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The Journal of Chemical Physics, ISSN 0021-9606, 04/2016, Volume 144, Issue 15, p. 154307
The reductive conversion of CO2 into industrial products (e.g., oxalic acid, formic acid, methanol) can occur via aqueous CO2 − as a transient intermediate.... 
Water | Solvents | Water chemistry | Zero point energy | Carbon dioxide | Substitution reactions | Raman spectroscopy | Charge distribution | Acid base equilibrium | Electron states | Anions | Solvation | Oxalic acid | Formic acid | Radiolysis | RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEAR CHEMISTRY
Journal Article
The Journal of Chemical Physics, ISSN 0021-9606, 03/2019, Volume 150, Issue 9, p. 094304
Journal Article
Journal of Chemical Physics, ISSN 0021-9606, 04/2016, Volume 144, Issue 15
The reductive conversion of CO{sub 2} into industrial products (e.g., oxalic acid, formic acid, methanol) can occur via aqueous CO{sub 2}{sup −} as a transient... 
ANIONS | OXALIC ACID | PERTURBATION THEORY | INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY | FORMIC ACID | RADICALS | CARBON DIOXIDE | RAMAN SPECTROSCOPY | EXPERIMENTAL DATA | SOLVATION | COBALT | ISOTOPIC EXCHANGE
Journal Article
Nature Communications, ISSN 2041-1723, 05/2017, Volume 8, Issue 1, p. 15435
The nature and extent of hydrogen bonding in water has been scrutinized for decades, including how it manifests in optical properties. Here we report vacuum... 
VAPOR | H2O | DISSOCIATION | 1ST ABSORPTION-BAND | MULTIDISCIPLINARY SCIENCES | LIQUID WATER | DIMERS | PHOTODISSOCIATION | Chemical physics | INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY | Physical chemistry
Journal Article
Review of Scientific Instruments, ISSN 0034-6748, 01/2015, Volume 86, Issue 1, p. 015102
We present the design and characteristics of an ultrathin flow cell optimized for vacuum ultraviolet transmission spectroscopy experiments on supercritical... 
INSTRUMENTS & INSTRUMENTATION | PHYSICS, APPLIED | Variable thickness | Solvents | Ultraviolet spectroscopy | Carbon dioxide | Metal vapors | Foils | Critical point | Micrometers | Vapor deposition | Supercritical fluids | Sapphire | Spectrum analysis | Absorption spectra
Journal Article
JOURNAL OF PHYSICAL CHEMISTRY LETTERS, ISSN 1948-7185, 05/2019, Volume 10, Issue 9, pp. 2220 - 2226
The partial molar volume of the hydrated electron was investigated with pulse radiolysis and transient absorption by measuring the pressure dependence of the... 
ATOMIC-HYDROGEN | MATERIALS SCIENCE, MULTIDISCIPLINARY | GAMMA-RADIOLYSIS | HIGH-TEMPERATURE | PHYSICS, ATOMIC, MOLECULAR & CHEMICAL | CHEMISTRY, PHYSICAL | HIGH-PRESSURES | NANOSCIENCE & NANOTECHNOLOGY | SOLVATION | NONCAVITY MODELS | RESONANCE | PULSE-RADIOLYSIS | WATER | LIQUIDS | Science & Technology - Other Topics | Chemistry | Materials Science | Physics
Journal Article
Journal of Chemical Physics, ISSN 0021-9606, 07/2013, Volume 139, Issue 1, p. 014302
Journal Article
Journal of Chemical Physics, ISSN 0021-9606, 01/2013, Volume 138, Issue 4, p. 044506
The time-resolved Raman observation of a prototype of the hetero-atom three electron bonds (-X-OH) that often form on encounter of the OH radical with chemical... 
SPECTROSCOPY | RESOLVED RESONANCE RAMAN | PROTON REACTIVITY | BONDS | PHYSICS, ATOMIC, MOLECULAR & CHEMICAL | WASSRIGER LOSUNG | ADDUCTS | SPECTRA | CATION | ATMOSPHERE | Spectrum Analysis, Raman | Quantum Theory | Oxidation-Reduction | Hydroxyl Radical - chemistry | Sulfides - chemistry | Water - chemistry | Dimethyl | Sulfides | Encounters | Chemical bonds | Biochemistry | Mathematical models | Gas phases | Radicals
Journal Article
The Journal of Physical Chemistry A, ISSN 1089-5639, 03/2007, Volume 111, Issue 10, pp. 1869 - 1878
The rate constants for the reactions of phenol with the hydroxyl radical (OH•) in water have been measured from room temperature to 380 °C using electron pulse... 
