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Angewandte Chemie International Edition, ISSN 1433-7851, 09/2015, Volume 54, Issue 38, pp. 11245 - 11249
BCl3 is an inexpensive electrophile which induces the borylative cyclization of a wide range of substituted alkynes to regioselectively form polycycles... 
cyclizations | heterocycles | boron | synthetic methods | alkynes | ELECTROPHILIC CYCLIZATION | ACTIVATION | B(C6F5) | CHEMISTRY, MULTIDISCIPLINARY | BONDS | CONSTRUCTION | CYCLOISOMERIZATION | OMEGA-ARYL-1-ALKYNES | CATALYZED BORYLATION | DERIVATIVES | Communications | Communication
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 11/2017, Volume 23, Issue 63, pp. 15889 - 15893
The Suzuki–Miyaura (SM) reaction is one of the most important methods for C−C bond formation in chemical synthesis. In this communication, we show for the... 
transmetallation | cross-coupling | alkylation | boron | zincate | ORGANOBORON COMPOUNDS | PALLADIUM | REAGENTS | COMPLEXES | TERTIARY ALKYL-HALIDES | SECONDARY | CHEMISTRY, MULTIDISCIPLINARY | TRANSMETALATION | ESTERS | BENZYL HALIDES | Carbon-carbon composites | Cross coupling | Toxicity | Esters | Chemical reactions | Zincates | Zinc | Aromatic compounds | Bromides | Biocompatibility | Samarium | Chemical synthesis | Borates | Communications | Communication
Journal Article
Chemical Science, ISSN 2041-6520, 2017, Volume 8, Issue 12, pp. 7969 - 7977
Heteroatom doping into polyaromatic hydrocarbons (PAHs) is a powerful approach for modifying key physical properties, however, there are extremely few modular... 
NITROGEN | B-N | CHEMISTRY, MULTIDISCIPLINARY | POLYCYCLIC AROMATIC-HYDROCARBONS | BUILDING-BLOCKS | PERSPECTIVES
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 02/2017, Volume 23, Issue 9, pp. 2217 - 2224
Lower Lewis acidity boranes demonstrate greater tolerance to combinations of water/strong Brønsted bases than B(C6F5)3, this enables Si−H bond activation by a... 
water tolerance | reductive amination | boron | protodeboronation | frustrated Lewis pairs | HYDROGENATION | MECHANISM | SIGMA-BOND ACTIVATION | COMPLEXES | REACTIVITY | CARBONYL-COMPOUNDS | SALTS | CHEMISTRY, MULTIDISCIPLINARY | FACILE PROTOCOL | CATALYZED N-ALKYLATION | CARBOXYLIC-ACIDS | Silane | Conjugates | Amines | Catalysts | Boranes | Tolerances | Alkylamines | Aldehydes | Adducts | Full Paper | Full Papers
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 05/2015, Volume 54, Issue 19, pp. 5688 - 5692
The direct C(sp2)C(sp3) cross‐coupling of diaryl zinc reagents with benzylic, primary, secondary, and tertiary alkyl halides proceeded in the absence of... 
cross‐coupling | alkyl halides | organozinc reagents | zinc | synthetic methods | cross-coupling | ARYLATIONS | ANION | COMPLEXES | ELECTROPHILES | CHEMISTRY, MULTIDISCIPLINARY | Zinc | Solvents | Construction | Purification | Catalysts | Ambient temperature | Halides | Tolerances | Arrays
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 02/2011, Volume 50, Issue 9, pp. 2102 - 2106
Borenium does it direct: A boron analogue of the Friedel–Crafts reaction uses inexpensive catecholatoborenium cations that are sufficiently electrophilic to... 
borenium ions | borocations | boronate esters | electrophilic substitution | borylation | CONVERSION | C-H ACTIVATION | CHEMISTRY, MULTIDISCIPLINARY | STRATEGIES | HETEROARENES | TEMPERATURE | ARYL HALIDES | DIBORON REAGENTS | HETEROAROMATIC COMPOUNDS | CATALYZED BORYLATION | DERIVATIVES
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 10/2016, Volume 138, Issue 40, pp. 13361 - 13368
Thienyl di-N-methyliminodiacetic acid (MIDA) boronate esters are readily synthesized by electrophilic C–H borylation producing bench stable crystalline solids... 
PCPDTBT | ORGANIC SOLAR-CELLS | CONJUGATED POLYMERS | BUILDING-BLOCKS | PERFORMANCE | SPECIATION | PHOTOVOLTAIC APPLICATIONS | POLYTHIOPHENES | POLYMERIZATION | DERIVATIVES | CHEMISTRY, MULTIDISCIPLINARY | Polymerization | Usage | Chemical properties | Chemical synthesis | Chemical compounds
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 09/2014, Volume 20, Issue 40, pp. 12874 - 12880
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 01/2017, Volume 56, Issue 1, pp. 354 - 358
BCl3‐induced borylative cyclization of aryl‐alkynes possessing ortho‐EMe (E=S, O) groups represents a simple, metal‐free method for the formation of... 
annulation | electrophilic cyclization | organoboranes | cross coupling | borylation | Organoboranes | Couplings | Esters | Boron chlorides | Aromatic compounds | Alkynes | Communications | Communication
Journal Article
Chemical Communications: Chem Comm, ISSN 1359-7345, 03/2015, Volume 51, Issue 29, pp. 6257 - 6274
The incorporation of boron into the core structure of fused polycyclic aromatics generates compounds with highly attractive properties that have recently... 
Backbone | Optoelectronics | Boron | Aromatic compounds | Hydrocarbons | Boron compounds | Ladders
Journal Article
Organometallics, ISSN 0276-7333, 07/2017, Volume 36, Issue 14, pp. 2597 - 2604
Fused and ladder-type benzothiadiazole–arylamine donor–acceptor C,N-chelated boron complexes were synthesized through direct electrophilic C–H borylation. The... 
ORGANOBORON COMPOUNDS | HYDROBORATION | SOLAR-CELLS | CONJUGATED POLYMERS | SEMICONDUCTORS | ORGANIC ELECTRONICS | CHEMISTRY, ORGANIC | N BOND | GENERATION | C-H BORYLATION | 1,1-HYDROBORATION | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article