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Science, ISSN 0036-8075, 2/2012, Volume 335, Issue 6068, pp. 567 - 570
Alkene hydrosilylation, the addition of a silicon hydride (Si-H) across a carbon-carbon double bond, is one of the largest-scale industrial applications of... 
Silanes | Side effects | Alkenes | Catalysts | Platinum | Isomerization | REPORTS | Iron | Silicon | Catalysis | Silicones | TRANSITION-METAL-COMPLEXES | DINITROGEN | MULTIDISCIPLINARY SCIENCES | Silicon compounds | Research | Olefins | Chemical bonds | Chemical reactions | Chemical compounds | Iron catalysts
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 10/2019, Volume 25, Issue 57, pp. 13202 - 13207
The industry‐scale production of methylchloromonosilanes in the Müller–Rochow Direct Process is accompanied by the formation of a residue, the direct process... 
disilane cleavage | lithium chloride | lithium hydride | monosilanes | alkali and alkaline earth metal salts | Aluminum compounds | Dichloropropane | Chlorides | Silane | Lithium compounds | Metal hydrides | Salts | Disproportionation | Chlorine | Lithium chloride | Alkali metals | Metals | Lithium | Reintroduction | Earth | Alkaline earth metals | Reduction | Siloxane | Cleavage | Lithium chlorides | Lithium hydrides | Full Paper | Full Papers
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 03/2019, Volume 25, Issue 15, pp. 3698 - 3698
Invited for the cover of this issue is the group of Norbert Auner at the Goethe‐Universität Frankfurt am Main, Germany. The image depicts the Müller–Rochow... 
Chlorides | Silane | Dichloropropane
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 03/2019, Volume 25, Issue 15, pp. 3809 - 3815
The Müller–Rochow direct process (DP) for the large‐scale production of methylchlorosilanes MenSiCl4−n (n=1–3) generates a disilane residue (MenSi2Cl6−n,... 
silanes | silicon | direct process residue | cleavage reactions | phosphonium chlorides | DISPROPORTIONATION | MECHANISM | CONVERSION | ELIMINATION | METHYLCHLORODISILANES | THERMAL-DECOMPOSITION | CHEMISTRY, MULTIDISCIPLINARY | POLAR LINKINGS | SI-SI BOND | POLES | RESIDUE | Dichloropropane | Hydrogen | Chlorides | Silane | Phosphorus | Cleavage | Hydrogen chlorides | Catalysts | Ethers
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 06/2019, Volume 25, Issue 36, pp. 8499 - 8502
The industrial production of monosilanes MenSiCl4−n (n=1–3) through the Müller–Rochow Direct Process generates disilanes MenSi2Cl6−n (n=2–6) as unwanted... 
silanes | density functional calculations | disilane cleavage | direct process residue | bifunctional monosilanes | CONVERSION | METHYLCHLORODISILANES | CLEAVAGE | CHEMISTRY, MULTIDISCIPLINARY | CHLOROSILANES | SI-SI BOND | SELECTIVE SYNTHESIS | SPECTRUM | CATION | HALOSILANES | Hydrogenation | Usage | Silane | Byproducts | Industrial production | Metal hydrides | Side reactions | Incineration | Coordination compounds
Journal Article
Macromolecular Chemistry and Physics, ISSN 1022-1352, 12/2019, Volume 220, Issue 23, pp. 1900408 - n/a
The influence of a backbone microstructure on the side chain crystallization of a comb‐like polymer is analyzed systematically using a tailor‐made random... 
block copolymers | order–disorder transition | X‐ray diffraction | lamellar packing | polysiloxane | self‐assembly | Backbone | Temperature dependence | Chain mobility | Siloxanes | Crystallization | Block copolymers | Molecular chains | Hexagonal lattice | Molecular conformation | Chain dynamics | Polymers | Microstructure | Low temperature
Journal Article
1993, Studies in organic chemistry, ISBN 0444817158, Volume 49, xix, 644
Book
Chemistry – A European Journal, ISSN 0947-6539, 03/2019, Volume 25, Issue 15, pp. 3695 - 3695
The large‐scale production of methylchloromonosilanes by the Müller–Rochow Direct Process represents an entry into the silicone industry. Along with the main... 
silanes | silicon | direct process residue | cleavage reactions | phosphonium chlorides
Journal Article
Macromolecular Chemistry and Physics, ISSN 1022-1352, 12/2019, Volume 220, Issue 23, pp. 1970048 - n/a
Back Cover: In article number 1900408, Debarshi Dasgupta and co‐workers unveil how controlling the microstructure reinforces the structural stability of alkyl... 
