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chemistry, multidisciplinary (6) 6
chemistry, organic (6) 6
analysis (4) 4
catalysis (4) 4
chemical properties (4) 4
chemistry, inorganic & nuclear (4) 4
olefin aziridination (4) 4
reduction (4) 4
asymmetric cyclopropanation (3) 3
c-h amination (3) 3
chemistry (3) 3
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1,1,3,3-tetramethyldisiloxane (2) 2
allylic amination (2) 2
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thermal stability (2) 2
triphenylphosphine oxide (2) 2
trishydroborate (2) 2
1,1,3,3‐tetramethyldisiloxane (1) 1
1-amino-2-naphthalenecarboxylic acid-derivatives (1) 1
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Angewandte Chemie, International Edition, ISSN 1433-7851, 11/2013, Volume 52, Issue 48, pp. 12510 - 12529
Journal Article
ACS Catalysis, ISSN 2155-5435, 02/2012, Volume 2, Issue 2, pp. 270 - 279
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 08/2011, Volume 133, Issue 31, pp. 12264 - 12273
The mechanism of cobalt(II) porphyrin-catalyzed benzylic C–H bond amination of ethylbenzene, toluene, and 1,2,3,4-tetrahydronaphthalene (tetralin) using a... 
FNWI top publication | ASYMMETRIC CYCLOPROPANATION | COMPLEXES | AMIDATION | ALLYLIC AMINATION | SULFAMATE ESTERS | BOND FORMATION REACTIONS | OLEFIN AZIRIDINATION | ARYL AZIDES | BASIS-SETS | METAL | CHEMISTRY, MULTIDISCIPLINARY | Azides | Usage | Electron paramagnetic resonance spectroscopy | Analysis | Density functionals | Chemical properties | Hydrogen bonding | Porphyrins
Journal Article
Zeitschrift für anorganische und allgemeine Chemie, ISSN 0044-2313, 08/2017, Volume 643, Issue 14, pp. 877 - 877
The cover picture shows the efficient reduction of triphenylphosphine oxide to triphenylphosphine via the simultaneous action of Brønsted acids and silanes,... 
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 01/2012, Volume 134, Issue 1, pp. 201 - 204
Journal Article
Inorganics, ISSN 2304-6740, 2016, Volume 4, Issue 4, p. 34
  A simple protocol is presented here for the use of inexpensive polymethylhydrosiloxane (PMHS), a waste product of the silicon industry, as stoichiometric... 
Reduction | Phosphine oxides | PMHS | Sustainable chemistry | Polymerization | Phosphorus content | Metals | Nitric oxide | phosphine oxides | sustainable chemistry | reduction
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 06/2011, Volume 133, Issue 25, pp. 9704 - 9707
Journal Article
Organometallics, ISSN 0276-7333, 01/2013, Volume 32, Issue 2, pp. 363 - 373
New, stable heterobidentate phosphane–olefin ligands based on the dibenzo[b,f]phosphepine backbone are reported together with their redox properties and... 
1ST ISOLATED EXAMPLES | ATOMS LI | ORDER REGULAR APPROXIMATION | STEERING LIGANDS | DENSITY-FUNCTIONAL CALCULATIONS | AB-INITIO | PHOSPHORUS ANALOGS | CHEMISTRY, ORGANIC | HARTREE-FOCK | GENERALIZED GRADIENT APPROXIMATION | GAUSSIAN-BASIS SETS | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Synthesis, ISSN 0039-7881, 7/2007, Volume 2007, Issue 14, pp. 2135 - 2144
ABSTRACT Deprotonation of the N-benzylhetarylmethanimines 9, 12, 15, and 18 at -78 °C with subsequent warming to room temperature over 16 hours and treatment... 
paper | Amine | Electrocyclic reaction | Annulation | Alkyne | Rearrangement | annulation | CHEMISTRY, ORGANIC | alkyne | electrocyclic reaction | DERIVATIVES | amine | rearrangement
Journal Article
Organic Letters, ISSN 1523-7060, 03/2007, Volume 9, Issue 6, pp. 1049 - 1052
Deprotonation of alkynyl imines 1 with LDA at low temperature and subsequent transmetalation with copper thiophenolate gives the annulated azepines 11a − i in... 
