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Science, ISSN 0036-8075, 12/2017, Volume 358, Issue 6367, pp. 1168 - 1171
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 05/2016, Volume 22, Issue 21, pp. 7158 - 7162
A β‐diketiminato magnesium alkyl complex, [CH{C(Me)NDipp}2}MgnBu] (Dipp=2,6‐iPr2C6H3), was shown to be an effective pre‐catalyst for the first reported... 
magnesium | hydroboration | synthetic methods | allosterism | COMPLEXES | ALKALINE-EARTH CATALYSIS | SELECTIVE REDUCTION | DIMERS | CARBON-DIOXIDE | CHEMISTRY, MULTIDISCIPLINARY | Analysis | Catalysis | Magnesium | Hydroboration | Equivalence | Catalysts | Boranes | Evolution | Carbodiimides
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 11/2018, Volume 57, Issue 47, pp. 15500 - 15504
Journal Article
Nature Communications, ISSN 2041-1723, 04/2017, Volume 8, Issue 1, p. 15022
Organoboranes are some of the most synthetically valuable and widely used intermediates in organic and pharmaceutical chemistry. Their synthesis, however, is... 
FUNCTIONALIZATION | LITHIUM BORYL | ANION | DIANION | MULTIDISCIPLINARY SCIENCES | CENTERED NUCLEOPHILE | COMPLEXES | REACTIVITY | CHEMISTRY | BORYLLITHIUM | B BONDS
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 11/2017, Volume 56, Issue 47, pp. 15131 - 15135
The para‐selective C−H alkylation of aniline derivatives furnished with a pyrimidine auxiliary is herein reported. This reaction is proposed to take place via... 
reaction mechanisms | ruthenium | C−H activation | arenes | homogeneous catalysis | ENANTIOSELECTIVE DEAROMATIZATION | ACID | SPIROINDOLENINES | IRIDIUM | STEREOSELECTIVE MIGRATION | CHEMISTRY, MULTIDISCIPLINARY | DESYMMETRIZATION | ASYMMETRIC ALLYLIC SUBSTITUTIONS | C-H activation | DEAROMATIZATION REACTIONS | CARBON-CARBON | INDOLE ALKALOIDS | Aniline | Ruthenium | Catalysis | Derivatives | Catalysts | Alkylation
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 07/2017, Volume 139, Issue 29, pp. 10036 - 10054
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 08/2015, Volume 54, Issue 34, pp. 10009 - 10011
Journal Article
CHEMISTRY-A EUROPEAN JOURNAL, ISSN 0947-6539, 11/2015, Volume 21, Issue 45, pp. 15960 - 15963
Catalytic dehydrocoupling of primary and secondary phosphines has been achieved for the first time using an iron pre-catalyst. The reaction proceeds under mild... 
HYDROPHOSPHINATION | ACTIVATION | radicals | REACTIVITY | TERMINAL ALKYNES | P-H | MECHANISMS | phosphanes | BOND-CLEAVAGE | CHEMISTRY, MULTIDISCIPLINARY | 3-COORDINATE | HYDRIDE | CARBONYL-COMPLEXES | homogeneous catalysis | iron | phosphorus | Olefins | Catalysis
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 11/2015, Volume 54, Issue 45, pp. 13362 - 13365
Dehydrocoupling reactions between the boranes HBpin and 9‐borabicyclo[3.3.1]nonane and a range of amines and anilines ensue under very mild reaction conditions... 
amines | magnesium | BN coupling | boron | alkaline‐earth metals | B-N coupling | alkaline-earth metals | BN coupling | COMPLEXES | REACTIVITY | ION | AMMONIA-BORANE | HYDROAMINATION | HYDROGEN STORAGE | CHEMISTRY, MULTIDISCIPLINARY | CALCIUM | CHEMISTRY | AMINOBORANES | Amines | Earth | Chemical reactions | Boranes | Acidity | Magnesium | Catalysis | Substrates | Intermediates | Aniline | Hydrides | Resultants | Borohydrides | Communications | B–N coupling
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 09/2015, Volume 21, Issue 40, pp. 14075 - 14084
The mononuclear N‐heterocyclic carbene (NHC) copper alkoxide complexes [(6‐NHC)CuOtBu] (6‐NHC=6‐MesDAC (1), 6‐Mes (2)) have been prepared by addition of the... 
hydrides | carbenes | copper | diamidocarbenes | alkoxide ligands | N-HETEROCYCLIC CARBENE | C-H BOND | RING-EXPANSION | CHEMISTRY, MULTIDISCIPLINARY | 3+2 CYCLOADDITION | EFFICIENT CATALYSTS | SELECTIVE SEMIHYDROGENATION | MIGRATORY INSERTION | X-RAY | CARBON-DIOXIDE | ELECTRONIC-STRUCTURE | Comparative analysis | Telomerase | Ketones | Insertion | Hydrides | Hydrosilylation | Catalysis | Copper | Coordination compounds | Carbenes | Alkynes | Alkoxides
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 05/2009, Volume 48, Issue 22, pp. 4013 - 4016
High‐de‐hydride! A straightforward reaction between a magnesium silylamido/N‐heterocyclic carbene adduct and phenylsilane provides a {Mg4H6} cluster molecule... 
hydrides | magnesium | amides | cluster compounds | carbene ligands | Carbene ligands | Amides | Hydrides | Magnesium | Cluster compounds | COMPLEX | COMPOUND | CHEMISTRY, MULTIDISCIPLINARY | INVERSE CROWN | METALLOCENES | MOLECULES | HYDROGEN | METALS | TETRAHYDROFURAN | CARBENE ADDUCTS | DOUBLE-BOND
Journal Article
European Polymer Journal, ISSN 0014-3057, 05/2019, Volume 114, pp. 319 - 325
[Display omitted] •We report the characterisation of several complexes based upon monopyrrolidine ligands.•All complexes have been characterised by single... 
Initiators | Lactide | ROP | ALKOXIDE INITIATORS | POLYMER SCIENCE | ZINC-COMPLEXES | ZIRCONIUM COMPLEXES | RAC-LACTIDE | ISOSELECTIVE POLYMERIZATION | RACEMIC LACTIDE | SINGLE-SITE CATALYSTS | POLY(LACTIC ACID) | RING-OPENING POLYMERIZATION | METAL-COMPLEXES | Zirconium | Analysis | Metals | Polymerization | Magnesium | Chemical synthesis | Coordination compounds | Zinc
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 12/2017, Volume 56, Issue 51, pp. 16363 - 16366
Reactions of a magnesium‐based pinacolatoboryl nucleophile with the electrophilic organoboranes, 9‐BBN and Ph3B, provide facile B−B′ single bond formation.... 
boranes | diborane | magnesium | main-group chemistry | boryl groups | METAL-PROMOTED REACTIONS | NUCLEOPHILIC BORON | HYDRIDE ABSTRACTION | ORGANIC-SYNTHESIS | SINGLE | CARBORANES |