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Journal of the American Chemical Society, ISSN 0002-7863, 06/2014, Volume 136, Issue 25, pp. 9195 - 9202
The Al­(I) compound NacNacAl (1, NacNac = [ArNC­(Me)­CHC­(Me)­NAr]− and Ar = 2,6-Pri 2C6H3) reacts with H–X (X = H, Si, B, Al, C, N, P, O) σ bonds of H2,... 
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 04/2014, Volume 53, Issue 17, pp. 4413 - 4417
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 04/2015, Volume 21, Issue 16, pp. 6144 - 6149
An unprecedented trinuclear heteroleptic AgI complex was isolated using a stable multidentate 2,4,6‐tris(2‐pyrimidyl)‐1,3,5‐triazine (TPymT) ligand. The... 
crystal structure | silver cluster | catalysis | aziridination | olefins | Silver cluster | Catalysis | Aziridination | Olefins | Crystal structure
Journal Article
Dalton Transactions, ISSN 1477-9226, 04/2015, Volume 44, Issue 14, pp. 6368 - 6373
The investigation of a pentagonal bipyramidal Co(II) complex with large positive anisotropy (D approximate to +30 cm(-1)) revealed field induced... 
SPIN-LATTICE-RELAXATION | ZERO-FIELD | IRON(II) PYRROLIDE COMPLEXES | TRANSITION-METAL-COMPLEXES | MAGNETIZATION | KRAMERS IONS | II COMPLEXES | CROSSOVER | LIGAND | ELECTRONIC-STRUCTURE | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, ISSN 0002-7863, 06/2014, Volume 136, Issue 25, pp. 9195 - 9202
The Al(I) compound NacNacAl (1, NacNac = [ArNC(Me)CHC(Me)NAr](-) and Ar = 2,6-(Pr2C6H3)-C-i) reacts with H-X (X = H, Si, B, Al, C, N, P, O) a bonds of H-2,... 
REDUCTIVE-ELIMINATION | HYDROGEN | INFRARED-SPECTRA | ACTIVATION | CRYSTAL-STRUCTURE | STRUCTURAL-CHARACTERIZATION | ALUMINUM(I) COMPOUND | FRUSTRATED LEWIS PAIRS | MAIN-GROUP COMPOUNDS | CHEMISTRY, MULTIDISCIPLINARY | B(C6F5)-CATALYZED HYDROSILYLATION | Chemical bonds | Research | Chemical synthesis | Analysis
Journal Article
The Journal of Physical Chemistry C, ISSN 1932-7447, 12/2015, Volume 119, Issue 48, pp. 27104 - 27117
A series of phosphine oxide-iodofluorobenzene cocrystals featuring relatively strongly halogen-bonded PO···I–C motifs has been prepared mechanochemically and... 
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 10/2013, Volume 52, Issue 43, pp. 11290 - 11293
The electronic and magnetic properties of the complexes [Co(terpy)Cl2] (1), [Co(terpy)(NCS)2] (2), and [Co(terpy)2](NCS)2 (3) were investigated. The... 
cobalt | single‐molecule magnets | multiple relaxation pathways | spin crossover | single-molecule magnets | SINGLE-MOLECULE MAGNET | ZERO-FIELD | CRYSTAL | ANISOTROPY | CHEMISTRY, MULTIDISCIPLINARY | ION MAGNET | Magnetization | Magnetic fields | Cobalt | Pathways | Electronics | Ligands | Crossovers | Magnetic properties
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 06/2014, Volume 136, Issue 22, pp. 8003 - 8010
Two different coupling strategies were employed to create ErIII single-molecule magnets (SMMs) using high blocking temperature mononuclear precursors. The... 
SANDWICH COMPLEX | SYMMETRY | GROUND-STATE | BEHAVIOR | RELAXATION | BLOCKING | EXCHANGE | ANISOTROPY BARRIER | CHEMISTRY, MULTIDISCIPLINARY | ION MAGNET | Magnetic hysteresis | Usage | Research | Anisotropy | Erbium
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 06/2011, Volume 133, Issue 23, pp. 8830 - 8833
The magnetic dilution method was employed in order to elucidate the origin of the slow relaxation of the magnetization in a Dy2 single-molecule magnet (SMM).... 
Chemical Sciences | Coordination chemistry
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 03/2014, Volume 53, Issue 10, pp. 2711 - 2715
Reduction of the cationic GeII complex [dimpyrGeCl][GeCl3] (dimpyr=2,6‐(ArN=CMe)2NC5H3, Ar=2,6‐iPr2C6H3) with potassium graphite in benzene affords an air... 
pyridine | low oxidation states | germanium | DFT calculations | EPR spectroscopy | Schiff bases | Pyridine | Nitrogen | Benzene | Ligands
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 09/2013, Volume 135, Issue 36, pp. 13242 - 13245
The effect of electron-withdrawing ligands on the energy barriers of Single-Molecule Magnets (SMMs) is investigated. By introducing highly electron-withdrawing... 
