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ACS CATALYSIS, ISSN 2155-5435, 07/2015, Volume 5, Issue 7, pp. 4300 - 4308
New binepine ligands have been synthesized, and characterized and have been shown to induce high diastereo- and enantioselectivity in the intramolecular... 
PHOSPHEPINE | HYDROGENATION | chiral phosphines | INDOLINES | CHEMISTRY, PHYSICAL | C-C coupling C-H activation | asymmetric catalysis | CATALYST | INTRAMOLECULAR ALKANE ARYLATION | FUNCTIONALIZATION | C(SP)-H ACTIVATION | palladium | CHIRAL MONODENTATE PHOSPHINES | DERIVATIVES | ACCESS
Journal Article
Chemical Science, ISSN 2041-6520, 05/2013, Volume 4, Issue 5, pp. 2241 - 2247
We report a general palladium-catalyzed beta-arylation of Boc-piperidines, which yields a variety of valuable 3-arylpiperidines in a simple and direct manner.... 
H BOND ACTIVATION | LITHIOAMINE SYNTHETIC EQUIVALENTS | SUBSTITUTION | ENANTIOSELECTIVE SYNTHESIS | ALPHA-ARYLATION | DIPOLE-STABILIZED CARBANIONS | CHEMISTRY, MULTIDISCIPLINARY | ARYL CHLORIDES | PALLADIUM-CATALYZED AMINATION | CYCLIC AMINES | DIASTEREOISOMERS | Chemical Sciences | Catalysis
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 03/2014, Volume 53, Issue 10, pp. 2678 - 2682
The palladium‐catalyzed ligand‐controlled arylation of α‐zincated acyclic amines, obtained by directed α‐lithiation and transmetalation, is described. Whereas... 
density functional calculations | palladium | cross‐coupling | arylation | CC coupling | C-C coupling | cross-coupling | SUZUKI | CARBON | SCOPE | SECONDARY | CHEMISTRY, MULTIDISCIPLINARY | CC coupling | IN-SITU IR | ARYL | LITHIATION | Amines - chemistry | Ligands | Amines - chemical synthesis | Catalysis | Palladium - chemistry | Molecular Conformation
Journal Article
Organic and Biomolecular Chemistry, ISSN 1477-0520, 2009, Volume 7, Issue 17, pp. 3413 - 3420
Journal Article
Organic Letters, ISSN 1523-7060, 08/2017, Volume 19, Issue 16, pp. 4203 - 4206
4-Aminoquinolines were prepared in a three-step synthesis starting from substituted anthranilonitriles. The condensation on 1,1,1-trichloro-4-ethoxybut-3-enone... 
CHEMISTRY, ORGANIC | KETONES | ROUTE | FUNCTIONALIZED 4-AMINOQUINOLINES | DERIVATIVES | SUBSTITUTED QUINOLINES
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 12/2015, Volume 54, Issue 52, pp. 15744 - 15749
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 02/2012, Volume 18, Issue 7, pp. 1932 - 1944
Journal Article
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, ISSN 1433-7851, 12/2018, Volume 57, Issue 52, pp. 17089 - 17093
Molecular materials that possess a toroidal moment associated to a non-magnetic ground state are known as single-molecule toroics (SMTs) and are usually planar... 
ZERO-FIELD | GROUND-STATE | COMPLEXES | cubanes | single molecule toroics | CHEMISTRY, MULTIDISCIPLINARY | lanthanides | magnetic properties | MONONUCLEAR | SPINTRONICS | dysprosium | MAGNETIC-MOMENT | EXCHANGE | DYSPROSIUM TRIANGLES
Journal Article
ACS Catalysis, ISSN 2155-5435, 02/2016, Volume 6, Issue 2, pp. 1028 - 1036
Ethylene/butadiene copolymerization can be performed by neodymocene catalysts in the presence of an alkylating/chain transfer agent. A variety of... 
butadiene | copolymerization | DFT | mechanism | neodymocene | ethylene | CYCLO-COPOLYMERIZATION | MOLECULAR-ORBITAL METHODS | AB-INITIO | CHEMISTRY, PHYSICAL | POLYMERIZATION | DENSITY FUNCTIONALS | ENERGY-ADJUSTED PSEUDOPOTENTIALS | DIENE COPOLYMERIZATION | BASIS-SETS | MAGNESIUM COMPLEXES | CATALYSTS | Chemical Sciences
Journal Article
New Journal of Chemistry, ISSN 1144-0546, 2017, Volume 41, Issue 17, pp. 9210 - 9215
The Pd-catalyzed C-H arylation of heterocycles with aryl halides is a straightforward and more environmentally-friendly route to the synthesis of well-defined,... 
FUNCTIONALIZATION | POLYMERS | MECHANISM | FREE PALLADIUM | COMPLEXES | CHEMISTRY | HECK REACTIONS | BETA-ARYLATION | POLYCONDENSATION | CHEMISTRY, MULTIDISCIPLINARY | CATALYZED DIRECT ARYLATION
Journal Article
European Journal of Inorganic Chemistry, ISSN 1434-1948, 01/2018, Volume 2018, Issue 3-4, pp. 333 - 339
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 03/2014, Volume 53, Issue 10, pp. 2678 - 2682
The palladium‐catalyzed ligand‐controlled arylation of α‐zincated acyclic amines, obtained by directed α‐lithiation and transmetalation, is described. Whereas... 
Organic chemistry | Chemical Sciences
Journal Article
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, ISSN 1434-1948, 01/2018, Issue 3-4, pp. 333 - 339
A new family of three Dy-III mononuclear complexes and one DyIII chain system based on the same ligand [1,3-di(pyridin-4-yl)propane-1,3-dione] has been... 
Crystal structures | COMPLEXES | ION MAGNETS | STATE | RELAXATION | Dysprosium | ANISOTROPY | CHEMISTRY, INORGANIC & NUCLEAR | MAGNETOSTRUCTURAL CORRELATIONS | SYMMETRY | Single-molecule studies | Ab initio calculations | ABSORPTION | LIGAND | Magnetic properties
Journal Article
Organic Letters, ISSN 1523-7060, 10/2013, Volume 15, Issue 19, pp. 5056 - 5059
Silyl ketene acetals are shown to be competent nucleophiles in Pd-catalyzed migrative C(sp3)–H arylations. Compared to the parent ester lithium enolates, they... 
FUNCTIONALIZATION | ACTIVATION | KETO-ESTERS | ALPHA-ARYLATION | COUPLING REACTIONS | CHEMISTRY, ORGANIC | METAL | PIPERIDINES | ALKYL 2-ARYLALKANOATES | C-H BONDS | CARBOXYLIC-ACID DERIVATIVES | Organic chemistry | Chemical Sciences
Journal Article