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chemistry, organic (8) 8
functionalization (8) 8
catalysis (7) 7
catalysis, phase‐transfer catalysis (5) 5
chemistry, multidisciplinary (5) 5
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ergot alkaloids (4) 4
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Organic Letters, ISSN 1523-7060, 2013, Volume 15, Issue 11, pp. 2818 - 2821
Journal Article
ISSN 1359-7345, 5/2017, Volume 53, Issue 37, pp. 5117 - 512
The C4-aminated indole scaffold is frequently encountered in several natural products and biologically active compounds. Herein we disclose a simple and short... 
Journal Article
Organic Letters, ISSN 1523-7060, 12/2013, Volume 15, Issue 24, pp. 6262 - 6265
A highly regioselective functionalization of indole at the C-4 position by employing an aldehyde functional group as a directing group, and Ru as a catalyst,... 
FUNCTIONALIZATION | PALLADIUM | ACIDS | ARYLATION | ERGOT ALKALOIDS | CHEMISTRY, ORGANIC | BOND FORMATION | ALDEHYDES | IDENTIFICATION | EFFICIENT | ORTHO-ALKENYLATION | Stereoisomerism | Indoles - chemical synthesis | Organometallic Compounds - chemistry | Molecular Structure | Catalysis | Indoles - chemistry | Ruthenium - chemistry
Journal Article
Organic Letters, ISSN 1523-7060, 06/2013, Volume 15, Issue 11, pp. 2818 - 2821
A highly regioselective alkenylation of indole at the C2-position has been achieved using the Ru(II) catalyst by employing a directing group strategy. This... 
H BOND ACTIVATION | FUNCTIONALIZATION | DIRECT ARYLATION | PROTECTING GROUP | ATOM ECONOMY | CHEMISTRY, ORGANIC | OLEFINS | CARBON-HYDROGEN BONDS | CLEAVAGE | PALLADIUM ACETATE | ORTHO-ALKENYLATION
Journal Article
Chemical Communications, ISSN 1359-7345, 2017, Volume 53, Issue 37, pp. 5117 - 5120
The C4-aminated indole scaffold is frequently encountered in several natural products and biologically active compounds. Herein we disclose a simple and short... 
DIRECTING GROUP | BOND AMIDATION | ROOM-TEMPERATURE | INDOLACTAM-V | SULFONYL AZIDES | NITROGEN-SOURCE | C-H AMIDATION | INTERMOLECULAR AMIDATION | N-PIVALOYLINDOLES | SYNTHETIC ROUTE | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
Organic Letters, ISSN 1523-7060, 10/2015, Volume 17, Issue 19, pp. 4658 - 4661
A 1,4-addition with the nucleophilic center generated at the ortho carbon atom of an aromatic ketone in the presence of the highly reactive α-C–H bond, using a... 
CATALYZED ASYMMETRIC 1,4-ADDITION | FUNCTIONALIZATION | ALKENES | CARBON | MECHANISM | ACIDS | SCOPE | METHYLENECYCLOPROPANES | CHEMISTRY, ORGANIC | HYDROARYLATION | CONJUGATE ADDITION
Journal Article
ISSN 1359-7345, 10/2018, Volume 54, Issue 79, pp. 112 - 1123
A Rh( iii )-catalyzed C-H activation of indole at the C4-position leading to novel and switchable functionalization has been reported by employing a weakly... 
Journal Article
Organic Letters, ISSN 1523-7060, 11/2016, Volume 18, Issue 21, pp. 5496 - 5499
A novel mode of achieving site selectivity between C-2 and C-4 positions in the indole framework by altering the property of the ketone directing group is... 
DIRECT C2-OLEFINATION | OLEFINATION | O BOND | GROUP STRATEGY | BOND FUNCTIONALIZATION | REGIOSELECTIVE SYNTHESIS | ERGOT ALKALOIDS | ACTIVATION/CYCLIZATION | CHEMISTRY, ORGANIC | PYRROLES | C-H ACTIVATION
Journal Article
Chemical Communications : Chem Comm, ISSN 1359-7345, 01/2018, Volume 54, Issue 79, pp. 11200 - 11203
A Rh(iii)-catalyzed C–H activation of indole at the C4-position leading to novel and switchable functionalization has been reported by employing a weakly... 
Rhodium | Activation | Deuteration
Journal Article
Chemical Science, ISSN 2041-6520, 01/2019, Volume 10, Issue 41, pp. 9548 - 9554
We herein disclose a diastereoselective ring opening of non-donor–acceptor cyclopropanes via an intramolecular Friedel–Crafts alkylation en route to... 
Stereoselectivity | Crafts | Configurations | Crystallography | Carbon | Ring opening | Alkylation | Organic compounds
Journal Article
Organic Letters, ISSN 1523-7060, 10/2015, Volume 17, Issue 19, pp. 4662 - 4665
Synthesis of 3-(indol-2-yl)­succinimide derivatives is presented using a directing group strategy. Selective functionalization of C-2 in the presence of highly... 
DIRECTING GROUP | FUNCTIONALIZATION | ALKENES | DIRECT C2-OLEFINATION | ATOM ECONOMY | RING-OPENING REACTIONS | REGIOSELECTIVE SYNTHESIS | CHEMISTRY, ORGANIC | BOND ACTIVATION | DERIVATIVES | ORTHO-ALKENYLATION
Journal Article
Chemical Communications: Chem Comm, ISSN 1359-7345, 06/2017, Volume 53, Issue 46, pp. 6251 - 6254
A Rh(iii)-catalyzed C-H activation followed by conjugate addition to maleimides, using carboxylic acid as a traceless/deciduous directing group, to formally... 
