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Journal of the American Chemical Society, ISSN 0002-7863, 01/2015, Volume 137, Issue 1, pp. 42 - 45
A zerovalent copper- and cobalt-catalyzed direct coupling of the sp3 α-carbon of alcohols with alkenes and hydroperoxides was developed in which the... 
Journal Article
Synthesis (Germany), ISSN 0039-7881, 2019, Volume 51, Issue 5, pp. 1049 - 1062
Journal Article
Synthesis, ISSN 0039-7881, 03/2019, Volume 51, Issue 5, pp. 1049 - 1062
Abstract Alkenes are ubiquitous in Nature and their functionalization continues to attract attention from the scientific community. On the other hand,... 
short review
Journal Article
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, ISSN 0002-7863, 01/2015, Volume 137, Issue 1, pp. 42 - 45
A zerovalent copper- and cobalt-catalyzed direct coupling of the sp(3) alpha-carbon of alcohols with alkenes and hydroperoxides was developed in which the... 
C(SP)-H BONDS | ALLYLIC ALCOHOLS | CARBONYLATION-PEROXIDATION | ASYMMETRIC ADDITION | BOND ACTIVATION | ENANTIOSELECTIVE ADDITION | AROMATIC-ALDEHYDES | C-H FUNCTIONALIZATION | NUCLEOPHILIC-ADDITION | CHEMISTRY, MULTIDISCIPLINARY | GRIGNARD-REAGENTS
Journal Article
Chemical Science, ISSN 2041-6520, 12/2012, Volume 3, Issue 12, pp. 3458 - 3462
Copper-catalyzed olefinic trifluoromethylation and oxytrifluoromethylation of enamides is reported. The direct olefinic C-H trifluoromethylation constitutes an... 
BORONIC ACIDS | HYPERVALENT IODINE | MEDIATED TRIFLUOROMETHYLATION | BOND FORMATION | FLUORINE | ARYL | ENANTIOSELECTIVE ALPHA-TRIFLUOROMETHYLATION | OXIDATIVE TRIFLUOROMETHYLATION | ELECTROPHILIC TRIFLUOROMETHYLATION | CHEMISTRY, MULTIDISCIPLINARY | TERMINAL ALKENES | Synthesis
Journal Article
Chem. Sci, ISSN 2041-6520, 2014, Volume 5, Issue 12, pp. 4939 - 4943
This paper describes an efficient method to β-keto methyl sulfones and (E)-vinyl methyl sulfones using DMSO as the substrate. The methyl sulfonyl radical... 
Journal Article
Chemical Science, ISSN 2041-6520, 12/2014, Volume 5, Issue 12, pp. 4939 - 4943
This paper describes an efficient method to beta-keto methyl sulfones and (E)-vinyl methyl sulfones using DMSO as the substrate. The methyl sulfonyl radical... 
OXIDATION | C-S BOND | BETA-KETO-SULFONES | DIMETHYLSULFOXIDE | EFFICIENT SYNTHESIS | OH-RADICALS | HYDROGEN-PEROXIDE | DIMETHYL-SULFOXIDE | DERIVATIVES | CHEMISTRY, MULTIDISCIPLINARY | AEROBIC OXYSULFONYLATION | Alkenes | Catalysts | Catalysis | Copper | Sulfones | Radicals | Alkynes | Isotopic labeling
Journal Article
Angewandte Chemie, ISSN 1433-7851, 03/2014, Volume 53, Issue 10, p. 2722
  The rhodium(III)-catalyzed ortho CH alkynylation of non-electronically activated arenes is disclosed. This process features a straightforward and highly... 
Journal Article
Chemical Communications, ISSN 1359-7345, 11/2012, Volume 48, Issue 91, pp. 11232 - 11234
Ruthenium- and rhodium-catalyzed direct oxidative cross-coupling reactions of acrylamides with alkenes were developed. These methods provide an efficient route... 
H BOND ACTIVATION | OXIDATIVE OLEFINATION | FUNCTIONALIZATIONS | MECHANISM | 2-PYRIDONES | CYTOTOXIC MACROLIDE | SELECTIVE SYNTHESIS | LINEAR 1,3-BUTADIENES | CHEMISTRY, MULTIDISCIPLINARY | ALKENYLATION | ACRYLATES | Alkenes - chemistry | Oxidation-Reduction | Stereoisomerism | Amides - chemistry | Catalysis | Ruthenium - chemistry | Rhodium - chemistry | Acrylamides - chemistry
Journal Article
ISSN 2041-6520, 10/2014, Volume 5, Issue 12, pp. 4939 - 4943
This paper describes an efficient method to β-keto methyl sulfones and ( E )-vinyl methyl sulfones using DMSO as the substrate. The methyl sulfonyl radical... 
Journal Article
Organic Letters, ISSN 1523-7060, 07/2015, Volume 17, Issue 13, pp. 3210 - 3213
A protocol,enabled by rhodium-catalyzed C-H functionalization of indoles with acryloyl silanes was developed, providing a convenient and highly effective... 
DIRECTING GROUP | ROOM-TEMPERATURE | MILD CONDITIONS | COUPLING REACTION | ARENES | CHEMISTRY, ORGANIC | OXIDATIVE ANNULATION | INTERNAL ALKYNES | BOND-CLEAVAGE | ACYLSILANES | CONJUGATE ADDITION
Journal Article
Chemical Communications, ISSN 1359-7345, 10/2011, Volume 47, Issue 37, pp. 10458 - 10460
Cationic rhodium complex-catalyzed olefination of phenol derivatives for the direct introduction of an alpha,beta-unsaturated ester appendage is described. In... 
ACTIVATION | ACID | BOND FUNCTIONALIZATION | REACTIVITY | OXIDATIVE COUPLING REACTION | ANILIDES | BENZENES | EFFICIENT | CHEMISTRY, MULTIDISCIPLINARY | ALKENYLATION | INDOLES
Journal Article
ISSN 1359-7345, 5/2018, Volume 54, Issue 44, pp. 5618 - 5621
Herein we demonstrate that an alkylation of indoles could be accessed through C-H bond functionalization with α,α-difluorovinyl tosylate. The key aspect for... 
Journal Article
Nature Communications, ISSN 2041-1723, 06/2015, Volume 6, Issue 1, p. 7472
Fluoroalkenes represent a class of privileged structural motifs, which found widespread use in medicinal chemistry. However, the synthetic access to... 
OLEFINIC TRIFLUOROMETHYLATION | CRAFTS-TYPE CYCLIZATION | H FLUOROALKENYLATION | VINYLIC FLUORINES | MULTIDISCIPLINARY SCIENCES | ARENES | ARYL | ALKYNES | CLEAVAGE | 5-ENDO-TRIG CYCLIZATION | FLUOROOLEFINS
Journal Article
Organic Letters, ISSN 1523-7060, 06/2013, Volume 15, Issue 12, pp. 2914 - 2917
An efficient catalytic enantioselective hetero-Diels–Alder reaction of Danishefsky’s dienes with α-carbonyl esters using a chiral In(III)–pybox complex has... 
Journal Article
Chemical communications (Cambridge, England), ISSN 1359-7345, 09/2014, Volume 50, Issue 69, pp. 9865 - 9868
Rh(III)-catalyzed C-H olefinic alkynylation of enamides for the stereospecific construction of synthetically useful Z-type enynamides is reported. This... 
Journal Article
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