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 08/2014, Volume 136, Issue 34, pp. 12108 - 12118
The aryl-substituted bis­(imino)­pyridine cobalt methyl complex, (MesPDI)­CoCH3 (MesPDI = 2,6-(2,4,6-Me3C6H2-NCMe)2C5H3N), promotes the catalytic... 
ELECTRONIC-STRUCTURES | CARBONYL-COMPLEXES | HYDROGENATION | IRON CATALYSTS | HYDROSILATION | CHEMISTRY, MULTIDISCIPLINARY | ANTI-HYDROSILYLATION | RUTHENIUM COMPLEX | TERMINAL ALKENES | SIGMA-BOND METATHESIS | VINYL-SILANES
Journal Article
Organometallics, ISSN 0276-7333, 07/2012, Volume 31, Issue 13, pp. 4886 - 4893
Iron dialkyl complexes, [N3]Fe(CH2SiMe3)2, with three different classes of tridentate, nitrogen-based “[N3]” ligands, aryl-substituted bis(imino)pyridines,... 
HYBRID DFT | AUXILIARY BASIS-SETS | ATOMS LI | APPROXIMATE | TRANSITION-METAL-COMPLEXES | ZETA VALENCE QUALITY | CHEMISTRY, ORGANIC | EFFICIENT | GAUSSIAN-BASIS SETS | CATALYSTS | PREDICTION | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
ACS Catalysis, ISSN 2155-5435, 10/2012, Volume 2, Issue 10, pp. 2169 - 2172
Aryl-substituted bis(imino)pyridine iron dinitrogen complexes are active for the hydrosilylation of 1,2,4-trivinylcyclohexane with tertiary alkoxy silanes, a... 
Hydrosilylation | Iron | Catalysis | Trivinylcyclohexene | Silane | trivinylcyclohexene | HYDROGENATION | silane | COMPLEXES | hydrosilylation | DINITROGEN | CHEMISTRY, PHYSICAL | iron | catalysis
Journal Article
The AAPS Journal, ISSN 1550-7416, 1/2020, Volume 22, Issue 1, pp. 1 - 7
The phase-appropriate application of analytical methods to characterize, monitor, and control particles is an important aspect of the development of safe and... 
Biochemistry, general | Biotechnology | Biomedicine | control strategy | Pharmacy | protein aggregation | drug product | subvisible particles | Pharmacology/Toxicology | biotech
Journal Article
Applied Organometallic Chemistry, ISSN 0268-2605, 03/2010, Volume 24, Issue 3, pp. 222 - 228
Recently, metal nanoparticles have found applications in various fields, which have necessitated exploration of new avenues to obtain such materials. In this... 
trioctylamine | stabilizing agents | metal nanoparticles | octadecylsilane | TEM | Metal nanoparticles | Octadecylsilane | Trioctylamine | Stabilizing agents | ZEROVALENT PALLADIUM | CROSS-COUPLING REACTION | HECK | MECHANISM | BOND FORMATION | COLLOIDS | IRON | CHEMISTRY, INORGANIC & NUCLEAR | METALS | MONODISPERSE PALLADIUM NANOPARTICLES | CHEMISTRY, APPLIED | CATALYTIC-ACTIVITY
Journal Article
Anthropology Today, ISSN 0268-540X, 04/2004, Volume 20, Issue 2, pp. 4 - 9
This article forms part of an ongoing debate on rights and the use of the term indigenous, which has so far included exchanges in Current Anthropology, the New... 
Apartheid | Forests | Land resources | Hunter gatherers | Political debate | Anthropology | Paleoanthropology | Political anthropology | Racism | Indigenous peoples
Journal Article
10/2019
There is provided novel mono-acrylate functionalized siloxane monomer containing carbosiloxane linkage for improved hydrolysis resistance. This invention also... 
