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Angewandte Chemie International Edition, ISSN 1433-7851, 02/2018, Volume 57, Issue 9, pp. 2441 - 2444
Vinyl boron ate complexes of enantioenriched secondary alkyl pinacolboronic esters undergo stereospecific radical‐induced 1,2‐migration in radical polar... 
α-chiral ketones | radical polar crossover reactions | boronic esters | protodeborylation | B-ALKYLCATECHOLBORANES | FLUOROALKYLATION | CARBONYL-COMPOUNDS | CHEMISTRY, MULTIDISCIPLINARY | REARRANGEMENT | METHODOLOGY | REDUCTION | ESTERS | ASYMMETRIC ALKYLATION | alpha-chiral ketones | FLUORINE | HOMOLOGATION | Boron | Ketones | Iodides | Migration | Esters | Alkanes | Oxidation | Communications | Communication
Journal Article
Science, ISSN 0036-8075, 03/2017, Volume 355, Issue 6328, pp. 936 - 938
Vinyl boronic esters are valuable substrates for Suzuki-Miyaura cross-coupling reactions. However, boron-substituted alkenes have drawn little attention as... 
Catalysts | Metals | Migration | Esters | Alcohol | Carbon | Crossovers | Alcohols | Lactones | Chemistry | Boron | Anions | Chemical bonds | Charge transfer | Carbon-carbon composites | Chemical reactions | Radicals
Journal Article
Advanced Synthesis & Catalysis, ISSN 1615-4150, 12/2019
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 02/2018, Volume 57, Issue 9, p. 2441
Vinyl boron ate complexes of enantioenriched secondary alkyl pinacolboronic esters undergo stereospecific radical-induced 1,2-migration in radical polar... 
Usage | Ketones | Esters | Enantiomers
Journal Article
Organic Letters, ISSN 1523-7060, 06/2018, Volume 20, Issue 12, pp. 3666 - 3669
Radical-polar crossover reactions of dienylboronate complexes are applied to the synthesis of functionalized secondary and tertiary allylboronic esters. The... 
BORON | REAGENTS | ALLYLBORATION | ALLYLATION | CHEMISTRY | CHEMISTRY, ORGANIC | ALDEHYDES | DERIVATIVES | Letter
Journal Article
Organic Letters, ISSN 1523-7060, 03/2016, Volume 18, Issue 5, pp. 1206 - 1209
A transition-metal-free one-pot sequence for the synthesis of 3-peroxy-substituted oxindoles from readily prepared 2-cyano-2-diazo-acetamides is reported. The... 
H FUNCTIONALIZATION | ALPHA-DIAZOCARBONYL COMPOUNDS | ORGANIC-SYNTHESIS | DESIGN | ASYMMETRIC-SYNTHESIS | CATALYZED INTRAMOLECULAR CYCLIZATION | EFFICIENT SYNTHESIS | OXINDOLES | CHEMISTRY, ORGANIC | PEROXY NATURAL-PRODUCTS | TERT-BUTYL HYDROPEROXIDE
Journal Article
Chemical Science, ISSN 2041-6520, 01/2019, Volume 10, Issue 24, pp. 6210 - 6214
Pinacol boronic esters are highly valuable building blocks in organic synthesis. In contrast to the many protocols available on the functionalizing... 
Alkenes | Esters | Homology | Catalysis | Cholesterol
Journal Article
Chemical Science, ISSN 2041-6520, 2019, Volume 10, Issue 24, pp. 6210 - 6214
Pinacol boronic esters are highly valuable building blocks in organic synthesis. In contrast to the many protocols available on the functionalizing... 
HYDROBORATION | COUPLING REACTIONS | CONVERSION | SECONDARY | POLAR CROSSOVER REACTIONS | CONVENIENT | PROTONOLYSIS | INVERSION | CHEMISTRY, MULTIDISCIPLINARY | SATURATED COMPOUNDS | ORGANOBORANES
Journal Article
Science, ISSN 0036-8075, 03/2017, Volume 355, Issue 6328, p. 936
DOI: 10.1126/science.aa13803 
Chemical reactions | Chemical research | Research
Journal Article
Organic Letters, ISSN 1523-7060, 12/2018, Volume 20, Issue 24, pp. 7933 - 7936
Multicomponent reactions of diazo compounds have attracted much attention in recent years. Such transformations are generally conducted by applying transition... 
REARRANGEMENT | INSERTION | ASYMMETRIC-SYNTHESIS | H BOND | HYPERVALENT IODINE(III) | CATALYZED OXY-ALKYNYLATION | CHEMISTRY, ORGANIC | ENANTIOSELECTIVE CYCLOPROPANATION | TANDEM YLIDE | DONOR/ACCEPTOR CARBENOIDS | DIAZOCARBONYL COMPOUNDS
Journal Article
European Journal of Organic Chemistry, ISSN 1434-193X, 03/2016, Volume 2016, Issue 9, pp. 1751 - 1759
A series of nucleophiles, including primary and secondary amines, primary alcohols, and thiols, as well as diethyl malonate and nitromethane, were added to... 
Michael addition | Fluorine | Enones | Nucleophilic addition | SUBSTITUTION | DIELS-ALDER REACTIONS | BUILDING-BLOCKS | CHEMISTRY, ORGANIC | ALPHA,BETA-UNSATURATED CARBONYL-COMPOUNDS | ALPHA | CHEMICAL CONSEQUENCES | ALKENES | HETEROCYCLES | DERIVATIVES | CONJUGATE ADDITION | Ketones | Thiols | Fluorides
Journal Article
Angewandte Chemie, ISSN 0044-8249, 02/2018, Volume 130, Issue 9, p. 2466
Vinyl-Bor-At-Komplexe, hergestellt aus Enantiomeren-angereicherten Alkylpinakolboronsaureestern, durchlaufen stereospezifische, radikalisch induzierte... 
Journal Article
Angewandte Chemie, ISSN 0044-8249, 02/2018, Volume 130, Issue 9, pp. 2466 - 2469
Vinyl‐Bor‐At‐Komplexe, hergestellt aus Enantiomeren‐angereicherten Alkylpinakolboronsäureestern, durchlaufen stereospezifische, radikalisch induzierte... 
Synthesemethoden | Radikalisch/ionische Kreuzungsreaktion | Protodeborylierung | α-Chirale Ketone | Boronsäureester
Journal Article
Angewandte Chemie, ISSN 0044-8249, 02/2018, Volume 130, Issue 9, pp. 2466 - 2469
Vinyl‐Bor‐At‐Komplexe, hergestellt aus Enantiomeren‐angereicherten Alkylpinakolboronsäureestern, durchlaufen stereospezifische, radikalisch induzierte... 
Alkanes | Oxidation
Journal Article
ChemInform, ISSN 0931-7597, 07/2016, Volume 47, Issue 31, pp. no - no
The Michael addition of different nucleophiles including malonates and nitromethane as carbon nucleophiles, thiols, primary and secondary amines as well as... 
ketone derivatives (benzene compounds) | amines (benzene compounds) | mercaptans, thioethers (benzene compounds) | addition reactions | amines (acyclic compounds) | mercaptans, thioethers (acyclic compounds) | ketone derivatives (acyclic compounds) | Benzene | Thiols
Journal Article
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