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catalysis (15) 15
aldehydes (11) 11
science & technology (9) 9
synthesis of natural products and potential drugs (9) 9
animals (7) 7
iridium (7) 7
life sciences & biomedicine (5) 5
alcohols (4) 4
chemical properties (4) 4
diastereoselective syntheses, enantioselective syntheses (4) 4
male (4) 4
molecular structure (4) 4
research (4) 4
aliphatic compounds (3) 3
amines (3) 3
analysis (3) 3
asymmetry (3) 3
catalysis, phase‐transfer catalysis (3) 3
chemical synthesis (3) 3
chlorination (3) 3
enantiomers (3) 3
inhibitors (3) 3
katalyse (3) 3
mice (3) 3
stereoisomer (3) 3
stereoisomerism (3) 3
stereoisomers (3) 3
substitution reactions (3) 3
synthesis (3) 3
aldehyd (2) 2
allylation (2) 2
allylierung (2) 2
antifungal agents (2) 2
apoptosis (2) 2
asymmetric synthesis (2) 2
atpenins (2) 2
bioisosterism (2) 2
biological sciences (2) 2
body weight (2) 2
caspase 8 - genetics (2) 2
caspase 8 - physiology (2) 2
catalysts (2) 2
cell death (2) 2
chains (2) 2
chemistry (2) 2
chemistry, multidisciplinary (2) 2
chlorinated natural products (2) 2
cobalt - chemistry (2) 2
crystallography, x-ray (2) 2
c‐c bond formation (2) 2
dual catalysis (2) 2
duale katalyse (2) 2
exchange (2) 2
exchanging (2) 2
fas-associated death domain protein - genetics (2) 2
fas-associated death domain protein - physiology (2) 2
female (2) 2
fungicides (2) 2
germany - epidemiology (2) 2
inhibition of respiratory chain (2) 2
iridium - chemistry (2) 2
kidney tubules - cytology (2) 2
materials selection (2) 2
models, molecular (2) 2
multidisciplinary sciences (2) 2
physical sciences (2) 2
physiological aspects (2) 2
piperidine (2) 2
receptor-interacting protein serine-threonine kinases - genetics (2) 2
receptor-interacting protein serine-threonine kinases - physiology (2) 2
reperfusion injury - prevention & control (2) 2
science & technology - other topics (2) 2
tetrahydrocannabinol (2) 2
totalsynthese (2) 2
turkeys (2) 2
3-hydroxysteroid dehydrogenases - metabolism (1) 1
abattoirs (1) 1
access control (1) 1
acetaldehyd (1) 1
acetaldehyde (1) 1
acid sphingomyelinase (1) 1
acute kidney injury (1) 1
agriculture (1) 1
agriculture, dairy & animal science (1) 1
aldehyde (1) 1
aldehyde derivatives (1) 1
alkenes (1) 1
alkenes - chemistry (1) 1
alkohole (1) 1
alkynes - chemistry (1) 1
allyl compounds - chemistry (1) 1
allyl-alcohol (1) 1
allylalkohol (1) 1
allylation; catalysis; iridium; piperidines; stereoselective synthesis (1) 1
allylic compounds (1) 1
allylierungen (1) 1
amine catalysis (1) 1
aminkatalyse (1) 1
anesthesia (1) 1
anesthetics (1) 1
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Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 04/2017, Volume 139, Issue 16, pp. 5627 - 5639
This Perspective presents an overview of catalytic enantio­selective transformations that allow convenient access to all stereo­isomers of a given product with... 
Physical Sciences | Chemistry | Chemistry, Multidisciplinary | Science & Technology | Usage | Chemical properties | Catalysis | Chemical synthesis | Isomerism
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 03/2017, Volume 139, Issue 10, pp. 3603 - 3606
Journal Article
Science (American Association for the Advancement of Science), ISSN 0036-8075, 5/2013, Volume 340, Issue 6136, pp. 1065 - 1068
An important challenge in asymmetric synthesis is the development of fully stereodivergent strategies to access the full complement of stereoisomers of... 
Observational research | Amines | Catalysts | RESEARCH ARTICLES | Catalysis | Aldehydes | Nucleophiles | Alcohols | Iridium compounds | Carbon-carbon composites | Branched | Concerts | Bonding | Versatility
Journal Article
Science (American Association for the Advancement of Science), ISSN 0036-8075, 05/2013, Volume 340, Issue 6136, pp. 1065 - 1068
An important challenge in asymmetric synthesis is the development of fully stereodivergent strategies to access the full complement of stereoisomers of... 
Science & Technology - Other Topics | Multidisciplinary Sciences | Science & Technology
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 02/2014, Volume 136, Issue 8, pp. 3020 - 3023
We describe the fully stereodivergent, dual catalytic α-allylation of linear aldehydes. The reaction proceeds via direct iridium-catalyzed substitution of... 
