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Angewandte Chemie International Edition, ISSN 1433-7851, 05/2014, Volume 53, Issue 21, pp. 5356 - 5360
The development of visible‐light‐induced photocatalysts for chemoselective functional group transformations has received considerable attention.... 
amines | cyanation | dehydrogenation | photoredox catalysis | polyoxometalates | Cerium | Automated teller machines | Catalysis | Sole | Amines | Oxidants | Dehydrogenation | Photocatalysis | Oxidizing agents | Irradiation | Charge transfer | Photocatalysts
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 03/2012, Volume 51, Issue 10, pp. 2434 - 2437
An Ag4 diamond is encapsulated by silicotungstate ligands in TBA8[Ag4(DMSO)2(γ‐H2SiW10O36)2]⋅2 DMSO⋅2 H2O (Ag4; DMSO=dimethyl sulfoxide,... 
oxidation | cluster compounds | silver | polyoxometalates | synthetic methods
Journal Article
ISSN 1477-9226, 5/2019, Volume 48, Issue 21, pp. 7138 - 7143
The host-guest interaction between a half spherical-type dodecavanadate ( V12 ) and a neutral molecule guest was evaluated by monitoring the flip of a VO 5... 
Journal Article
Chemistry – An Asian Journal, ISSN 1861-4728, 08/2017, Volume 12, Issue 15, pp. 1909 - 1914
A dodecavanadate, [V12O32]4−, is an inorganic bowl‐type host with a cavity entrance with a diameter of 4.4 Å in the optimized structure. Linear, bent, and... 
vanadium | host–guest systems | structure elucidation | anions | polyoxometalates | MIXED-VALENCE | SPECTROSCOPY | POLYOXOVANADATE | BUILDING-BLOCKS | GUEST | REACTIVITY | METAL-ORGANIC FRAMEWORK | IONS | CLUSTER | CHEMISTRY, MULTIDISCIPLINARY | INCLUSION COMPLEX | Nuclear magnetic resonance spectroscopy | Analysis
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 12/2018, Volume 57, Issue 49, pp. 16051 - 16055
Design of cavities for a target molecule and the elucidation of the corresponding host–guest interactions are important for molecular manipulation. A discrete... 
host–guest systems | polyoxometalates | polytopal rearrangements | bowl structures | host-guest systems | RECOGNITION | ION | BOTTOM | MAGNETIC-RESONANCE SPECTROSCOPY | REARRANGEMENTS | CHEMISTRY, MULTIDISCIPLINARY | CLUSTER SHELLS | INCLUSION | SELECTIVITY | Pyramids | Vacuum | Entrances | Carbon dioxide | Vapors | Dichloromethane | Dichloroethane | Insertion | Holes | Methylene chloride | Electrostatic properties
Journal Article
New Journal of Chemistry, ISSN 1144-0546, 11/2019, Volume 43, Issue 45, pp. 17703 - 17710
A mixed-valence hexamanganese complex, [MnIII4MnIV2O6(V4O13)2(MeCO2)2]6− [1(MeCO2)], has been synthesized by the reaction of a dimanganese precursor,... 
Journal Article
Chemistry Letters, ISSN 0366-7022, 01/2017, Volume 46, Issue 9, p. 1406
By the oxidation of decavanadate {n-Bu4N}4[V10O26] in the presence of F− and Pd(NO3)2 in dimethyl sulfoxide (DMSO), a palladium-supported fluoride-incorporated... 
Nuclear magnetic resonance--NMR | Dimethyl sulfoxide | Oxidation | Palladium | Fluorides
Journal Article
European Journal of Inorganic Chemistry, ISSN 1434-1948, 01/2019, Volume 2019, Issue 3-4, pp. 529 - 533
By the reaction of Y(NO3)3 and {Et4N}[VO3] in organic media, yttrium‐containing polyoxovanadates are synthesized and classified into sandwich‐type... 
