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Journal of the American Chemical Society, ISSN 0002-7863, 1900, Volume 137, Issue 13, pp. 4534 - 4542
Mechanistic investigations on the Cp*Rh­(III)-catalyzed direct C–H amination reaction led us to reveal the new utility of 1,4,2-dioxazol-5-one and its... 
SULFONYL AZIDES | AROMATIC KETONES | COUPLING REACTIONS | NATURAL-PRODUCTS | INTERMOLECULAR AMIDATION | ATOM-TRANSFER | N BOND FORMATION | SYNTHETIC ROUTE | CARBON-NITROGEN BONDS | FORMING REACTIONS | CHEMISTRY, MULTIDISCIPLINARY | Chemical reactions | Ruthenium | Chemical properties | Research
Journal Article
Organic Letters, ISSN 1523-7060, 01/2016, Volume 18, Issue 2, pp. 232 - 235
The rhodium­(III)-catalyzed direct C–H functionalization of azobenzenes with ethyl glyoxalate and aryl glyoxals is described. This protocol provides the facile... 
FUNCTIONALIZATION | AMIDATION | INDAZOLES | CHEMISTRY, ORGANIC | OLEFINS | N BOND FORMATION | ARYL | 1H-INDAZOLES | CLEAVAGE | ALKENYLATION | Azo Compounds - chemistry | Glyoxal - chemistry | Indazoles - chemistry | Cyclization | Indazoles - chemical synthesis | Ketones - chemistry | Molecular Structure | Catalysis | Glyoxal - analogs & derivatives | Rhodium - chemistry | Aldehydes - chemistry
Journal Article
Chemical Communications, ISSN 1359-7345, 2017, Volume 53, Issue 2, pp. 384 - 387
Rh(0)/Rh(iii) core–shell nanoparticles were prepared by surface oxidation of Rh nanoparticles with N-bromosuccinimide. They were employed as heterogeneous... 
Journal Article
The Journal of Organic Chemistry, ISSN 0022-3263, 04/2018, Volume 83, Issue 7, pp. 4070 - 4077
The rhodium­(III)-catalyzed C–H functionalization followed by intramolecular annulation reactions between azobenzenes and sulfoxonium ylides is described. This... 
H BOND ACTIVATION | FUNCTIONALIZATION | CATALYSIS | DESIGN | AROMATIC AZO-COMPOUNDS | ANILINES | CHEMISTRY, ORGANIC | OLEFINS | INHIBITORS | CYCLIZATION | OXYGEN-ATOM
Journal Article
Chemical communications (Cambridge, England), ISSN 1359-7345, 10/2017, Volume 53, Issue 81, pp. 11197 - 11200
The rhodium(iii)-catalyzed C(sp )-H amination reaction of 8-methylquinolines and azodicarboxylates is described. A cationic rhodium catalyst in the presence of... 
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 03/2011, Volume 133, Issue 11, pp. 3780 - 3783
A new catalytic protocol for the regioselective direct arylation of quinoline derivatives at the 8-position has been developed. The reaction is catalyzed by a... 
ORGANIC-SYNTHESIS | C-H BOND | RH(I)-CATALYZED DIRECT ARYLATION | DIRECT AMINATION | AROMATIC HETEROCYCLES | DIRHODIUM(II) COMPLEXES | CARBENE COMPLEXES | HETEROAROMATIC-COMPOUNDS | CHEMISTRY, MULTIDISCIPLINARY | ARYLBORONIC ACIDS | CATALYZED DIRECT ARYLATION | Quinoline | Arylation | Chemical properties | Rhodium | Analysis | Electric properties
Journal Article
Chemical Engineering Research and Design, ISSN 0263-8762, 01/2019, Volume 141, pp. 455 - 463
[Display omitted] •The physical properties were almost the same regardless of preparation method.•Metal dispersion is closely related to synthesis method.•The... 
Incipient wetness | Impregnation | Rhodium | N2O decomposition | Citric acid | γ-Alumina pellet | O decomposition | NITROUS-OXIDE | ENGINEERING, CHEMICAL | H2O | O-2 | gamma-Alumina pellet
Journal Article
The Journal of Organic Chemistry, ISSN 0022-3263, 02/2015, Volume 80, Issue 3, pp. 1818 - 1827
Journal Article
Fuel, ISSN 0016-2361, 01/2015, Volume 139, pp. 314 - 320
[Display omitted] •S/C ratio and temperature influenced steam-biogas reforming over the Pd–Rh/metal foam catalyst.•CH4 conversion was affected by both steam... 
