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Nature Communications, ISSN 2041-1723, 06/2015, Volume 6, Issue 1, p. 7472
Fluoroalkenes represent a class of privileged structural motifs, which found widespread use in medicinal chemistry. However, the synthetic access to... 
OLEFINIC TRIFLUOROMETHYLATION | CRAFTS-TYPE CYCLIZATION | H FLUOROALKENYLATION | VINYLIC FLUORINES | MULTIDISCIPLINARY SCIENCES | ARENES | ARYL | ALKYNES | CLEAVAGE | 5-ENDO-TRIG CYCLIZATION | FLUOROOLEFINS
Journal Article
Chem. Sci, ISSN 2041-6520, 2014, Volume 5, Issue 12, pp. 4939 - 4943
This paper describes an efficient method to β-keto methyl sulfones and (E)-vinyl methyl sulfones using DMSO as the substrate. The methyl sulfonyl radical... 
Journal Article
Chemical Communications, ISSN 1359-7345, 11/2012, Volume 48, Issue 91, pp. 11232 - 11234
Ruthenium- and rhodium-catalyzed direct oxidative cross-coupling reactions of acrylamides with alkenes were developed. These methods provide an efficient route... 
H BOND ACTIVATION | OXIDATIVE OLEFINATION | FUNCTIONALIZATIONS | MECHANISM | 2-PYRIDONES | CYTOTOXIC MACROLIDE | SELECTIVE SYNTHESIS | LINEAR 1,3-BUTADIENES | CHEMISTRY, MULTIDISCIPLINARY | ALKENYLATION | ACRYLATES | Alkenes - chemistry | Oxidation-Reduction | Stereoisomerism | Amides - chemistry | Catalysis | Ruthenium - chemistry | Rhodium - chemistry | Acrylamides - chemistry
Journal Article
Chemical Communications, ISSN 1359-7345, 10/2011, Volume 47, Issue 37, pp. 10458 - 10460
Cationic rhodium complex-catalyzed olefination of phenol derivatives for the direct introduction of an alpha,beta-unsaturated ester appendage is described. In... 
ACTIVATION | ACID | BOND FUNCTIONALIZATION | REACTIVITY | OXIDATIVE COUPLING REACTION | ANILIDES | BENZENES | EFFICIENT | CHEMISTRY, MULTIDISCIPLINARY | ALKENYLATION | INDOLES
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 07/2014, Volume 53, Issue 29, pp. 7491 - 7494
In this study, a remarkably simple and direct strategy has been successfully developed to selectively label target cysteine residues in fully unprotected... 
dyes/pigments | allenes | peptides | sulfur | protein modifications | NUCLEOPHILES | ALKYNES | CHEMISTRY, MULTIDISCIPLINARY | PROTEASES | Proteins | Cysteine | Thiols | Cystine | Labeling | Conjugates | Peptides | Handles | Strategy | Marking | Conversion
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 08/2013, Volume 52, Issue 33, pp. 8584 - 8587
Journal Article
Chemical Communications, ISSN 1359-7345, 07/2010, Volume 46, Issue 26, pp. 4779 - 4781
A highly efficient and mild palladium-catalyzed decarboxylative cross-coupling of aryl boronic acids and alkynyl carboxylic acids for the synthesis of... 
CARBON-ATOMS | HALIDES | ACETYLENES | OLEFINATION | AROMATIC CARBOXYLATES | SONOGASHIRA REACTION | BIARYL SYNTHESIS | TERMINAL ALKYNES | CHEMISTRY, MULTIDISCIPLINARY | ARYL CHLORIDES | Alkynes - chemistry | Boronic Acids - chemistry | Catalysis | Palladium - chemistry | Carboxylic Acids - chemistry
Journal Article
Organic & biomolecular chemistry, ISSN 1477-0520, 05/2015, Volume 13, Issue 18, pp. 5105 - 5109
The Fe(III)- or Ag(I)-catalyzed oxidative fluorination of cyclopropanols via radical rearrangement is disclosed. This process features a straightforward and... 