Amines | Influence | Chemical properties | Iridium | Catalysis | Research | Aldehydes
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 11/2015, Volume 54, Issue 48, pp. 14363 - 14367
Fully stereodivergent dual‐catalytic α‐allylation of protected α‐amino‐ and α‐hydroxyacetaldehydes is achieved through iridium‐ and amine‐catalyzed... 
iridium | aldehydes | amine catalysis | dual catalysis | stereodivergence
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 12/2012, Volume 134, Issue 50, pp. 20276 - 20278
A highly enantioselective polycyclization method has been developed using the combination of Lewis acid activation with iridium-catalyzed allylic substitution.... 
Polyenes - chemistry | Catalysis | Cyclization | Stereoisomerism | Iridium - chemistry | Allylic compounds | Analysis | Polyenes | Substitution reactions | Chemical properties | Ring formation (Chemistry) | Iridium | Index Medicus
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 03/2017, Volume 139, Issue 10, pp. 3868 - 3875
A cobalt-catalyzed method for the 1,1-diboration of terminal alkynes with bis­(pinacolato)­diboron (B2Pin2) is described. The reaction proceeds efficiently at... 
Boron Compounds - chemistry | Boron Compounds - chemical synthesis | Models, Molecular | Crystallography, X-Ray | Alkynes - chemistry | Molecular Structure | Catalysis | Cobalt - chemistry | Research | Index Medicus
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 09/2017, Volume 56, Issue 38, pp. 11515 - 11519
An iridium‐catalyzed cyclocondensation of amino alcohols and aldehydes is reported. Intramolecular allylic substitution by an enamine intermediate and... 
iridium | piperidines | catalysis | allylation | stereoselective synthesis | Catalysis | Iridium | Piperidine | Aldehydes | Chemical synthesis | Alcohols
Journal Article
Synfacts, ISSN 1861-1958, 02/2014, Volume 10, Issue 2, pp. 0113 - 0113
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 12/2014, Volume 53, Issue 50, pp. 13898 - 13901
All four stereoisomers of Δ9‐tetrahydrocannabinol (Δ9‐THC) were synthesized in concise fashion using stereodivergent dual catalysis. Thus, following identical... 
tetrahydrocannabinol | dual catalysis | total synthesis | stereodivergent synthesis | Dual catalysis | Tetrahydrocannabinol | Total synthesis | Stereodivergent synthesis | Stereoisomerism | Dronabinol - chemical synthesis | Dronabinol - chemistry | Index Medicus
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 02/2020, Volume 142, Issue 8, pp. 3923 - 3930
Unsymmetric 1,1-diboryl alkenes bearing one −[BPin] (BPin = pinacolatoboryl) and one −[BDan] (BDan = 1,8-diaminonaphthalatoboryl) substituent each were... 
Index Medicus
Journal Article
Organic letters, ISSN 1523-7060, 04/2013, Volume 15, Issue 7, pp. 1634 - 1637
A cobalt-catalyzed photochemical synthesis of allylic trifluoromethanes from styrene derivatives using 2,2,2-trifluoroethyl iodide is described. The method... 
Chemistry, Organic - methods | Styrenes - chemical synthesis | Hydrocarbons, Fluorinated - chemical synthesis | Styrenes - chemistry | Hydrocarbons, Fluorinated - chemistry | Molecular Structure | Catalysis | Cobalt - chemistry | Chemistry, Organic - instrumentation | Photochemical Processes | Index Medicus
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 12/2018, Volume 140, Issue 48, pp. 16704 - 16710
The first synthesis of (−)-mitrephorone A is disclosed along with discussion and study of synthetic strategies. The natural product includes a highly congested... 
Journal Article
Organic letters, ISSN 1523-7060, 11/2019, Volume 21, Issue 21, pp. 8705 - 8707
Enantioselective synthesis of a highly versatile building block en route to trachylobanes and related terpenoids is presented. The synthesis features... 
Index Medicus
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 08/2019, Volume 141, Issue 31, pp. 12212 - 12218
The iridium-catalyzed asymmetric allylic substitution under biphasic conditions is reported. This approach allows the use of various unstable and/or volatile... 
Index Medicus
Journal Article
Synfacts, ISSN 1861-1958, 11/2013, Volume 9, Issue 11, pp. 1143 - 1143
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 11/2015, Volume 54, Issue 48, p. 14363
  Fully stereodivergent dual-catalytic [alpha]-allylation of protected [alpha]-amino- and [alpha]-hydroxyacetaldehydes is achieved through iridium- and... 
Journal Article
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