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reactivity (11) 11
chemistry, inorganic & nuclear (8) 8
silicon (8) 8
structural-characterization (8) 8
chemistry (7) 7
ligands (7) 7
chemistry, multidisciplinary (6) 6
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activation (5) 5
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n ligands (5) 5
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fester zustand (4) 4
kristallstrukturanalyse (4) 4
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spectroscopy (4) 4
bond (3) 3
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pentacoordinate silicon complexes (2) 2
selenium (2) 2
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skeletons (2) 2
stable silylenes (2) 2
stereoisomerism (2) 2
tellurium (2) 2
1,3-butadiene (1) 1
2,4,6-tri-tert-butyl-1,3,5-triphosphabenzene (1) 1
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aziridines - chemistry (1) 1
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Angewandte Chemie International Edition, ISSN 1433-7851, 07/2012, Volume 51, Issue 28, pp. 7020 - 7023
Well looked‐after: Reductive HCl elimination of the λ6‐silicon(IV) complex 1 leads to the λ3‐silicon(II) species 2, a novel type of donor‐stabilized silylene.... 
N ligands | tungsten | silicon compounds | coordination chemistry | silylenes | THERMALLY STABLE SILYLENES | CHLOROSILYLENE | N-HETEROCYCLIC SILYLENE | REACTIVITY | STRUCTURAL-CHARACTERIZATION | BASE-STABILIZED DICHLOROSILYLENE | CHEMISTRY, MULTIDISCIPLINARY | CARBONYL-COMPLEXES | CHEMISTRY | HOMOLOGS | SKELETONS | Ligands
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 09/2014, Volume 20, Issue 39, pp. 12411 - 12415
Reaction of the donor‐stabilized silylene 1 (which is three‐coordinate in the solid state and four‐coordinate in solution) with BEt3 and BPh3 leads to the... 
Lewis acids | silicon | bonding analysis | boron | coordination chemistry | Lewis bases | REACTIVITY | STRUCTURAL-CHARACTERIZATION | CHEMISTRY, MULTIDISCIPLINARY | SILYLENE | METAL-CARBONYL-COMPLEXES | LIGAND | DENSITY-FUNCTIONAL THEORY | BOND | PENTACOORDINATE SILICON(IV) COMPLEXES | Crystal structure | Silicon compounds | Lewis acid | Solid state | Spectroscopy | Quantum chemistry | Formations | Bonding
Journal Article
European Journal of Inorganic Chemistry, ISSN 1434-1948, 10/2014, Volume 2014, Issue 30, pp. 5099 - 5102
Journal Article
European Journal of Inorganic Chemistry, ISSN 1434-1948, 12/2013, Volume 2013, Issue 34, pp. 5821 - 5825
The first donor‐stabilized silylenes with guanidinato ligands, compounds 4 and 6, were synthesized and structurally characterized in the solid state and in... 
Silylenes | Silicon | Coordination modes | N li­gands | N ligands | COMPLEXES | REACTIVITY | CHEMISTRY, INORGANIC & NUCLEAR | AMIDINATE | GERMANIUM(II) | BIDENTATE | CHEMISTRY | METAL COORDINATION | SILICON(II) | Ligands | Diffraction | Crystals | Single crystals | Solid state | Synthesis | X ray diffraction
Journal Article
Dalton Transactions, ISSN 1477-9226, 10/2011, Volume 40, Issue 38, pp. 9844 - 9857
Journal Article
Chemistry: A European Journal, ISSN 0947-6539, 2014, Volume 20, Issue 50, pp. 16462 - 16466
Reaction of the donor-stabilized silylene 1 (which is three-coordinate in the solid state and four-coordinate in solution) with [HMCp(CO) 
density functional calculations | cations | silicon | N ligands | transition metals | N ligands | ACTIVATION | N-HETEROCYCLIC SILYLENE | REACTIVITY | NEUTRAL 6-COORDINATE | CHEMISTRY, MULTIDISCIPLINARY | BIDENTATE | 5-COORDINATE SILICON(IV) COMPLEXES | CHEMISTRY | LIGAND | DENSITY-FUNCTIONAL THEORY
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 12/2012, Volume 18, Issue 51, pp. 16288 - 16291
Silylenes: Reaction of the donor‐stabilized silylene 1 with elemental sulfur, selenium, or tellurium led to the formation of 2 a–c [SiN4X skeletons (X=S, Se,... 
