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ISSN 1359-7345, 8/2018, Volume 54, Issue 69, pp. 9643 - 9646
Cobalt( ii ) complexes with the general structure [Co II (OTf)( Y,X Py 2 Ts tacn)](OTf) ( 1 R , where Y,X Py 2 Ts tacn is 1,4-di( p -Y, m -X-picolyl)-7- R... 
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 02/2015, Volume 54, Issue 9, pp. 2729 - 2733
Highly enantioselective epoxidation of α‐substituted styrenes with aqueous H2O2 is described by using a chiral iron complex as the catalyst and N‐protected... 
bioinspired catalysis | epoxidation | non‐heme iron complexes | asymmetric catalysis | amino acids | Epoxidation | Amino acids | Non-heme iron complexes | Asymmetric catalysis | Bioinspired catalysis
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 05/2014, Volume 20, Issue 20, pp. 6171 - 6183
The synthesis and characterisation of the pentadentate ligand 1,4‐di(picolyl)‐7‐(p‐toluenesulfonyl)‐1,4,7‐triazacyclononane (Py2Tstacn) and their metal... 
water reduction | cobalt | hydrogen | electrochemistry | homogeneous catalysis | photochemistry
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 04/2018, Volume 57, Issue 17, pp. 4603 - 4606
We report here the first purely organometallic fac‐[MnI(CO)3(bis‐MeNHC)Br] complex with unprecedented activity for the selective electrocatalytic reduction of... 
spectroelectrochemistry | carbon dioxide | electrocatalysis | manganese | N-heterocyclic carbenes | ACIDS | BULKY BIPYRIDINE LIGANDS | TRICARBONYL COMPLEXES | CARBON-DIOXIDE | MOLECULAR CATALYSIS | CHEMISTRY, MULTIDISCIPLINARY | LOCAL PROTON SOURCE | Heterocyclic compounds | Chemical reduction | Catalysis | Carbon monoxide | Catalysts | Carbon dioxide | Manganese | Communications | Communication
Journal Article
Nature Chemistry, ISSN 1755-4330, 10/2011, Volume 3, Issue 10, pp. 807 - 813
Water oxidation catalysis constitutes the bottleneck for the development of energy-conversion schemes based on sunlight. To date, state-of-the-art homogeneous... 
NONHEME IRON | ELECTRON-TRANSFER | LIGANDS | MODELS | CHEMISTRY, MULTIDISCIPLINARY | EPOXIDATION | PEROXO | Nitrates - chemistry | Oxidation-Reduction | Cerium - chemistry | Iron - chemistry | Oxides - chemistry | Water - chemistry | Catalysis | Kinetics | Coordination Complexes - chemistry | Spectrophotometry, Ultraviolet | Hydrogen-Ion Concentration | Periodic Acid - chemistry
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 05/2014, Volume 20, Issue 19, pp. 5696 - 5707
Density functional theory (DFT) is employed to: 1) propose a viable catalytic cycle consistent with our experimental results for the mechanism of chemically... 
reaction mechanisms | density functional calculations | ligands | iron | redox chemistry | CO2 REDUCTION | SOLAR-ENERGY | O BOND FORMATION | CHEMISTRY, MULTIDISCIPLINARY | RUTHENIUM CATALYST | ARTIFICIAL LEAF | DENSITY | HYDROGEN | COUPLED ELECTRON-TRANSFER | PHOTOSYSTEM-II | QUANTUM-CHEMICAL CHARACTERIZATION | Oxidation-reduction reaction | Analysis | Iron | Ligands | Oxidation | Valence | Catalysts | Barriers | Catalysis | Bonding
Journal Article
Chemical Communications, ISSN 1359-7345, 2018, Volume 54, Issue 69, pp. 9643 - 9646
Cobalt(ii) complexes with the general structure [Co-II(OTf)((Y,X)Py(2)(Ts)tacn)](OTf) (1(R), where (Y,X)Py(2)(Ts)tacn is... 
ALCOHOLS | NANOPARTICLES | PHOTOCATALYTIC REDUCTION | AROMATIC KETONES | SOLAR-ENERGY | HYDROGEN-PRODUCTION | POWER | ALDEHYDES | CHEMISTRY, MULTIDISCIPLINARY | Organic chemistry | Reduction | Ketones | Acetophenone | Electron transfer | Selectivity | Catalysis | Cobalt compounds
Journal Article
Angewandte Chemie, ISSN 0044-8249, 04/2018, Volume 130, Issue 17, pp. 4693 - 4696
We report here the first purely organometallic fac‐[MnI(CO)3(bis‐MeNHC)Br] complex with unprecedented activity for the selective electrocatalytic reduction of... 
Elektrokatalyse | Spektroelektrochemie | N-heterocyclische Carbene | Kohlendioxid | Mangan | Heterocyclic compounds | Chemical reduction | Catalysis | Carbon monoxide | Catalysts | Carbon dioxide | Manganese
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 06/2013, Volume 19, Issue 25, pp. 8042 - 8047
Getting in tune: Systematic tuning of the electronic properties of modular non‐heme iron coordination complexes can be used to extract important information on... 
electronic effects | iron | homogeneous catalysis | water oxidation | OXYGEN EVOLUTION | MECHANISM | KINETICS | PHOTOSYSTEM-II | O BOND FORMATION | CHEMISTRY, MULTIDISCIPLINARY | RUTHENIUM CATALYST | OXO COMPLEXES | Oxidation-reduction reaction | Iron | Iron and steel industry | Catalysts | Electronics | Oxidation | Modular | Catalysis | Tuning
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 03/2012, Volume 18, Issue 12, pp. 3721 - 3728
A series of chiral mono‐, di‐, and trinuclear gold(I) complexes have been prepared and used as precatalysts in the asymmetric cyclohydroamination of... 
enantioselectivity | gold | asymmetric catalysis | modular ligands | hydroamination | Equivalence | Asymmetry | Catalysts | Rendering | Congeners | Catalysis | Touch | Symmetry
Journal Article
Angewandte Chemie, ISSN 0044-8249, 04/2019, Volume 131, Issue 15, pp. 4923 - 4928
The chemical inertness of abundant and commercially available alkyl chlorides precludes their widespread use as reactants in chemical transformations.... 
Synthesemethoden | Cyclisierungen | Reaktionsmechanismen | Photochemie | Halogenalkane | Dichloropropane | Catalysis | Metal catalysts | Cobalt | Olefins | Chlorides | Organic chemistry | Alkenes | Catalysts | Bonding strength | Nickel | Basicity
Journal Article
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