OXIDATION | AQUEOUS-SOLUTIONS | BENZENE | TEMPERATURE-DEPENDENCE | GAS-PHASE REACTION | PULSE-RADIOLYSIS | KINETICS | RATE CONSTANTS | PHYSICS, ATOMIC, MOLECULAR & CHEMICAL | CHEMISTRY, PHYSICAL | OH RADICALS | HYDRATED ELECTRONS | Phenols | Hydroxides | Chemical properties | Absorption spectra | Radicals (Chemistry) | Analysis
Journal Article
Nuclear Inst. and Methods in Physics Research, A, ISSN 0168-9002, 01/2013, Volume 698, pp. 44 - 48
We describe the design, characterization, and implementation of a vacuum ultraviolet (VUV) monochromator for use in filtering stray and scattered light from... 
Vacuum ultraviolet | Spectroscopy | Synchrotron | Monochromator | Scattered light | Stray light | INSTRUMENTS & INSTRUMENTATION | NUCLEAR SCIENCE & TECHNOLOGY | PHYSICS, PARTICLES & FIELDS | Nuclear radiation | Spectrum analysis | Particle accelerators | Beams (radiation) | Filtration | Filtering | Detectors | Dynamic range | Monochromators | Ultraviolet
Journal Article
JOURNAL OF PHYSICAL CHEMISTRY A, ISSN 1089-5639, 03/2007, Volume 111, Issue 10, pp. 1835 - 1843
The rate constant for the self-recombination of hydroxyl radicals ((OH)-O-center dot) in aqueous solution giving H2O2 product has been measured from 150 to 350... 
ELEVATED-TEMPERATURES | HIGH-PRESSURE RANGE | AQUEOUS-SOLUTIONS | TEMPERATURE-DEPENDENCE | PULSE-RADIOLYSIS | RATE CONSTANTS | SUPERCRITICAL WATER | PHYSICS, ATOMIC, MOLECULAR & CHEMICAL | INDUCED FLUORESCENCE MEASUREMENTS | CHEMISTRY, PHYSICAL | PEROXIDE POTENTIAL SURFACE | ALIPHATIC ALCOHOL RADICALS
Journal Article
The Journal of Physical Chemistry B, ISSN 1520-6106, 05/2012, Volume 116, Issue 21, pp. 6215 - 6224
Journal Article
Journal Article
Israel Journal of Chemistry, ISSN 0021-2148, 03/2014, Volume 54, Issue 3, pp. 302 - 315
The .OH radical induced oxidation of nicotine was studied using pulse radiolysis techniques from pH 1 to 13.6. Theoretical calculations were used to help... 
reaction mechanisms | density functional calculations | electron transfer | radicals | kinetics | Nuclear radiation | Hydrogen | Oxidation-reduction reaction | Radiolysis | Chemical properties | Hydrogen-ion concentration | Nicotine
Journal Article
The journal of physical chemistry. A, ISSN 1089-5639, 08/2007, Volume 111, Issue 32, p. 7777
Yields for H2, H(.) atom, and hydrated electron production in beta/gamma radiolysis of water have been measured from room temperature up to 400 degrees C on a... 
Journal Article
JOURNAL OF PHYSICAL CHEMISTRY A, ISSN 1089-5639, 02/2010, Volume 114, Issue 5, pp. 2142 - 2150
Pulse radiolysis experiments published several years ago (J. Phys. Chem. A, 2002, 106, 2430) raised the possibility that the carbonate radical formed from... 
HYDROXYL RADICALS | ACID-BASE-EQUILIBRIUM | PULSE-RADIOLYSIS | FLASH-PHOTOLYSIS | SUPERCRITICAL WATER | HIGH-TEMPERATURE | PHYSICS, ATOMIC, MOLECULAR & CHEMICAL | CHEMISTRY, PHYSICAL | HYDROGEN-PEROXIDE | HYDRATED ELECTRONS | CYCLIC HYDRAZIDES | AQUEOUS-SOLUTION
Journal Article
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