tellurium | sulfur | selenium | silicon compounds | silylenes | SERIES | COMPOUND | REACTIVITY | STRUCTURAL-CHARACTERIZATION | THIOESTERS | CHEMISTRY, MULTIDISCIPLINARY | KINETICALLY STABILIZED SILANETHIONE | LIGANDS | BIDENTATE
Journal Article
DALTON TRANSACTIONS, ISSN 1477-9226, 2011, Volume 40, Issue 38, pp. 9844 - 9857
Journal Article
Dalton Transactions, ISSN 1477-9226, 10/2010, Volume 39, Issue 39, pp. 9401 - 9413
The novel neutral hexacoordinate bis(benzamidinato) silicon(IV) complexes 1-10 (SiN4X2 skeletons; X = F, Cl, Br, C, N, S, Se) were synthesised and... 
SKELETONS | STRUCTURAL-CHARACTERIZATION | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Inorganic Chemistry, ISSN 0020-1669, 10/2013, Volume 52, Issue 19, pp. 11593 - 11599
Reaction of the donor-stabilized silylene 1 with [Cr(CO)6], [Mo(CO)6], [W(CO)6], or [Fe(CO)5] leads to the formation of the transition-metal silylene complexes... 
CARBONYL-COMPLEXES | BASE-STABILIZED SILYLENE | DIVALENT SILICON | STABLE SILYLENES | COVALENT RADII | N-HETEROCYCLIC SILYLENE | REACTIVITY | STRUCTURAL-CHARACTERIZATION | CRYSTAL-STRUCTURES | BIS(SILYLENE)IRON | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Organometallics, ISSN 0276-7333, 11/2014, Volume 33, Issue 21, pp. 6141 - 6148
Reaction of the donor-stabilized silylene 1 (which is three-coordinate in the solid state and four-coordinate in solution) with organic 1,3-dienes... 
KETONES | ACTIVATION | STABLE SILYLENE | 1,3-BUTADIENE | BONDS | REACTIVITY | CHEMISTRY | CHEMISTRY, ORGANIC | SILICON(IV) COMPLEXES | BUTA-1,3-DIENE | 2,4,6-TRI-TERT-BUTYL-1,3,5-TRIPHOSPHABENZENE | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Chemistry: A European Journal, ISSN 0947-6539, 12/2014, Volume 20, Issue 50, pp. 16462 - 16466
Reaction of the donor-stabilized silylene 1 (which is three-coordinate in the solid state and four-coordinate in solution) with [HMCp(CO) sub(3)] (M=Mo, W;... 
Solid state | Spectroscopy | Cationic | Spectroscopic analysis | Joining | Formations | Acetic acid | Crystal structure
Journal Article
Chemistry, ISSN 0947-6539, 12/2012, Volume 18, Issue 51, p. 16288
  Silylenes: Reaction of the donor-stabilized silylene 1 with elemental sulfur, selenium, or tellurium led to the formation of 2a-c [SiN(4)X skeletons (X = S,... 
Journal Article
Chemistry: A European Journal, ISSN 0947-6539, 12/2012, Volume 18, Issue 51, pp. 16288 - 16291
Silylenes: Reaction of the donor-stabilized silylene 1 with elemental sulfur, selenium, or tellurium led to the formation of 2a-c [SiN sub(4)X skeletons (X=S,... 
Formations | Selenium | Sulfur | Tellurium
Journal Article
ISSN 1477-9226, 9/2010, Volume 39, Issue 39, pp. 941 - 9413
The novel neutral hexacoordinate bis(benzamidinato)silicon (iv) complexes 1-10 ( Si N 4 X 2 skeletons; X = F, Cl, Br, C, N, S, Se) were synthesised and... 
Journal Article
Organometallics, ISSN 0276-7333, 07/2015, Volume 34, Issue 14, pp. 3532 - 3537
Transverse-field muon spin rotation (TF-mu SR) spectra have been obtained for muoniated free. radicals formed by positive muon irradiation of a series of... 
DENSITY | ISOTOPES | ROTATION | SILYLENE | HYDROGEN | REACTIVITY | CHEMISTRY, ORGANIC | ATOMS | BASIS-SETS | HYPERFINE | ORGANIC FREE-RADICALS | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
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