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Journal of the American Chemical Society, ISSN 0002-7863, 10/2014, Volume 136, Issue 42, pp. 14654 - 14657
Thanks to rational ligand design, the first gold(I) complexes to undergo oxidative addition of aryl iodides were discovered. The reaction proceeds under mild... 
HALIDES | CATALYSIS | ACTIVATION | DFT | MECHANISM | COMPLEXES | SYN-INSERTION | BOND | ALLENES | ALKYNES | CHEMISTRY, MULTIDISCIPLINARY | Density functionals | Gold compounds | Chemical properties | Analysis | Chemical Sciences
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 09/2018, Volume 57, Issue 36, pp. 11732 - 11736
The first catalytic application of well‐defined (P,C) cyclometalated gold(III) complexes is reported. The bench‐stable bis(trifluoroacetyl) complexes 2 a,b... 
hydroarylation | homogeneous catalysis | gold(III) | alkynes | P-based ligands | INSERTION | ACTIVATION | REACTIVITY | GOLD COMPLEXES | OXIDATIVE ADDITION | CHEMISTRY, MULTIDISCIPLINARY | C-H BONDS | FUNCTIONALIZATION | NORBORNENE | CHEMISTRY | OLEFINS | Gold | Transformation | Catalysts | Catalysis | Coordination compounds | Trifluoroacetyl | Alkynes
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 01/2018, Volume 57, Issue 5, pp. 1306 - 1310
The [(P,P)Au=C(Ph)CO2Et]+ complex 3 [where (P,P) is an o‐carboranyl diphosphine ligand] was prepared by diazo decomposition at −40 °C. It is the first α‐oxo... 
gold | homogeneous catalysis | diazo compounds | bidentate ligand | carbene complexes | Gold | Phenols | Chelation | Ligands | Catalysis | Carbenes | Crystallography | Crystal structure | Chemical Sciences
Journal Article
European Journal of Inorganic Chemistry, ISSN 1434-1948, 06/2018, Volume 2018, Issue 20-21, pp. 2387 - 2392
The reaction of the hydrotris(3,5‐dimethylpyrazolyl)borate potassium salt KTpMe2 with [Mg(c‐C3H5)2(dioxane)x] gives [TpMe2Mg(c‐C3H5)] (1) in 70 % yield. Full... 
Cyclopropyl group | Alkaline earth metals | Scorpionate | Magnesium | Grignard | ALKYL DERIVATIVES | CYCLIC ESTERS | COMPOUND | REACTIVITY | RHODIUM COMPLEX | CHEMISTRY, INORGANIC & NUCLEAR | HYBRID SCORPIONATE/CYCLOPENTADIENYL MAGNESIUM | RING-OPENING POLYMERIZATION | C SIGMA-INTERACTIONS | BOND | INITIATORS | Dioxane | Borates | X-ray diffraction | Potassium salts | Ligands | Chemical Sciences | Coordination chemistry
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 12/2014, Volume 53, Issue 52, pp. 14512 - 14516
The specific electronic properties of bent o‐carborane diphosphine gold(I) fragments were exploited to obtain the first classical carbonyl complex of gold... 
gold | carbenoids | carbonyl ligands | π‐backdonation | diphosphines | Diphosphines | Gold | Carbenoids | Carbonyl ligands | π-backdonation | Chemical Sciences
Journal Article
Chemical Science, ISSN 2041-6520, 2018, Volume 9, Issue 16, pp. 3932 - 3940
Gold(III) complexes are garnering increasing interest for opto-electronic, therapeutic and catalytic applications. But so far, very little is known about the... 
FUNCTIONALIZATION | CATALYSIS | ETHYLENE | AU-C | REACTIVITY | COORDINATION | ELIMINATION | GOLD COMPLEXES | MEMORY DEVICES | CHEMISTRY, MULTIDISCIPLINARY | LIVED EXCITED-STATES | Gold | Optoelectronics | Reactivity | Ethylene | Chain branching | Insertion | Ligands | Influence | Cations | Catalysis | Nitrogen
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 07/2013, Volume 52, Issue 28, pp. 7160 - 7163
Complete control: Alkynes and allenes are shown to insert into AuSi bonds with complete stereocontrol and in most cases complete regiocontrol. The ensuing... 
gold | allenes | insertion reaction | vinyl complexes | alkynes | PALLADIUM | SILICON BOND | MECHANISM | COMPLEXES | HOMOGENEOUS GOLD CATALYSIS | REACTIVITY | REDUCTIVE ELIMINATION | CHEMISTRY, MULTIDISCIPLINARY | BORONIC ACIDS | TRANSMETALATION | ELEMENTARY STEPS | Insertion | Gold | Spectroscopy | Inserts | Crystallography | Alkynes
Journal Article