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Chemistry : a European journal, ISSN 0947-6539, 2018, Volume 24, Issue 45, pp. 11795 - 11802
.... The dialane disproportionates into Al 0 and Al III when heated to 219 °C. In order to access lower oxidation states of aluminum, Schnöckel et al. introduced Cp* (Cp... 
aluminum | Lewis base | dialane | disproportionation | transition metals | RHODIUM | CP-ASTERISK-AL | COMPLEXES | COMPOUND | REACTIVITY | ADDUCT | CHEMISTRY, MULTIDISCIPLINARY | LIGANDS | AL-AL | BOND | PAIRS | Metals | Disproportionation
Journal Article
Inorganic Chemistry, ISSN 0020-1669, 08/2017, Volume 56, Issue 15, pp. 8996 - 9008
Herein, we report on the synthesis and structural characterization of a series of trigonal and tetrahedral cationic copper­(I) complexes, bearing phosphine or... 
MOLECULAR DESIGN | ENERGY-GAP LAW | DELAYED FLUORESCENCE | LIGANDS | LUMINESCENT YTTERBIUM | BASIS-SETS | CU(I) COMPLEXES | GENERALIZED GRADIENT APPROXIMATION | METAL-COMPLEXES | C-H | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Chemistry : a European journal, ISSN 0947-6539, 2018, Volume 24, Issue 1, pp. 266 - 273
... at the boron centers, enable the formation of kinetically stable diborene(4) compounds, [LRB=BRL], isoelectronic to R 2 C=CR 2 alkenes. A couple of Lewis base‐free... 
spectroscopy | boron | diborenes | electron donors | N-heterocyclic carbenes | INSERTION | AB-INITIO | COMPLEXES | CHEMISTRY, MULTIDISCIPLINARY | POTENTIAL CURVES | BORON MULTIPLE BONDS | CHALCOGENS | LIGANDS | BORYLENE | GENERATION | Coplanarity | Stability | Nuclear magnetic resonance--NMR | Crystallography | Destabilization | Electrons
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 2019, Volume 58, Issue 1, pp. 338 - 342
A new pathway for the ring expansion reaction of antiaromatic boroles with organic azides is reported. While the reaction usually leads to 1,2‐azaborinines, it... 
reaction mechanisms | azides | heterocycles | boron | ring expansion | ANTIAROMATICITY | MOLECULAR-STRUCTURE | CRYSTAL-STRUCTURE | FERROCENYLPYRIDINE | COMPLEXES | 1,3,2-DIAZAPHOSPHININES | CHEMISTRY, MULTIDISCIPLINARY | AROMATICITY | LIGANDS | PLATINUM(II) | PALLADIUM(II) | Azides (organic) | Pyridines | Transformation | Heterocyclic compounds | Reagents | Density functional theory | Benzonitrile
Journal Article
ISSN 1477-9226, 3/2016, Volume 45, Issue 13, pp. 5583 - 5589
Tridentate amine-imine-phosphine ligands, R 2 PC 5 H 7 NC 2 H 4 NEt 2 [ R PNN(H)], where R = Pr i or Bu t are synthesized using a straightforward protocol of... 
Journal Article
Inorganic chemistry, ISSN 0020-1669, 02/2019, Volume 58, Issue 4, pp. 2652 - 2658
A range of mono- and bis-adducts of beryllium dichloride with cyclic (alkyl)­(amino)­carbenes (CAAC), cyclic diamidocarbene (DAC), and carbodiphosphorane (CDP)... 