Optimum reforming condition | Steam reforming of biogas | S/C ratio | Reaction temperature | Pd–Rh/(CeZrO2–Al2O3) catalyst | Pd-Rh/(CeZrO | catalyst | Al | NICKEL CONTENT | ENGINEERING, CHEMICAL | METHANE | ENERGY & FUELS | Pd-Rh/(CeZrO2-Al2O3) catalyst | Palladium catalysts | Palladium | Biogas | Biomass energy
Journal Article
Tetrahedron Letters, ISSN 0040-4039, 08/2015, Volume 56, Issue 32, pp. 4678 - 4682
[Display omitted] The rhodium(III)-catalyzed ortho-C–H functionalization of 2-arylbenzo[d]thiazoles with α-diazo esters is described. This transformation... 
C–H activation | Diazo ester | Rhodium | Alkylation | 2-Arylbenzothiazole | C-H activation | PALLADIUM | ACTIVATION | CHEMISTRY, ORGANIC | BOND FORMATION | N-TOSYLHYDRAZONES | FUNCTIONALIZATION | POSSIBLE ANTAGONIST | 2-AMINO-6-TRIFLUOROMETHOXY BENZOTHIAZOLE | ORTHO-ARYLATION | AMINO-ACID NEUROTRANSMISSION | ALKENYLATION
Journal Article
PHYSICAL REVIEW LETTERS, ISSN 0031-9007, 12/2019, Volume 123, Issue 24, p. 246001
Bimetallic catalysts can undergo segregation or redistribution of the metals driven by oxidizing and reducing environments. Bragg coherent diffraction imaging... 
PLATINUM | OXIDES | PHYSICS, MULTIDISCIPLINARY | STRAIN | Composition | Radial distribution | Catalysts | Electrocatalysts | Nanoparticles | Nanoalloys | Bimetals | Diffraction | Rhodium | Gas flow | Imaging | Rhodium base alloys | Oxidation | Catalysis | Physics - Materials Science | MATERIALS SCIENCE
Journal Article
Chemical Science, ISSN 2041-6520, 08/2015, Volume 6, Issue 8, pp. 4479 - 4483
We describe a Rh-catalyzed desymmetrization of all-carbon quaternary centers from alpha,alpha-bis(allyl)aldehydes by a cascade featuring isomerization and... 
ALKENE | ASYMMETRIC-SYNTHESIS | ENANTIOSELECTIVE SYNTHESIS | 4-PENTENALS | INTRAMOLECULAR HYDROACYLATION | CONSTRUCTION | BOND ACTIVATION | ALDEHYDES | DIRECT INTERMOLECULAR HYDROACYLATION | CHEMISTRY, MULTIDISCIPLINARY | CYCLOPENTANONES | Olefins | Isomerization | Cascades | Ligands | Activation | Formations | Bonding
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 02/2008, Volume 130, Issue 6, pp. 1824 - 1825
N-fused pentaphyrins (NFP5), stable forms of meso-aryl pentaphyrins, are interesting platforms to realize Hückel aromaticity, nonaromaticity, and Möbius... 
CHEMISTRY, MULTIDISCIPLINARY | PORPHYRIN | Technology application | Nuclear magnetic resonance spectroscopy | Chemical properties | Structure | Aromatic compounds | Pyrrole
Journal Article
NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION B-BEAM INTERACTIONS WITH MATERIALS AND ATOMS, ISSN 0168-583X, 08/2018, Volume 429, pp. 1 - 8
Journal Article
Angewandte Chemie - International Edition, ISSN 1433-7851, 09/2015, Volume 54, Issue 37, pp. 10975 - 10979
The first CH bond activation with pyridotriazoles as coupling partners is presented using a Rh-III catalyst. The pyridotriazoles can be used as new carbene... 
fluorophore | C-H activation | carbene | rhodium | triazole | BOND FUNCTIONALIZATION | TERMINAL ALKYNES | TRANSANNULATION | DIAZO-COMPOUNDS | DIRECT ARYLATIONS | CARBENE MIGRATORY INSERTION | CHEMISTRY, MULTIDISCIPLINARY | N-TOSYLHYDRAZONES | PROBES | 1,2,3-TRIAZOLES
Journal Article
The Journal of Organic Chemistry, ISSN 0022-3263, 10/2016, Volume 81, Issue 20, pp. 9878 - 9885
The rhodium­(III)-catalyzed direct C–H functionalization of various indolines with 1,4,2-dioxazol-5-ones as new amidating agents is described. This... 
CANCER-CELLS | AGENT | PALLADIUM | CATALYSIS | ACTIVATION | C-7 POSITION | MICROTUBULE | 7-SUBSTITUTED INDOLES | NATURAL-PRODUCTS | BOND FUNCTIONALIZATIONS | CHEMISTRY, ORGANIC
Journal Article
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