CHEMISTRY, ORGANIC | Protons | Anions | Copper - chemistry | Cyclization | Stereoisomerism | Azepines - chemical synthesis | Crystallography, X-Ray | Organometallic Compounds - chemistry | Alkynes - chemistry | Catalysis | Carbon - chemistry
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 04/2007, Volume 13, Issue 11, pp. 3113 - 3119
Deprotonation of benzothiophene‐derived alkynyl imine 11 with lithium diisopropylamide (LDA) and subsequent transmetalation with ZnCl2 etherate furnished... 
azepines | density functional calculations | lithium | zinc compounds | organic chemistry | ring closure | Organic chemistry | Zinc compounds | Lithium | Density functional calculations | Ring closure | Azepines | 1-AMINO-2-NAPHTHALENECARBOXYLIC ACID-DERIVATIVES | LITHIUM COMPOUNDS | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
Synlett, ISSN 0936-5214, 10/2007, Volume 2007, Issue 17, pp. 2733 - 2737
Abstract Hydrazones 12A,B,F furnish annulated indenone derivatives (6-azafulvenes) 13A-D upon deprotonation with T-BuOK in DMF at 50 °C. In contrast,... 
letter | Quinolines | Hydrazones | Heterocycles | Anionic electrocyclic reactions | Indenes | 6-azafulvenes | CARBANION | indenes | ISOQUINOLINES | CHEMISTRY, ORGANIC | anionic electrocyclic reactions | heterocycles | SN2 | LITHIUM COMPOUNDS | hydrazones | quinolines | NEUTRAL NITROGEN | CYCLIZATION
Journal Article
Zeitschrift fur Anorganische und Allgemeine Chemie, ISSN 0044-2313, 08/2017, Volume 643, Issue 14, pp. 916 - 921
Recently, Brønsted acids, such as phosphoric acids, carboxylic acids, and triflic acid, were found to catalyze the reduction of phosphine oxides to the... 
Brønsted acid | 1,1,3,3-Tetramethyldisiloxane | Reduction | Poly(methylhydrosiloxane) | Triphenylphosphine oxide | 1,1,3,3‐Tetramethyldisiloxane | CATALYTIC WITTIG REACTION | ROOM-TEMPERATURE | Bronsted acid | MOLECULAR-STRUCTURE | SECONDARY | CRYSTAL | BORANES | CHEMISTRY, INORGANIC & NUCLEAR | ZU PHOSPHINEN
Journal Article
European Journal of Inorganic Chemistry, ISSN 1434-1948, 01/2014, Volume 2014, Issue 10, pp. 1836 - 1842
DFT calculations were performed on copper(I) complexes of neutral scorpion ligands based on either pyrazolyl (Pz) or triazolyl (Tz) rings with both methane and... 
Transition metals | Tridentate ligands | Density functional calculations | Tripodal ligands | Inorganic Chemistry | Copper | Tripodal li­gands | COPPER(I) | ENERGY | SET | APPROXIMATION | HYDROLYSIS | COORDINATION | TRIS(PYRAZOLYL)HYDROBORATE | CHEMISTRY, INORGANIC & NUCLEAR | METAL COMPLEXATION | CHEMISTRY | CARBONYL | Ligands | Methane | Complexation | Mathematical analysis | Oxides | Carbon | Monomers | Phosphine oxide
Journal Article
Arkivoc, ISSN 1551-7012, 09/2007, Volume 2007, Issue 15, pp. 90 - 100
In the reaction of 5-methyl-5H-isoindolo[2,1-a]benzimidazole 2 with N-arylmaleimides 3a-f a novel unexpected rearrangement led to the... 
Michael addition | Atropisomerism | Isoindolo[2,1-a]- benzimidazole | Cycloaddition | Diels-Alder reaction | CRITERIA | cycloaddition | ISOINDOLES | CHEMISTRY | CHEMISTRY, ORGANIC | isoindolo[2,1-a]benzimidazole | atropisomerism
Journal Article
Zeitschrift fur Anorganische und Allgemeine Chemie, ISSN 0044-2313, 08/2017, Volume 643, Issue 14, pp. 916 - 921
Recently, Brønsted acids, such as phosphoric acids, carboxylic acids, and triflic acid, were found to catalyze the reduction of phosphine oxides to the... 
Reduction | Triphenylphosphine oxide | Brønsted acid | 1,1,3,3-Tetramethyldisiloxane | Inorganic Chemistry | Poly(methylhydrosiloxane)
Journal Article
ChemInform, ISSN 0931-7597, 04/2012, Volume 43, Issue 15, pp. no - no
Journal Article
European Journal of Inorganic Chemistry, ISSN 1434-1948, 04/2014, Volume 2014, Issue 10, p. 1836
DFT calculations were performed on copper(I) complexes of neutral scorpion ligands based on either pyrazolyl (Pz) or triazolyl (Tz) rings with both methane and... 
Methane | Analysis
Journal Article
Organometallics, ISSN 0276-7333, 04/2012, Volume 31, Issue 8, pp. 3308 - 3315
A set of substituted tris(pyrazolyl)phosphine oxides (OP(pzx)3) has been prepared in high yield and applied as neutral scorpion-type ligands. The P apex... 
FUNCTIONALIZATION | METAL COMPLEXATION | DONOR LIGANDS | CARBENE INSERTION | CARBONYL | CHEMISTRY, ORGANIC | STRUCTURAL-CHARACTERIZATION | POLY(PYRAZOLYL)BORATE | CATALYSTS | POLYPYRAZOLYLBORATE LIGANDS | TRIS(PYRAZOLYL)HYDROBORATE | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
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