STATES | SYMMETRY | SPINTRONICS | BEHAVIOR | LANTHANIDE COMPLEXES | RELAXATION | ANISOTROPY BARRIER | CHEMISTRY, MULTIDISCIPLINARY | Measurement | Chemical reaction, Rate of | Electron transport | Analysis | Methods | Surface energy
Journal Article
Chemical Communications, ISSN 1359-7345, 02/2014, Volume 50, Issue 13, pp. 1602 - 1604
A mononuclear Er-III sandwich type complex, [Li(DME)(3)][Er-III(COT'')(2)], was isolated using 1,4-bis(trimethylsilyl) cyclooctatetraenyl dianion (COT'').... 
SINGLE-MOLECULE MAGNET | BLOCKING | CLUSTER | SPIN QUBITS | CHEMISTRY, MULTIDISCIPLINARY | RATIONAL DESIGN
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 03/2013, Volume 135, Issue 9, pp. 3502 - 3510
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 11/2017, Volume 23, Issue 66, pp. 16763 - 16767
Efficient electrocatalytic production of H2 from mixed water/acetonitrile solutions was achieved using three new CoII complexes supported by the neutral pincer... 
ruthenium | cobalt | hydrogen | saline | electrocatalysis | Hydrogen | Cobalt | Pyridine | Pyridines | Saline water | Catalysts | Glassy carbon | Hydrogen ion concentration | Acetonitrile
Journal Article
Angewandte Chemie - International Edition, ISSN 0570-0833, 2012, Volume 51, Issue 6, pp. 1366 - 1369
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 12/2017, Volume 23, Issue 68, pp. 17269 - 17278
Journal Article
Dalton Transactions, ISSN 1477-9226, 2018, Volume 47, Issue 34, pp. 11782 - 11787
A recently designed nitrogen-rich ligand is successfully applied as a scaffold for lanthanide ions to show that the intricate chemistry of energetic materials... 
LUMINESCENCE | ENERGETIC MATERIALS | CLICK CHEMISTRY | BIS(TETRAZOLE) LIGANDS | COORDINATION POLYMERS | MOLECULE MAGNET | DERIVATIVES | METAL-COMPLEXES | FRAMEWORKS | CHEMISTRY, INORGANIC & NUCLEAR | Organic chemistry | Magnetic induction | Magnetic relaxation | Energetic materials | Ligands | Magnetism | Dysprosium | Chemical synthesis | Scaffolds
Journal Article
Inorganic Chemistry, ISSN 0020-1669, 07/2015, Volume 54, Issue 13, pp. 6195 - 6202
The encapsulating N1,N3-bis(3-methoxysalicylidene)diethylenetriamine (H(2)valdien) ligand was employed to isolate two novel Dy-III compounds which contain rare... 
SINGLE-MOLECULE MAGNET | SALEN-TYPE | REDUCTION | BEHAVIOR | AGGREGATE | LANTHANIDE COMPLEXES | REACTIVITY | COORDINATION | CLUSTER | SCHIFF-BASE LIGANDS | CHEMISTRY, INORGANIC & NUCLEAR | Ferromagnetism | Research | Coupling (molecular) | Unit cell | Bridging | Anisotropy | Magnetic permeability | Lanthanides | Encapsulating
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 10/2011, Volume 133, Issue 40, pp. 15814 - 15817
Bis(imino)pyridine pincer ligands in conjunction with two isothiocyanate ligands have been used to prepare two mononuclear Co(II) complexes. Both complexes... 
SPIN | MAGNETIZATION | COMPLEXES | RELAXATION | IRON | ANISOTROPY | CHEMISTRY, MULTIDISCIPLINARY | CATALYSTS | COBALT | Spin coupling | Pyridine | Magnetization | Analysis | Copper compounds | Chemical properties | Structure | Magnetic properties
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 06/2016, Volume 22, Issue 24, pp. 8063 - 8067
Selective reactions between nucleophilic N,N′‐diaryl‐heterocyclic carbenes (NHCs) and electrophilic fluorinated alkenes afford NHC fluoroalkenes in high... 
carbenes | imidazolium | fluoroalkenes | NMR spectroscopy | pyrrolidine | PALLADIUM | DIELS-ALDER REACTIONS | COMPLEXES | REACTIVITY | COORDINATION | POLYMERIZATION | CHEMISTRY, MULTIDISCIPLINARY | ORGANOCATALYSTS | CHEMISTRY | OLEFINS | UMPOLUNG | Cytokinins | Nuclear magnetic resonance spectroscopy | Pyridine | Fluorides | Mass spectrometry | Lewis acid | Alkenes | Mathematical analysis | X-rays | Fluorination | Carbenes
Journal Article