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Journal of Organometallic Chemistry, ISSN 0022-328X, 08/2019, Volume 893, pp. 61 - 71
The heterometallic hydride [MoWCp ( -H)( -PCy )(CO) ] was prepared in 30% yield through reaction of an equimolar mixture of [Mo Cp (CO) ] and [W Cp (CO) ] with... 
Agostic complexes | Carbyne complexes | Carbonylate complexes | Hydride complexes | Metal−metal interactions | Heterometallic complexes
Journal Article
European Journal of Inorganic Chemistry, ISSN 1434-1948, 03/2017, Volume 2017, Issue 9, pp. 1280 - 1283
An efficient synthetic route for the preparation of the title anions was implemented, and it involved two‐electron reduction of iodide‐bridged [MMoCp(µ‐I)(µ‐PR... 
P ligands | Anions | Carbonyl ligands | Heterometallic complexes | Metal–metal interactions | REACTIVITY | METAL MULTIPLE BONDS | CRYSTAL-STRUCTURES | ANION | TRANSITION-METALS | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
CHEMICAL COMMUNICATIONS, ISSN 1359-7345, 03/2019, Volume 55, Issue 19, pp. 2809 - 2812
Novel N-phosphinoguanidines ((HNPr)-Pr-i)((Ph2PNPr)-Pr-i)C(NAr) (Ar = 2,6-(Pr2C6H3)-Pr-i, 2,4,6-Me3C6H2) react with AlMe3 to afford phosphinimine-amidinato... 
ACTIVATION | RHODIUM | GUANYLATION | COMPLEXES | REACTIVITY | CARBONYL-COMPOUNDS | COORDINATION | FRUSTRATED LEWIS PAIRS | CHEMISTRY, MULTIDISCIPLINARY | CATALYSTS
Journal Article
Inorganic Chemistry, ISSN 0020-1669, 02/2018, Volume 57, Issue 3, pp. 912 - 915
The title compound was prepared upon irradiation of acetonitrile solutions of the readily available hexacarbonyl [MoReCp(mu-H) (mu-PCy2) (CO)(6)]. The... 
CATALYSIS | ACTIVATION | METAL | SERIES | BONDS | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Inorganics, ISSN 2304-6740, 12/2018, Volume 6, Issue 4, p. 125
Complexes displaying multiple bonds between different metal atoms have considerable synthetic potential because of the combination of the high electronic and... 
Metal-metal multiple bonds | Hydride complexes | Binuclear carbonyl complexes | Density functional theory calculations | Heterometallic complexes | hydride complexes | heterometallic complexes | metal–metal multiple bonds | density functional theory calculations | binuclear carbonyl complexes
Journal Article
Organometallics, ISSN 0276-7333, 10/2018, Volume 37, Issue 20, pp. 3425 - 3436
The ability of the title anion to act as an acceptor of simple donors and to participate in E-H bond activation processes (E = p-block element) was analyzed by... 
DIMOLYBDENUM COMPLEXES | TOTAL ENERGIES | MOLYBDENUM | AB-INITIO | P-C | SET MODEL CHEMISTRY | C-C | REACTIVITY | CHEMISTRY, ORGANIC | RHENIUM | HYDRIDE | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
European Journal of Inorganic Chemistry, ISSN 1434-1948, 10/2013, Volume 2013, Issue 28, pp. 4998 - 5008
Treatment of solutions of ammonia–borane (NH 3 · BH 3 , AB) with catalytic amounts (5 mol‐%) of the singly bonded dimers [M 2 Cp 2 (CO) 6 ] [M = Cr ( 1a ), Mo... 
Boranes | Amines | Group 6 elements | Dehydrogenation | Metal–metal bonds | Metal-metal bonds | ROOM-TEMPERATURE | BORON-NITROGEN BONDS | CATALYTIC DEHYDROCOUPLING/DEHYDROGENATION | HYDROGEN-STORAGE | SPENT FUEL | SIMPLE ROUTE | CHEMISTRY, INORGANIC & NUCLEAR | REDUCTION | TRANSITION-METAL | DIMETHYLAMINE-BORANE | LIGAND | Catalysts | Activation | Dimers | Catalysis | Bonding | Conversion | Adducts
Journal Article
Organometallics, ISSN 0276-7333, 08/2015, Volume 34, Issue 15, pp. 3833 - 3841
The title compound reacted rapidly with N2CH(SiMe3) at room temperature to give the electron-precise hydride [W2Cp2(H)(mu-PCy2)(CO)(2){N-N2CH(SiMe3)}] (W-W =... 
ALKYLIDENE COMPLEXES | METAL TRIPLE BOND | BRIDGED CARBONYL DIMERS | DECARBONYLATION REACTIONS | OXIDATIVE ADDITIONS | DINITROGEN COMPLEXES | COORDINATED LIGANDS | CHEMISTRY, ORGANIC | CRYSTAL-STRUCTURES | ARENEDIAZONIUM IONS | STRUCTURAL CHARACTERIZATION | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Journal of Organometallic Chemistry, ISSN 0022-328X, 08/2019, Volume 893, p. 61
* W-H and W-C binding is favoured at hydride and alkyl derivatives of the title anion. The heterometallic hydride... 
Density functionals
Journal Article
European Journal of Inorganic Chemistry, ISSN 1434-1948, 03/2017, Volume 2017, Issue 9, pp. 1280 - 1283
An efficient synthetic route for the preparation of the title anions was implemented, and it involved two-electron reduction of iodide-bridged [MMoCp( mu -I)(... 
Anions | Synthesis | Precursors | Clusters | Ligands | Terminals | Derivatives | Molybdenum
Journal Article
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