MISCELLANEOUS APPLICATIONS OF MATERIALS | HYGIENE | BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES, AS HERBICIDES | TRAPPING | ORGANIC MACROMOLECULAR COMPOUNDS | ANIMAL HUSBANDRY | USE OF MATERIALS THEREFOR | THEIR PREPARATION OR CHEMICAL WORKING-UP | MEDICAL OR VETERINARY SCIENCE | FILLING PASTES | PLANT GROWTH REGULATORS | PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTSTHEREOF | MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENTSUBCLASSES OF CLASS C05 | ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAININGELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN,SULFUR, SELENIUM OR TELLURIUM | FISHING | MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVINGA SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES,SOIL-CONDITIONERS, WETTING AGENTS | MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONSONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS | CHEMICAL PAINT OR INK REMOVERS | CHEMISTRY | COATING COMPOSITIONS, e.g. PAINTS, VARNISHES ORLACQUERS | MANUFACTURE THEREOF | FORESTRY | FERTILISERS | MISCELLANEOUS COMPOSITIONS | DYES | WOODSTAINS | AGRICULTURE | FERTILISERS CHARACTERISED BY THEIR FORM | CORRECTING FLUIDS | ORGANIC CHEMISTRY | PEST REPELLANTS OR ATTRACTANTS | HUMAN NECESSITIES | MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVINGCARBON-TO-CARBON UNSATURATED BONDS | ADHESIVES | PAINTS | INKS | HUNTING | METALLURGY | PASTES OR SOLIDS FOR COLOURING OR PRINTING | PREPARATIONS FOR MEDICAL, DENTAL, OR TOILET PURPOSES | POLISHES | NATURAL RESINS | COMPOSITIONS BASED THEREON
Patent
09/2019
A water soluble silicone macromer comprising a siloxane backbone having grafted thereto a suitable number of hydrophilic groups to render the macromer water... 
SURGERY | HYGIENE | OPTICAL ELEMENTS, SYSTEMS, OR APPARATUS | FILTERS IMPLANTABLE INTO BLOOD VESSELS | ORGANIC MACROMOLECULAR COMPOUNDS | THEIR PREPARATION OR CHEMICAL WORKING-UP | MEDICAL OR VETERINARY SCIENCE | DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF,TUBULAR STRUCTURES OF THE BODY, E.G. STENTS | FIRST-AID KITS | CONTACT LENSES | MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS, OR SURGICALARTICLES | ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES | BANDAGES, DRESSINGS OR ABSORBENT PADS | SPECTACLES | MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONSONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS | CHEMISTRY | PROSTHESES | OPTICS | TREATMENT OR PROTECTION OF EYES OR EARS | DIAGNOSIS | TRANSPORTING | SUNGLASSES OR GOGGLES INSOFAR AS THEY HAVE THE SAME FEATURESAS SPECTACLES | LAYERED PRODUCTS | HUMAN NECESSITIES | IDENTIFICATION | DISINFECTION, STERILISATION, OR DEODORISATION OF AIR | COMPOSITIONS OF MACROMOLECULAR COMPOUNDS | MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVINGCARBON-TO-CARBON UNSATURATED BONDS | LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT ORNON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM | METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS INGENERAL | CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS, ORSURGICAL ARTICLES | METALLURGY | PHYSICS | PERFORMING OPERATIONS | COMPOSITIONS BASED THEREON | FOMENTATION
Patent
Applied Surface Science, ISSN 0169-4332, 1994, Volume 78, Issue 4, p. 485
Journal Article
10/2017
There is provided novel mono-acrylate functionalized siloxane monomer containing carbosiloxane linkage for improved hydrolysis resistance. This invention also... 
MISCELLANEOUS APPLICATIONS OF MATERIALS | HYGIENE | BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES, AS HERBICIDES | TRAPPING | ORGANIC MACROMOLECULAR COMPOUNDS | ANIMAL HUSBANDRY | USE OF MATERIALS THEREFOR | THEIR PREPARATION OR CHEMICAL WORKING-UP | MEDICAL OR VETERINARY SCIENCE | FILLING PASTES | PLANT GROWTH REGULATORS | PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTSTHEREOF | MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENTSUBCLASSES OF CLASS C05 | ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAININGELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN,SULFUR, SELENIUM OR TELLURIUM | FISHING | MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVINGA SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES,SOIL-CONDITIONERS, WETTING AGENTS | MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONSONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS | CHEMICAL PAINT OR INK REMOVERS | CHEMISTRY | COATING COMPOSITIONS, e.g. PAINTS, VARNISHES ORLACQUERS | MANUFACTURE THEREOF | FORESTRY | FERTILISERS | MISCELLANEOUS COMPOSITIONS | DYES | WOODSTAINS | AGRICULTURE | FERTILISERS CHARACTERISED BY THEIR FORM | CORRECTING FLUIDS | ORGANIC CHEMISTRY | PEST REPELLANTS OR ATTRACTANTS | HUMAN NECESSITIES | MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVINGCARBON-TO-CARBON UNSATURATED BONDS | ADHESIVES | PAINTS | INKS | HUNTING | METALLURGY | PASTES OR SOLIDS FOR COLOURING OR PRINTING | PREPARATIONS FOR MEDICAL, DENTAL, OR TOILET PURPOSES | POLISHES | NATURAL RESINS | COMPOSITIONS BASED THEREON
Patent
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