Conjugates | Aromatic compounds | Acrylic acid | Chemical bonds | Activation | Derivatives | Carboxylic acids | Nucleophiles
Journal Article
Chemical Communications, ISSN 1359-7345, 2017, Volume 53, Issue 46, pp. 6251 - 6254
A Rh( III)-catalyzed C-H activation followed by conjugate addition to maleimides, using carboxylic acid as a traceless/deciduous directing group, to formally... 
FUNCTIONALIZATION | PALLADIUM | CATALYZED VINYLATION | C-H BOND | ARYLATION | 1,4-ADDITION | ALKYNES | CHEMISTRY, MULTIDISCIPLINARY | HYDROARYLATION | BENZOIC-ACIDS | CARBOXYLIC-ACIDS
Journal Article
Chemical Communications, ISSN 1359-7345, 2018, Volume 54, Issue 79, pp. 11200 - 11203
A Rh(iii)-catalyzed C-H activation of indole at the C4-position leading to novel and switchable functionalization has been reported by employing a weakly... 
DIRECTING GROUP | DIRECT C2-OLEFINATION | MILD CONDITIONS | BOND FUNCTIONALIZATIONS | REGIOSELECTIVE SYNTHESIS | ERGOT ALKALOIDS | C-2 | PYRROLES | CHEMISTRY, MULTIDISCIPLINARY | ALKENYLATION | CONJUGATE ADDITION
Journal Article
The Journal of Organic Chemistry, ISSN 0022-3263, 07/2016, Volume 81, Issue 14, pp. 6056 - 6065
Maleimide has been used as a selective coupling partner to generate conjugate addition products exclusively. The typical Heck-type oxidative coupling that... 
RUTHENIUM-CATALYZED HYDROARYLATION | FUNCTIONALIZATION | CHEMICAL-REACTIONS | ORGANIC-SYNTHESIS | BENZAMIDES | SCOPE | ASSISTANCE | METHYLENECYCLOPROPANES | CHEMISTRY, ORGANIC | OLEFINS | CLEAVAGE | Chemical bonds | Usage | Ruthenium | Chemical properties | Catalysis
Journal Article
Asian Journal of Organic Chemistry, ISSN 2193-5807, 07/2018, Volume 7, Issue 7, pp. 1338 - 1342
Maleimides are not known to undergo oxidative‐Heck reaction because they lack a syn‐periplanar β‐hydrogen atom. Herein, we report a C−H activation‐based... 
oxidative Heck reaction | Synthetic methods | directing group | RhIII-Catalyst | maleimides
Journal Article
The Journal of Organic Chemistry, ISSN 0022-3263, 02/2018, Volume 83, Issue 4, pp. 1810 - 1818
A double C–H activation and double insertion process to achieve the synthesis benzo­[e]­indole frameworks has been disclosed. This type of benzannulation is... 
FUNCTIONALIZATION | CATALYZED REACTIONS | MALEIMIDES | ACETYLENE | ERGOT ALKALOIDS | CHEMISTRY | CHEMISTRY, ORGANIC | BOND FORMATION | PHENYLAZOLES | INTERNAL ALKYNES | C-H ACTIVATION | Ring formation (Chemistry) | Chemical properties | Analysis | Indole | Benzene
Journal Article
CHEMICAL SCIENCE, ISSN 2041-6520, 11/2019, Volume 10, Issue 41, pp. 9548 - 9554
We herein disclose a diastereoselective ring opening of non-donor-acceptor cyclopropanes via an intramolecular Friedel-Crafts alkylation en route to... 
HOMO-NAZAROV CYCLIZATION | ACYCLIC SYSTEMS | CATALYSIS | DONOR-ACCEPTOR CYCLOPROPANES | QUATERNARY STEREOGENIC CENTERS | STEREOCENTERS | C-C BONDS | CREATION | BROOK REARRANGEMENT | DERIVATIVES | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
Asian Journal of Organic Chemistry, ISSN 2193-5807, 07/2018, Volume 7, Issue 7, pp. 1338 - 1342
Maleimides are not known to undergo oxidative-Heck reaction because they lack a syn-periplanar beta-hydrogen atom. Herein, we report a C-H activation-based... 
oxidative Heck reaction | Synthetic methods | directing group | Catalyst | maleimides | DESIGN | ARYLATION | CHEMISTRY, ORGANIC | ALKYNES | SALTS | FREE-RADICALS | POTENT | BIOLOGICAL EVALUATION | INHIBITORS | ANHYDRIDES | Rh-III-Catalyst | UNSATURATED SYSTEMS
Journal Article
ChemInform, ISSN 0931-7597, 02/2016, Volume 47, Issue 9, pp. no - no
Maleimides add to the ortho‐position of aryl ketones to furnish regioselectively the o‐(succinimid‐3‐yl)aryl ketones in good to high yields. 
thiophene derivatives | ketones (benzene compounds) | catalysis, phase‐transfer catalysis | pyrrole derivatives | C‐C bond formation | Ketones | Thiophene | Catalysis
Journal Article
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