistry | Amino Acids - chemistry | Ferric Compounds - chemistry | Molecular Structure | Amino Acids - chemical synthesis | Catalysis
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7. Full Text Cobalt‐Catalyzed Oxidative C−H/C−H Cross‐Coupling between Two Heteroarenes
by Tan, Guangying and He, Shuang and Huang, Xiaolei and Liao, Xingrong and Cheng, Yangyang and You, Jingsong
Angewandte Chemie International Edition, ISSN 1433-7851, 08/2016, Volume 55, Issue 35, pp. 10414 - 10418
The first example of cobalt‐catalyzed oxidative C−H/C−H cross‐coupling between two heteroarenes is reported, which exhibits a broad substrate scope and a high... 
SET pathway | bi(hetero)aryls | oxidative C−H/C−H cross-coupling | cobalt catalysis | DIRECT ARYLATION | bi(hetero) aryls | DIRECTED C(SP)-H | oxidative C-H/C-H cross-coupling | UNACTIVATED ARENES | CHEMISTRY, MULTIDISCIPLINARY | INDOLES | BIDENTATE-CHELATION ASSISTANCE | ALIPHATIC AMIDES | FUNCTIONALIZATION | ARYL HALIDES | BOND ACTIVATION | AMINOQUINOLINE BENZAMIDES | Mass spectrometry | Cobalt | Catalysis | Deuterium | Exchanging | Temperature | Cross coupling | High resolution | Hydrogen | Electron transfer | Chemical reactions | Mass spectroscopy | Activation | High temperature | Trapping | Isotope effect | Functional anatomy | Temperature effects | Reaction time | Yield | Resonance | Electron paramagnetic resonance | Coupling | Functional groups
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8. Full Text Transition metal-catalyzed ketone-directed or mediated C-H functionalization
by Huang, Zhongxing and Lim, Hee Nam and Mo, Fanyang and Young, Michael C and Dong, Guangbin
Chemical Society Reviews, ISSN 0306-0012, 10/2015, Volume 44, Issue 21, pp. 7764 - 7786
Transition metal-catalyzed C-H functionalization has evolved into a prominent and indispensable tool in organic synthesis. While nitrogen, phosphorus and... 
ASYMMETRIC CONJUGATE ADDITION | AROMATIC KETONES | SILYL ENOL ETHERS | POTASSIUM TERT-BUTOXIDE | CARBON-HYDROGEN BONDS | WEAKLY COORDINATING KETONES | CHEMISTRY, MULTIDISCIPLINARY | DIRECT BETA-ARYLATION | ALKYL ARYL KETONES | AEROBIC DEHYDROGENATION | CONIA-ENE REACTION
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9. Full Text Manganese-catalyzed late-stage aliphatic C-H azidation
by Huang, Xiongyi and Bergsten, Tova M and Groves, John T
Journal of the American Chemical Society, ISSN 0002-7863, 04/2015, Volume 137, Issue 16, pp. 5300 - 5303
We report a manganese-catalyzed aliphatic azidation reaction that can, efficiently :Convert secondary, tertiary, and benzylic C-H bonds to the corresponding... 
AMINATION | COMPLEX | ACTIVATION | BONDS | PORPHYRINS | NITROGEN | OXIDATIONS | CHEMISTRY | IRON | FLUORINATION | CHEMISTRY, MULTIDISCIPLINARY | Benzyl Compounds - chemistry | Chemistry Techniques, Synthetic | Hydrocarbons - chemistry | Hydrocarbons - chemical synthesis | Models, Molecular | Benzyl Compounds - chemical synthesis | Catalysis | Manganese - chemistry | Azides - chemical synthesis | Azides - chemistry | Chemical bonds | Chemical reactions | Chemical properties | Research | Manganese
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10. Full Text Phenol-Directed C-H Functionalization
by Huang, Zheng and Lumb, Jean-Philip
ACS Catalysis, ISSN 2155-5435, 01/2019, Volume 9, Issue 1, pp. 521 - 555
Phenols are important starting materials, intermediates, and functional elements of a very broad range of chemicals and materials. They are large-volume... 
selectivity | oxidation | phenol | transition metal catalysis | C-H functionalization | N-ACETYL INDOLES | ASYMMETRIC-SYNTHESIS | ENANTIOSELECTIVE SYNTHESIS | OXIDATIVE 3+2 CYCLOADDITION | ALLYLIC ALKYLATION | CHEMISTRY, PHYSICAL | FORMAL RADICAL CYCLIZATION | COPPER-CATALYZED HYDROXYLATION | ORTHO-ARYLATION | FRIEDEL-CRAFTS REACTION | METAL-FREE
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11. Full Text Transition metal-catalyzed C-H functionalization of N-oxyenamine internal oxidants
by Huang, Huawen and Ji, Xiaochen and Wu, Wanqing and Jiang, Huanfeng
Chemical Society Reviews, ISSN 0306-0012, 2/2015, Volume 44, Issue 5, pp. 1155 - 1171
The transition metal-catalyzed C-H functionalization with hydroxylamine derivatives serving as both reactants and internal oxidants has attracted a lot of... 
ACTIVATION | O BOND | RHODIUM(III)-CATALYZED SYNTHESIS | ALKYNES SYNTHESIS | EFFICIENT SYNTHESIS | REGIOSELECTIVE SYNTHESIS | OXIME ACETATES | ISOQUINOLONE SYNTHESIS | CHEMISTRY, MULTIDISCIPLINARY | CYCLIZATION | PHENOXYACETAMIDES | Oxidants | Methyl alcohol | Oxidizing agents | Byproducts | Tolerances | Derivatives | Wastes | Carboxylic acids
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12. Full Text Transition-Metal-Catalyzed Direct Addition of Unactivated C-H Bonds to Polar Unsaturated Bonds
by Yang, Lei and Huang, Hanmin
Chemical Reviews, ISSN 0009-2665, 2015, Volume 115, Issue 9, pp. 3468 - 3517
CYCLIZATION DIRECT SYNTHESIS | N-HETEROCYCLIC CARBENE | INTRAMOLECULAR KETONE HYDROACYLATION | ONE-STEP SYNTHESIS | ONE-POT SYNTHESIS | O-P LIGAND | CARBON-HYDROGEN BONDS | DIRECT INTERMOLECULAR HYDROACYLATION | S-SUBSTITUTED ALDEHYDES | CHEMISTRY, MULTIDISCIPLINARY | FRIEDEL-CRAFTS ALKENYLATION | Transition Elements - chemistry | Catalysis | Hydrogen - chemistry | Carbon - chemistry | Chemical bonds | Transition metals | Research | Chemical properties
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13. Full Text Transition metal-catalyzed C-H functionalization of N-oxyenamine internal oxidants
by Huang, Huawen and Ji, Xiaochen and Wu, Wanqing and Jiang, Huanfeng
Chemical Society reviews, ISSN 0306-0012, 03/2015, Volume 44, Issue 5, pp. 1155 - 1171
The transition metal-catalyzed C-H functionalization with hydroxylamine derivatives serving as both reactants and internal oxidants has attracted a lot of... 
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