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Inorganic Chemistry, ISSN 0020-1669, 10/2015, Volume 54, Issue 20, pp. 9833 - 9844
When n-hexane solutions of an excess of sodium bis­(trimethylsilyl)­amide (NaHMDS) are combined with cesium halide... 
Journal Article
Acta Crystallographica Section E: Structure Reports Online, ISSN 1600-5368, 12/2012, Volume 68, Issue 12, pp. m1468 - M1468
The title compound, [Na-2(C6H18NSi2)(2)(C6H16N2)] n, was found to consist of dimeric [Na(NSiMe3)(2... 
mean ω(C-C) = 0.001 Å | wR factor = 0.067 | data-to-parameter ratio = 25.5 | single-crystal X-ray study | R factor = 0.023 | T = 123 K | CRYSTALLOGRAPHY
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 2017, Volume 56, Issue 23, pp. 6632 - 6635
Combining alkali‐metal‐mediated metalation (AMMM) and N‐heterocyclic carbene (NHC) chemistry, a novel C... 
metalation | mixed-metal chemistry | alkali metals | C−N activation | N-heterocyclic carbenes | COORDINATION CHEMISTRY | C-N activation | COMPLEXES | PLATFORMS | REACTIVITY | LITHIATION | CHEMISTRY, MULTIDISCIPLINARY | Heterocyclic compounds | Polarity | Ligands | Metals | Reagents | Intermediates
Journal Article
Inorganic Chemistry, ISSN 0020-1669, 10/2013, Volume 52, Issue 20, pp. 12023 - 12032
...(N,N-dimethyl-2-aminoethyl)­amine, [N­(CH2CH2NMe2)3, Me6TREN]. Molecular structure analysis by X-ray crystallography establishes that the cation... 
COORDINATION CHEMISTRY | BENZYL COMPLEXES | MEDIATED ZINCATION | SODIUM | ALKYLLITHIUM COMPOUNDS | LITHIUM DIISOPROPYLAMIDE | X-RAY | CRYSTAL-STRUCTURES | ORGANOLITHIUM COMPOUNDS | TMP-ZINCATE | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Angewandte Chemie, ISSN 0044-8249, 2017, Volume 129, Issue 23, pp. 6732 - 6735
Combining alkali‐metal‐mediated metalation (AMMM) and N‐heterocyclic carbene (NHC) chemistry, a novel C... 
Gemischtmetallische Systeme | N-Heterocyclische Carbene | Metallierung | Alkalimetalle | C-N-Aktivierung | Heterocyclic compounds
Journal Article
Dalton transactions : an international journal of inorganic chemistry, ISSN 1477-9226, 2015, Volume 44, Issue 12, pp. 5875 - 5887
The cleave and capture capacity of various bimetallic amido–alkyl mixtures is illustrated through reaction with the deprotonation sensitive ,... 
SODIUM TMP-ZINCATE | MEDIATED ZINCATION AMMZN | CAMBRIDGE STRUCTURAL DATABASE | CRYSTAL-STRUCTURE | BETA-PHENYLETHYLAMINES | DIRECTED ORTHO-METALATION | ISOQUINOLINE ALKALOIDS | RING-STACKING | META-METALATION | LITHIUM | CHEMISTRY, INORGANIC & NUCLEAR | Balancing | Sodium | Cationic | X-rays | Lithium | Cleavage | Bonding | Crystal structure
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 05/2017, Volume 56, Issue 22, pp. 6343 - 6343
... 6088 ff. that an N site deprotonation RIXS signature of 2‐TP, established in synchrotron measurements, was identified on a femtosecond timescale using the free‐electron‐laser LCLS... 
RIXS (resonant inelastic X-ray scattering) | protonation | selective bond cleavage | photochemistry | nitrogen | Femtosecond | X-ray scattering | Deformation | Quantum chemistry | Inelastic scattering | Photoexcitation
Journal Article
INORGANIC CHEMISTRY, ISSN 0020-1669, 10/2015, Volume 54, Issue 20, pp. 9833 - 9844
When n-hexane solutions of an excess of sodium bis(trimethylsilyl)amide (NaHMDS) are combined with cesium halide (halide = Cl, Br... 
AGOSTIC INTERACTIONS | CRYSTAL-STRUCTURE | MOLECULAR-STRUCTURES | REACTIVITY | METAL | HEXAMETHYLDISILAZIDE | LITHIUM DIISOPROPYLAMIDE LDA | MAGNESIUM COMPLEXES | CHLORIDE | AMIDES | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 03/2008, Volume 130, Issue 12, pp. 3754 - 3755
We report the crystal structure of the thiolate gold nanoparticle [TOA+][Au25(SCH2CH2Ph)18 -], where TOA+ = N(C8H17)4 +. The crystal structure reveals three types of gold atoms... 
STABILITY | RESOLUTION | AU-25 CLUSTERS | CHEMISTRY | SCALE | CHEMISTRY, MULTIDISCIPLINARY | MASS-SPECTROMETRY | Gold - chemistry | Nanoparticles - chemistry | Models, Molecular | Crystallography, X-Ray | Ligands | Sulfhydryl Compounds - chemistry | Organogold Compounds - chemistry | Nanoparticles | Gold compounds | Thiols | Optical properties | Analysis | Chemical properties | Structure | Chemical synthesis
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 10/2016, Volume 22, Issue 42, pp. 14968 - 14978
Journal Article