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The Journal of Organic Chemistry, ISSN 0022-3263, 11/2012, Volume 77, Issue 22, pp. 9959 - 9969
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 06/2011, Volume 133, Issue 21, pp. 8070 - 8073
The regioselective carbonylation of unactivated C(sp3)–H bonds of aliphatic amides was achieved using Ru3(CO)12 as a catalyst. The presence of a... 
HYDROGEN | ACTIVATION | CATALYTIC DEHYDROGENATION | ARYLATION | REGIOSPECIFIC FUNCTIONALIZATION | RHODIUM COMPLEXES | CHEMISTRY, MULTIDISCIPLINARY | C-H BONDS | ALKYL-GROUPS | ALKANES | Aminopyridines | Ruthenium | Chemical properties | Nitrogen | Carbon compounds
Journal Article
Chemical Science, ISSN 2041-6520, 11/2014, Volume 5, Issue 11, pp. 4339 - 4345
The direct alkenylation of C(sp(3))-H bonds was achieved by employing benzophenone and 1,2-bis(phenylsulfonyl) ethylene under photo-irradiation conditions.... 
FUNCTIONALIZATION | ORGANIC-SYNTHESIS | COUPLING REACTIONS | NATURAL-PRODUCTS | TRISUBSTITUTED VINYL TRIFLONES | SULFONES | CHEMISTRY, MULTIDISCIPLINARY | C-H BONDS | SYNTHETIC TOOLS | METAL-FREE | MOLECULAR-OXYGEN | Synthesis | Pyrroles | Chemical bonds | Derivatives | Carbon | Aliphatic compounds | Radicals | Methylene
Journal Article
Organic Letters, ISSN 1523-7060, 05/2013, Volume 15, Issue 9, pp. 2160 - 2163
A direct conversion of C(sp3)–H bonds to C(sp3)–F bonds has been developed. In this process, a catalytic N-oxyl radical generated from... 
MEDICINAL CHEMISTRY | FUNCTIONALIZATION | OXIDATION | BENZYLIC FLUORINATION | PHARMACEUTICALS | C-H FLUORINATION | ELEMENTAL FLUORINE | ORGANIC-COMPOUNDS | CHEMISTRY, ORGANIC | HYDROXYPHTHALIMIDE | MOLECULES | Hydrogen Bonding | Metals - chemistry | Halogenation | Molecular Structure | Catalysis | Carbon - chemistry | Fluorine - chemistry
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 05/2009, Volume 131, Issue 20, pp. 6898 - 6899
A new type of carbonylation of the ortho C−H bonds in aromatic amides 1, in which the pyridin-2-ylmethylamino moiety functions as a bidentate directing group,... 
ALCOHOLS | DIRECT ARYLATION | CARBON-MONOXIDE | AMINES | BENZENE-RING | COMPLEXES | ARYL | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
Organic and Biomolecular Chemistry, ISSN 1477-0520, 01/2013, Volume 11, Issue 1, pp. 164 - 169
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 06/2018, Volume 140, Issue 23, pp. 7332 - 7342
A mixed ligated amidoyttrium complex, Y­(NBn2)­(L1)­(THF)2 (8, L1 = N,N’-bis­(2,6-diisopropylphenyl)­ethylenediamine), served as a catalyst for addition of the... 
CYCLOPENTADIENYL LIGANDS | ASYMMETRIC-SYNTHESIS | AROMATIC N-HETEROCYCLES | CRYSTAL-STRUCTURES | NICKEL/LEWIS ACID CATALYSIS | SELECTIVE ALKENYLATION | NUCLEOPHILIC-ADDITION | CHEMISTRY, MULTIDISCIPLINARY | HYDRIDE COMPLEXES | ALKYL COMPLEXES | SIGMA-BOND METATHESIS
Journal Article
Organic Letters, ISSN 1523-7060, 11/2011, Volume 13, Issue 21, pp. 5928 - 5931
A general protocol for direct transformation of unreactive C(sp3)–H bonds to C(sp3)–CN bonds has been developed. The C–H activation was effected by... 