ORGANOMETALLIC COMPOUNDS | BONDING ANALYSIS | COMPLEXES | SOLID-STATE STRUCTURE | REACTIVITY | CRYSTAL-STRUCTURES | STRUCTURAL-CHARACTERIZATION | COORDINATION | N-HETEROCYCLIC CARBENES | MAIN-GROUP ELEMENTS | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Chemistry : a European journal, ISSN 0947-6539, 2017, Volume 23, Issue 64, pp. 16167 - 16170
Boroles are important motifs within functional materials. With the aim to prepare a pinacolboryl‐substituted derivative, the metallacycle transfer from... 
boranes | tin | multiple bonds | heterocycles | elimination | POLYMERS | RING EXPANSION | MAIN-GROUP | REACTIVITY | CHEMISTRY, MULTIDISCIPLINARY | PERFLUOROPENTAPHENYLBOROLE | PENTAPHENYLBOROLE | PENTAARYLBOROLES | RADII | CHEMISTRY | BOND | Zirconium | Tin | Boron | Oxygen atoms
Journal Article
Dalton transactions : an international journal of inorganic chemistry, ISSN 1477-9226, 2016, Volume 45, Issue 13, pp. 5583 - 5589
Simple condensation and deprotonation sequences allow the synthesis of modular tridentate ligands that mimic the coordination environment of the famous... 
ALCOHOLS | KETONES | N-HETEROCYCLIC CARBENE | DEHYDROGENATION | ACTIVATION | CONVERSION | ESTERS | COMPLEXES | HOMOGENEOUS CATALYTIC-HYDROGENATION | OSMIUM | CHEMISTRY, INORGANIC & NUCLEAR | Synthesis (chemistry) | Ruthenium | Catalysts | Precursors | Ligands | Activation | Benzyl alcohol | Phosphines
Journal Article
CHEMICAL COMMUNICATIONS, ISSN 1359-7345, 08/2018, Volume 54, Issue 65, pp. 9015 - 9018
.... In contrast, the reduction of the analogous cyclic (alkyl)(amino) carbene (CAAC) adduct yields a C-H activation product. 
BORYL ANION | TRIARYLBORON ANIONS | BORON-STABILIZED CARBANION | TRIMESITYLBORON | REACTIVITY | ANIONIC DIMETALLOBORYLENE COMPLEX | BORANE | 1,3,2,5-DIAZADIBORININE | RADICAL-ANION | CHEMISTRY, MULTIDISCIPLINARY | RAY CRYSTAL-STRUCTURE
Journal Article
Chemical science (Cambridge), ISSN 2041-6539, 2020, Volume 11, Issue 21, pp. 5559 - 5564
A cyclopentadienyl-substituted alumole is shown to undergo ring expansions with a series of organic azides, affording 1,2-azaaluminabenzenes either with or... 
ANTIAROMATICITY | BOROLES | INSERTION | ZIRCONACYCLOPENTADIENES | PENTAPHENYLBOROLE | COMPLEXES | METALLACYCLE TRANSFER | LIGAND | CHEMISTRY, MULTIDISCIPLINARY | CYCLIZATION | MOLECULES
Journal Article
Chemistry : a European journal, ISSN 1521-3765, 2019, Volume 25, Issue 72, pp. 16544 - 16549
The reactivity of a diruthenium tetrahydride complex towards three selected dihydroboranes was investigated. The use of [DurBH ] (Dur=2,3,5,6-Me C H) and [(Me Si) NBH... 
CP-ASTERISK | CATALYZED REACTIONS | dehydrocoupling | COMPLEXES | REACTIVITY | BORANE | (CP-ASTERISK-CR)B4H8 | CHEMISTRY, MULTIDISCIPLINARY | transition metal | KINETIC CONTROL LEADS | ruthenium | METALLABORANE CLUSTER | B-H activation | CHEMISTRY | boron | Organic chemistry | Chemical Sciences
Journal Article
Chemistry : a European journal, ISSN 0947-6539, 2019, Volume 25, Issue 72, pp. 16544 - 16549
Abstract The reactivity of a diruthenium tetrahydride complex towards three selected dihydroboranes was investigated. The use of [DurBH2] (Dur=2,3,5,6-Me4C6H)... 
ruthenium | boron | B−H activation | dehydrocoupling | transition metal | Bonding strength | Chains | Boron | Covalent bonds | Communications | Communication
Journal Article
Toxicology, ISSN 0300-483X, 2007, Volume 240, Issue 1, pp. 48 - 59
Journal Article