Ethers, Cyclic - chemistry | Oxidation-Reduction | Ketones - chemical synthesis | Iron - chemistry | Silver - chemistry | Catalysis | Fluorine - chemistry
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 02/2017, Volume 139, Issue 5, pp. 1762 - 1765
Using α,α-difluoromethylene alkyne as a nontraditional one-carbon reaction partner, a synthetically novel method for the construction of isoindolin-1-one... 
AMBIENT CONDITIONS | FUNCTIONALIZATION | CHIRAL ALLENES | FACILE SYNTHESIS | ENANTIOSELECTIVE SYNTHESIS | (ELECTRON-DEFICIENT ETA-CYCLOPENTADIENYL)RHODIUM(III) CATALYST | OXIDATIVE ANNULATION | ALKYNES | CHEMISTRY, MULTIDISCIPLINARY | N-PHENOXYACETAMIDES | CYCLIZATION
Journal Article
Chemical Science, ISSN 2041-6520, 12/2010, Volume 1, Issue 6, pp. 739 - 742
Phosphine-catalyzed one-pot isomerization and [2 + 3]-cycloaddition of 3-butynoates with electron-deficient olefins affords highly functionalized cyclopentenes... 
4+2 ANNULATION | PHOSPHINE-CATALYZED SYNTHESIS | FUNCTIONALIZED TETRAHYDROPYRIDINES | ASYMMETRIC-SYNTHESIS | ALLENIC ALCOHOLS | EFFICIENT SYNTHESIS | CARBONYL-COMPOUNDS | 3+2 CYCLOADDITION REACTIONS | CHEMISTRY, MULTIDISCIPLINARY | HOMOPROPARGYL ALCOHOLS | ELECTRON-DEFICIENT OLEFINS
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 07/2009, Volume 48, Issue 29, pp. 5355 - 5357
It does get in! A fluoride‐assisted direct cross‐coupling of cyclic enamides with trialkoxy aryl silanes by a palladium‐catalyzed CH activation leads to a... 
CH activation | palladium | enamides | arylation | CC coupling | C-C coupling | Arylation | Palladium | C-H activation | Enamides
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 06/2012, Volume 51, Issue 23, pp. 5701 - 5705
Z only: An atom‐economical synthetic route towards arylated Z‐enamides through double CH functionalization is described. The Z/E selectivity of the... 
palladium | CH functionalization | enamides | synthetic methods | arylation | C-H functionalization | REGIOSELECTIVE HECK ARYLATION | REACTIVITY | CHEMISTRY, MULTIDISCIPLINARY | INDOLES | FUNCTIONALIZATION | ACYL-N-VINYLAMINE | BOND ACTIVATION | CARBOXYLATION | ELECTRON-RICH OLEFINS | STEREOSELECTIVE-SYNTHESIS | ALKENYLATION | Aromatic compounds | Selectivity | Complexity
Journal Article
Nature Communications, ISSN 2041-1723, 12/2018, Volume 9, Issue 1, pp. 1321 - 8
Allylic sulfones, owning to their widespread distributions in biologically active molecules, received increasing attention in the past few years. However, the... 
SULFINIC ACIDS | SUBSTITUTION | METAL-FREE CONDITIONS | ALLYLIC ALCOHOLS | MULTIDISCIPLINARY SCIENCES | SULFONES | ORGANOINDIUM REAGENTS | Cross coupling | Transformation | Metals | Alcohol | Dehydration | Hydrogen bonding | Biological activity | Aliphatic compounds | Alcohols | Coupling (molecular) | Acids | Hydrogen bonds | Chemical bonds | Sulfur | Water purification | Column chromatography | Sulfones
Journal Article
Advanced Synthesis & Catalysis, ISSN 1615-4150, 02/2018, Volume 360, Issue 3, pp. 416 - 421
Journal Article