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ISSN 1359-7345, 8/2018, Volume 54, Issue 64, pp. 8842 - 8844
...ChemComm COMMUNICATION Complexation of asymmetric diborenes with magnesium bromide† Cite this: Chem. Commun., 2018, 54, 8842 Wei Lu and Rei Kinjo * Accepted... 
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 10/2015, Volume 54, Issue 41, pp. 12116 - 12120
Hydrophosphination of CO2 with 1,3,2‐Diazaphospholene (NHP‐H; 1) afforded phosphorus formate (NHP‐OCOH; 2) through the formation of a bond between the... 
hydrosilylation | N‐formylation | metal‐free catalysis | hydrophosphination | CO2 activation | metal-free catalysis | activation | N-formylation | FORMIC-ACID | ROOM-TEMPERATURE | CATALYTIC-REDUCTION | EFFICIENT ORGANOCATALYSTS | MOLECULAR-STRUCTURE | FRUSTRATED LEWIS PAIRS | AMMONIA-BORANE | CHEMISTRY, MULTIDISCIPLINARY | C BONDS | H BONDS | CARBON-DIOXIDE | Amines | Catalysis
Journal Article
ISSN 2041-6520, 2/2019, Volume 1, Issue 7, pp. 288 - 292
Activation of dioxygen (O 2 ) by 1,4,2,5-diazadiborinine 1 is reported. Two boron centers in 1 undergo a formal [4 + 2] cycloaddition with O 2 at room... 
Journal Article
Chemical Society reviews, ISSN 0306-0012, 2019, Volume 48, Issue 13, pp. 3613 - 3659
This review focuses on boron-containing heterocycles enabling the activation of σ- and π-bonds in small molecules. Most of the chemical and biological... 
BN ISOSTERES | PHYSICAL-PROPERTIES | DIELS-ALDER REACTIONS | CARBON-MONOXIDE | RING EXPANSION REACTIONS | N-H | REACTIVITY | BORYL ANIONS | P-H | O-H | CHEMISTRY, MULTIDISCIPLINARY | Organic chemistry | Boron | Transition metal compounds | Chemical bonds | Activation | Coordination compounds | Biological activity
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 06/2018, Volume 57, Issue 26, pp. 7846 - 7849
An annulated 1,3,2,5‐diazadiborinine with 14 π electrons has been synthesized and fully characterized. Experimental and computational studies revealed that... 
isocyanides | boron | main group chemistry | small-molecule activation | electronic structure | Ammonia | Molecular orbitals | Cycloaddition | Hydrogen bonds | Molecular chains | Computer applications
Journal Article
Chemistry, an Asian journal, ISSN 1861-4728, 2018, Volume 13, Issue 10, pp. 1279 - 1292
Because the construction of the C−C bond is one of the most significant reactions in organic chemistry, the development of an efficient strategy has attracted... 
boranes | organocatalysis | C−C coupling | boron | synthesis design | C-C coupling | H BOND | ENANTIOSELECTIVE SYNTHESIS | OXAZABOROLIDINIUM ION | B(C6F5)-CATALYZED ALLYLATION | LEWIS-ACID | FRIEDEL-CRAFTS REACTIONS | CHEMISTRY, MULTIDISCIPLINARY | ALLYLIC ALCOHOLS | MANNICH-TYPE REACTIONS | DIELS-ALDER REACTION | CARBOXYLIC-ACIDS
Journal Article
Chemistry : a European journal, ISSN 0947-6539, 2018, Volume 24, Issue 58, pp. 15656 - 15662
Journal Article
Nature communications, ISSN 2041-1723, 2016, Volume 7, Issue 1, p. 11871
... Wang1, Yongxin Li2, Rakesh Ganguly2, Hajime Hirao1 & Rei Kinjo1 Boranes have long been known as the archetypal Lewis acids owing to an empty p-orbital on the boron... 
HYDROGEN | N-HETEROCYCLIC CARBENE | DATIVE BONDS | ACTIVATION | HARTREE-FOCK MODEL | MULTIDISCIPLINARY SCIENCES | REACTIVITY | CHEMISTRY | MAIN-GROUP COMPOUNDS | BASIS-SET | INTERMOLECULAR INTERACTIONS
Journal Article
Angewandte Chemie, ISSN 0044-8249, 2019, Volume 131, Issue 1, pp. 237 - 241
A borane B(C6F5)3‐catalyzed metathesis reaction between the Si−C bond in the cyclic (alkyl)(amino)germylene (CAAGe) 1 and the Si−H bond in a silane (R3SiH; 2)... 
Strukturaufklärung | Borane | Germylene | Reaktionsmechanismen | Kreuzmetathese | Regeneration | Transformation | Hydrogen bonds | Isomerization | Metathesis | Decomposition reactions
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 2014, Volume 53, Issue 35, pp. 9280 - 9283
An isolable phenylborylene species supported by two oxazol‐2‐ylidene ligands was synthesized and structurally characterized. Computational studies revealed the... 
borylenes | carbenes | reactive species | boron | nucleophiles | FORM | DIBORENES | ANIONIC DIMETALLOBORYLENE COMPLEX | BORANES | CHEMISTRY, MULTIDISCIPLINARY | BORYLLITHIUM | BULKY | TRANSITION-METAL BORYL | CHEMISTRY | ALKYL AMINO CARBENES | GENERATION | Chemical tests and reagents | Chromium | Boron | Conjugates | Computation | Ligands | Nucleophiles | Adducts | Fragmentation
Journal Article
ISSN 1359-7345, 10/2019, Volume 55, Issue 86, pp. 1312 - 1314
The reaction of 1,4,2,5-diazadiborinine ( 1 ) with two equivalents of an aryl isonitrile afforded a bicyclic product containing an indole unit ( 2 ) or... 
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 2019, Volume 58, Issue 1, pp. 231 - 235
A borane B(C6F5)3‐catalyzed metathesis reaction between the Si−C bond in the cyclic (alkyl)(amino)germylene (CAAGe) 1 and the Si−H bond in a silane (R3SiH; 2)... 
reaction mechanisms | germylene | structure elucidation | cross-metathesis | borane | PHYSICAL-PROPERTIES | H BOND | COMPLEXES | REACTIVITY | FRUSTRATED LEWIS PAIRS | CHEMISTRY, MULTIDISCIPLINARY | ELEMENTS | METAL ALKYLS | GERMANIUM | N-HETEROCYCLIC GERMYLENE | CHEMISTRY | Regeneration | Transformation | Hydrogen bonds | Isomerization | Metathesis | Decomposition reactions
Journal Article