Cubanes | Polyoxometalates | Polyoxovanadates | Yttrium | Vanadates | DESIGN | COMPLEXES | FRAMEWORKS | CHEMISTRY, INORGANIC & NUCLEAR | CARBONATE | CLUSTERS | POLYOXOMETALATE | LANTHANIDE | Additives | Cages | Cations | Cubane | Chemical synthesis | Acetonitrile
Journal Article
New Journal of Chemistry, ISSN 1144-0546, 01/2019, Volume 43, Issue 45, pp. 17703 - 17710
A mixed-valence hexamanganese complex, [Mn4IIIMn2IVO6(V4O13)2(MeCO2)2]6− [1(MeCO2)], has been synthesized by the reaction of a dimanganese precursor,... 
Benzoates | Valence | Magnetic permeability | Acetonitrile | Oxidation | Derivatives | Cubane | Chemical synthesis | Crystallography | Functional groups | Manganese
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 08/2010, Volume 49, Issue 35, pp. 6096 - 6100
Zinc in: Polyoxometalate 1 reacts with Zn2+ ions in acetone to form a novel sandwich‐type POM 2 in almost quantitative yield. The H2O2‐based oxidation of... 
oxidation | alcohols | homogeneous catalysis | zinc | polyoxometalates | Polyoxometalates | Oxidation | Homogeneous catalysis | Zinc | Alcohols | POLYOXOMETALATE COMPLEXES | OLEFIN EPOXIDATION | SUBSTITUTED SILICOTUNGSTATE | 30-PERCENT HYDROGEN-PEROXIDE | CHEMISTRY, MULTIDISCIPLINARY | TRANSITION-METAL | STRUCTURAL CONTROL | RECYCLABLE CATALYST | MAGNETIC-PROPERTIES | MOLECULAR-OXYGEN
Journal Article
Inorganic Chemistry, ISSN 0020-1669, 09/2010, Volume 49, Issue 18, pp. 8194 - 8196
Two novel sandwich-type silicotungstates, TBA8[{Zn2W(O)O3}2H4{α-SiW9O33}2]·5H2O (α-Zn4; TBA = tetra-n-butylammonium) and TBA8[{Zn2W(O)O3}2H4{β-SiW9O33}2]·7H2O... 
Temperature | Oxidation-Reduction | Organometallic Compounds - chemical synthesis | Molecular Conformation | Models, Molecular | Organometallic Compounds - chemistry | Tungsten Compounds - chemistry | Zinc - chemistry | Isomerism
Journal Article
DALTON TRANSACTIONS, ISSN 1477-9226, 06/2019, Volume 48, Issue 21, pp. 7138 - 7143
The host-guest interaction between a half spherical-type dodecavanadate (V12) and a neutral molecule guest was evaluated by monitoring the flip of a VO5 unit... 
GUEST | RECOGNITION | REDUCTION | CLUSTER SHELLS | WATER | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
ISSN 1477-9226, 5/2016, Volume 45, Issue 18, pp. 7563 - 7569
Chloride-incorporated dodecavanadates show two distinct structures of the monoprotonated-form [HV 12 O 32 (Cl)] 4− ( closed-V12 ) with a spherical... 
Journal Article
Dalton Transactions, ISSN 1477-9226, 05/2016, Volume 45, Issue 18, pp. 7563 - 7569
Chloride-incorporated dodecavanadates show two distinct structures of the monoprotonated-form [HV sub(12)O sub(32)(Cl)] super(4-) (closed-V12) with a spherical... 
Time dependence | Mathematical analysis | Chlorides | Reagents | Exact solutions | Holes | Cations | Transformations
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 04/2008, Volume 130, Issue 16, pp. 5472 - 5478
The di- and tetranuclear metal sandwich-type silicotungstates of Cs10[(γ-SiW10O36)2{Zr(H2O)}2(μ-OH)2]·18H2O (Zr2, monoclinic, C2/c (No. 15), a = 25.3315(8) Å,... 
Silicones - chemistry | Cyclization | Models, Chemical | Oxides - chemistry | Zirconium - chemistry | Oxygen - chemistry | Catalysis | Tungsten Compounds - chemical synthesis | Binding Sites | Dimerization | Hafnium - chemistry
Journal Article
International Journal of Hematology, ISSN 0925-5710, 2/2015, Volume 101, Issue 2, pp. 133 - 139
Journal Article