CYANIERUNG | ETHERS | NITRILE | NUCLEOPHILIC-SUBSTITUTION | C-C | CHEMISTRY, ORGANIC | METAL | OXIDATIVE CYANATION | CYANIDE | MOLECULAR-OXYGEN | Molecular Structure | Cyanides - chemistry | Free Radicals - chemistry | Hydrogen - chemistry | Photochemical Processes | Proline - chemistry
Journal Article
Chemical Science, ISSN 2041-6520, 07/2013, Volume 4, Issue 8, pp. 3118 - 3123
Journal Article
Chemistry – An Asian Journal, ISSN 1861-4728, 01/2015, Volume 10, Issue 1, pp. 120 - 123
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 03/2010, Volume 132, Issue 9, pp. 3038 - 3046
The strikingly different behavior of the ylide-like, N-heterocyclic silylene LSi: (5: L = CH[(CCH2)CMe(NAr)2]; Ar = 2,6- i PrC6H3) versus its LSi→Ni(CO)3... 
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 02/2017, Volume 139, Issue 5, pp. 1814 - 1817
Zaragozic acid C (1) was isolated as a potent squalene synthase inhibitor. The 2,8-dioxabicyclo[3.2.1]­octane core of 1 is decorated with the three... 
REARRANGEMENT | OXIDATION | ALCOHOLS | SQUALENE SYNTHASE INHIBITOR | 1,2-DIKETONES | STRATEGY | SQUALESTATINS | PHOTOCYCLIZATION | CHEMISTRY, MULTIDISCIPLINARY | STRUCTURE ELUCIDATION | PROTECTS
Journal Article
Tetrahedron, ISSN 0040-4020, 06/2013, Volume 69, Issue 22, pp. 4466 - 4472
The regioselective carbonylation of unactivated C(sp )–H bonds of aliphatic amides, using 2-pyridinylmethylamine as a directing group in conjunction with Ru... 
Chelation | Carbonylation | Ruthenium | Catalysis | C–H bond activation | C-H bond activation | C(SP)-H BONDS | ACID DERIVATIVES | ROOM-TEMPERATURE | C-H BOND | BENZENE-RING | CHEMISTRY, ORGANIC | FUNCTIONALIZED GAMMA-BUTYROLACTONES | CARBON-MONOXIDE | AROMATIC AMIDES | COUPLING REACTIONS | DIRECT CARBONYLATION | Amides
Journal Article
Synthesis, ISSN 0039-7881, 04/2013, Volume 45, Issue 7, pp. 874 - 887
Abstract A general and practical synthetic protocol for the direct transformation of unreactive C(sp 3 )–H bonds to C(sp 3 )–CN bonds has been developed. The... 
feature article | radical reaction | cyanation | C-H functionalizations | nitriles | photochemistry | CONVENIENT SYNTHESIS | FREE-RADICAL CYANATION | NUCLEOPHILIC-SUBSTITUTION | CHEMISTRY, ORGANIC | PHOTOCHEMISCHE CYANIERUNG | C-H FUNCTIONALIZATION | OXIDATIVE CYANATION | ALPHA-AMINONITRILES | CARBON NUCLEOPHILES | STRECKER REACTIONS | MOLECULAR-OXYGEN
Journal Article
European Journal of Inorganic Chemistry, ISSN 1434-1948, 12/2018, Volume 2018, Issue 44, pp. 4771 - 4778
(N^C^N)‐Pincer type bis(iminomethyl)phenylPtII complexes 1 and 2 having a macrocyclic vaulting structure consisting of deca‐ undeca‐, and dodecamethylene... 
Pincer complexes | Macrocyclic ligands | NBO Analysis | Platinum | Structure elucidation | Pt–H interactions | Infrared spectroscopy | Hydrogen atoms | Nuclear magnetic resonance--NMR | Mass spectrometry | Hydrogen bonding
Journal Article