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chemistry, organic (60) 60
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Accounts of Chemical Research, ISSN 0001-4842, 05/2018, Volume 51, Issue 5, pp. 1272 - 1280
Conspectus Compounds containing a difluoromethylene unit have gained increasing attention due to their utility in drug design. Classic methods for the... 
MEDICINAL CHEMISTRY | PHOSPHONIUM SALTS | ACYL CHLORIDES | LIGHT | CARBONYL-COMPOUNDS | FLUORINE | ALDEHYDES | NUCLEOPHILIC DIFLUOROMETHYLATION | FLUOROALKYLATION REACTIONS | CHEMISTRY, MULTIDISCIPLINARY | DIFLUORINATED ORGANOZINC REAGENTS
Journal Article
European Journal of Organic Chemistry, ISSN 1434-193X, 01/2020, Volume 2020, Issue 3, pp. 393 - 396
A method for the photoredox fluoroalkylation of the C–H bond of azomethine compounds obtained from condensation of aldehydes and N‐methylpyrrolidinone‐derived... 
Radical reactions | Fluorine | Azomethines | Photocatalysis | Fluoroalkylation | HYDRAZONES | DESIGN | LIGHT | CHEMISTRY, ORGANIC | DIFLUOROALKYLATION | PERFLUOROALKYLATION | C(SP)-H FUNCTIONALIZATION | COPPER-CATALYZED TRIFLUOROMETHYLATION
Journal Article
Beilstein Journal of Organic Chemistry, ISSN 1860-5397, 07/2018, Volume 14, Issue 1, pp. 1637 - 1641
Journal Article
The Journal of Organic Chemistry, ISSN 0022-3263, 01/2018, Volume 83, Issue 1, pp. 478 - 483
A cross-coupling of acyl chlorides with gem-difluorinated organozinc reagents affording difluorinated ketones is described. In the reaction, acyl chlorides are... 
KETONES | DIFLUOROMETHYLATION | PRACTICAL SYNTHESIS | ACID | DIFLUOROCARBENE | ARYL HALIDES | CHEMISTRY, ORGANIC | FLUORINE | METAL CATALYSIS | ORGANOMETALLICS | ELECTROPHILES | Chemical reactions | Usage | Dichloropropane | Chemical properties | Chlorides
Journal Article
European Journal of Organic Chemistry, ISSN 1434-193X, 07/2019, Volume 2019, Issue 26, pp. 4119 - 4122
A method for the synthesis of bromodifluoromethyl‐substituted hydroxylamines via reaction of nitrones with dibromodifluoromethane is described. The reaction is... 
Nitrones | Radical reactions | Fluorine | Photocatalysis | Fluoroalkylation | ALKENES | IODODIFLUOROMETHYLATION | CHEMISTRY, ORGANIC | FLUOROALKYLATION REACTIONS | RADICAL-ADDITION | PHOTOREDOX CATALYSIS | TRIFLUOROMETHYLATION
Journal Article
Journal of Organic Chemistry, ISSN 0022-3263, 06/2019, Volume 84, Issue 12, pp. 8337 - 8343
A convenient method for performing a thiol-ene reaction is described. The reaction is performed under blue-light irradiation and catalyzed by photoactive Lewis... 
ACRIDINE-ORANGE | ALKENES | ROUTE | ACID | CLICK REACTION | PHOTOCATALYTIC INITIATION | POLYMER | CHEMISTRY | CHEMISTRY, ORGANIC | HYDROTHIOLATION | DERIVATIVES
Journal Article
Tetrahedron Letters, ISSN 0040-4039, 09/2016, Volume 57, Issue 36, pp. 3986 - 3992
Novel methods for the preparation and reactions of organozinc reagents are reviewed. [Display omitted] •Generation of organozinc reagents.•Halogen–zinc... 
Organozinc reagents | Negishi cross-coupling | Halogen/zinc exchange | Transmetalation | 3-COMPONENT SYNTHESIS | HIGHLY SELECTIVE METALATIONS | SECONDARY | CHEMISTRY, ORGANIC | ORGANOMETALLICS | ALKYL-HALIDES | BASE | MAGNESIUM | ZINC REAGENTS | ARYLZINC REAGENTS | COBALT-CATALYZED ADDITION | Chemical tests and reagents | Nitriles
Journal Article
Advanced Synthesis & Catalysis, ISSN 1615-4150, 10/2018, Volume 360, Issue 19, pp. 3788 - 3792
Journal Article
CHEMICAL SCIENCE, ISSN 2041-6520, 01/2020, Volume 11, Issue 3, pp. 737 - 741
A 4-tetrafluoropyridinylthio group was suggested as a new photoredox-active moiety. The group can be directly installed on difluorostyrenes in a single step by... 
