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Angewandte Chemie International Edition, ISSN 1433-7851, 04/2019, Volume 58, Issue 16, pp. 5338 - 5342
Complexity‐increasing Domino reactions comprising C−H allenylation, a Diels–Alder reaction, and a retro‐Diels–Alder reaction were realized by a versatile... 
pericyclic reactions | C−H activation | domino reactions | indolone alkaloids | manganese | DIRECTING GROUP | CATALYZED SYNTHESIS | ARYLATION | ALDEHYDES | CHEMISTRY, MULTIDISCIPLINARY | FUNCTIONALIZATION | ALKENES | C-H activation | ESTERS | ACCESS | KEY | ALKENYLATION | Pyridine | Diels-Alder reaction | Pyridines | Organic chemistry | Chemical reactions | Activation | Cascade chemical reactions | Manganese | Alkynes
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 02/2019, Volume 58, Issue 6, pp. 1684 - 1688
Bioorthogonal late‐stage diversification of structurally complex peptides has enormous potential for drug discovery and molecular imaging. In recent years,... 
peptides | cobalt | C−H activation | metathesis | cyclopeptides | TRYPTOPHAN | PALLADIUM | ARYLATION | ALLYLATION | AMIDATION | ALPHA-AMINO-ACIDS | CHEMISTRY, MULTIDISCIPLINARY | CARBON-HYDROGEN | FUNCTIONALIZATION | C-H activation | BONDS | STEREOSELECTIVE-SYNTHESIS | Activation | Palladium | Catalysts | Peptides | Cobalt | Metathesis
Journal Article
Theoretical Chemistry Accounts, ISSN 1432-881X, 05/2017, Volume 136, Issue 5, p. 1
The reaction of carbon dioxide with alpha-siloxy silanes assisted by cesium fluoride is studied by means of DFT calculations with the B97D functional.... 
Brook rearrangement | Counterions | DFT | activation | TRANSFORMATION | MOLECULAR-ORBITAL METHODS | EFFECTIVE CORE POTENTIALS | ACIDS | CO2 | CHEMISTRY, PHYSICAL | CARBOXYLATION | BASIS-SET | LACTONE | CO2 activation
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 10/2019, Volume 25, Issue 55, pp. 12712 - 12718
Arylated cyclobutanes were accessed by a versatile palladium‐catalyzed secondary C(sp3)−H activation, exploiting chelation assistance by modular triazoles. The... 
triazoles | C(sp3)−H activation | cyclobutanes | BODIPY | labeling | Chelation | Boron | Palladium | Cyclobutane | Natural products | Triazoles
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 11/2019
Journal Article
Angewandte Chemie, ISSN 0044-8249, 04/2019, Volume 131, Issue 16, pp. 5392 - 5396
Complexity‐increasing Domino reactions comprising C−H allenylation, a Diels–Alder reaction, and a retro‐Diels–Alder reaction were realized by a versatile... 
Dominoreaktionen | Indolonalkaloide | Pericyclische Reaktionen | Mangan | C-H-Aktivierung | Pyridine | Diels-Alder reaction | Pyridines | Organic chemistry | Chemical reactions | Activation | Cascade chemical reactions | Manganese | Alkynes
Journal Article
Organic Letters, ISSN 1523-7060, 10/2013, Volume 15, Issue 19, pp. 5040 - 5043
The mechanism and the role of KOtBu in an enantioselective NHC-catalyzed Stetter reaction between p-chlorobenzaldehyde and N-acylamido acrylate is established... 
CHEMISTRY, ORGANIC | ALDEHYDES | STEREOSELECTIVITY | MECHANISTIC INSIGHTS | ENALS
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 09/2018, Volume 140, Issue 37, pp. 11836 - 11847
The first Ru­(II)-catalyzed arylation of substrates without a directing group was recently developed. Remarkably, this process only worked in the presence of a... 
H BOND ACTIVATION | GENERAL ACID CATALYSIS | ELECTRON-DEFICIENT POLYFLUOROARENES | ARYL HALIDES | METALATION-DEPROTONATION MECHANISM | AROMATIC SUBSTITUTION | POTASSIUM POLYFLUOROBENZOATES | CHEMISTRY, MULTIDISCIPLINARY | CATALYZED DIRECT ARYLATION | C-H | CARBOXYLIC-ACIDS
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 10/2019, Volume 141, Issue 43, pp. 17198 - 17206
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 03/2018, Volume 140, Issue 11, pp. 3981 - 3987
An efficient protocol was developed to construct functionally dense quaternary carbons with concomitant formation of a new Csp3–Csp3 bond via Pd-catalyzed... 
METAL-FREE SYNTHESIS | CYCLOADDITION | VINYLETHYLENE CARBONATES | C-C | ALPHA-ALLYLATION | ALDEHYDES | ENANTIOSELECTIVE CONSTRUCTION | ALLYLIC SUBSTITUTION | CHEMISTRY, MULTIDISCIPLINARY | TETRASUBSTITUTED OLEFINS | HIGHLY EFFICIENT
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 09/2016, Volume 138, Issue 36, pp. 11970 - 11978
Journal Article
Angewandte Chemie, ISSN 0044-8249, 02/2019, Volume 131, Issue 6, pp. 1698 - 1702
Bioorthogonal late‐stage diversification of structurally complex peptides has enormous potential for drug discovery and molecular imaging. In recent years,... 
Cyclopeptide | Cobalt | Peptide | Metathese | C-H-Aktivierung | Palladium catalysts | Palladium | Drug discovery | Peptides | Activation | Catalysts | Metathesis
Journal Article
Chemical communications (Cambridge, England), ISSN 1359-7345, 11/2018, Volume 54, Issue 91, pp. 12840 - 12843
Ruthenium-catalysis enabled the C-5 selective C-H oxygenation of naphthoquinones, and also sets the stage for the site-selective introduction of a hydroxyl... 
UNITED-STATES | FUNCTIONALIZATION | ALKENES | PRIVILEGED STRUCTURES | MECHANISM | TRYPANOSOMA-CRUZI | CHAGAS-DISEASE | BOND ACTIVATION | DIRECT ARYLATIONS | DERIVATIVES | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
Angewandte Chemie (International ed. in English), 11/2018
Bioorthogonal late-stage diversification of structurally complex peptides has enormous potential for drug discovery and molecular imaging. In recent years,... 
Journal Article
Journal of the American Chemical Society, 01/2018
An efficient protocol was developed to construct functionally dense quaternary carbons with concomitant formation of a new Csp3-Csp3 bond via Pd-catalyzed... 
Journal Article
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