CATALYSIS | REAGENTS | CHEMISTRY, MULTIDISCIPLINARY | ACCESS | FLUOROALKYLATION | TRIFLUOROMETHYLATION
Journal Article
Synthesis, ISSN 0039-7881, 08/2018, Volume 50, Issue 15, pp. 2930 - 2935
Abstract Benzyl and allyl halides undergo homocoupling when treated with zinc in the presence of a catalytic amount of a cationic iridium(III) complex under... 
special topic | free radicals | photoredox | homocoupling | organozinc reagents | organic halides | ORGANIC-SYNTHESIS | CATALYSIS | ACTIVATION | MECHANISM | CHEMISTRY, ORGANIC | BROMIDES | C-H BONDS | REDUCTION | METAL | GENERATION | GRIGNARD-REAGENTS
Journal Article
Organic Letters, ISSN 1523-7060, 02/2013, Volume 15, Issue 4, pp. 917 - 919
Journal Article
Organic Letters, ISSN 1523-7060, 03/2016, Volume 18, Issue 5, pp. 996 - 999
gem-Difluorinated phosphonium salts, which are readily obtained from aldehydes and difluoromethylene phosphobetaine, can serve as a source of radicals under... 
ORGANOZINC REAGENTS | VISIBLE-LIGHT | ALKENES | DIFLUOROCARBENE | BROMODIFLUOROMETHYLATION | DIFLUOROMETHYL | CHEMISTRY, ORGANIC | CARBONYL-COMPOUNDS | TRANSFER RADICAL-ADDITION | PHOTOREDOX CATALYSIS | TRIFLUOROMETHYLATION
Journal Article
Organic Letters, ISSN 1523-7060, 02/2015, Volume 17, Issue 3, pp. 760 - 763
Journal Article
Journal of Organic Chemistry, ISSN 0022-3263, 01/2014, Volume 79, Issue 2, pp. 818 - 822
Journal Article
Organic Letters, ISSN 1523-7060, 02/2018, Volume 20, Issue 3, pp. 840 - 843
A method for the addition of fluorinated groups to nitrones using an iridium photocatalyst and ascorbic acid as a stoichiometric reducing agent is described.... 
MEDICINAL CHEMISTRY | HYDRAZONES | VISIBLE-LIGHT | REAGENTS | COMPLEXES | LIGHT PHOTOREDOX CATALYSIS | CHEMISTRY, ORGANIC | FLUORINE | RADICALS | PERFLUOROALKYLATION REACTIONS | TRIFLUOROMETHYLATION
Journal Article
JOURNAL OF ORGANIC CHEMISTRY, ISSN 0022-3263, 09/2019, Volume 84, Issue 17, pp. 11068 - 11079
The atom transfer radical addition reaction catalyzed by triphenylphosphine and copper(I) halide is described. The reaction proceeds under irradiation with 365... 
ALKENES | PHOSPHONIUM SALTS | HEXAFLUOROPROPENE | IODOPERFLUOROALKYLATION | CHEMISTRY, ORGANIC | OLEFINS | POLYMERIZATION | GENERATION | ALKYLATIONS | ATRA | PHOTOREDOX CATALYSIS
Journal Article
ISSN 1359-7345, 1/2019, Volume 55, Issue 9, pp. 1314 - 1317
A method for the assembly of the halodifluoromethyl group (CF 2 X, X = Cl, Br, I) is described. The reaction involves the light-mediated substitution of the... 
Journal Article
Chemical Communications : Chem Comm, ISSN 1359-7345, 01/2019, Volume 55, Issue 9, pp. 1314 - 1317
A method for the assembly of the halodifluoromethyl group (CF2X, X = Cl, Br, I) is described. The reaction involves the light-mediated substitution of the... 
Nuclear magnetic resonance--NMR | Substitution reactions
Journal Article
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