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Angewandte Chemie International Edition, ISSN 1433-7851, 05/2017, Volume 56, Issue 21, pp. 5821 - 5824
Vicinal stereocenters are found in many natural and unnatural compounds. Although metal‐catalyzed cross‐coupling reactions of unactivated alkyl electrophiles... 
cross-coupling | nickel | alkylation | asymmetric synthesis | zinc | HALIDES | REAGENTS | INDOLIZIDINE | BROMIDES | CHEMISTRY, MULTIDISCIPLINARY | QUINOLIZIDINE ALKALOIDS | ESTERS | RADICALS | ELECTROPHILES | Stereoisomers | Nickel | Synthesis | Organic compounds | Stereoselectivity | Catalysts | Pyrrolidine | Halides
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 04/2012, Volume 51, Issue 17, pp. 4122 - 4127
Copper‐catalyzed allylic alkylation of azoles, a pyridine N‐oxide, and fluoroarenes with secondary allylic phosphates proceeded under mild reaction conditions... 
regioselectivity | heteroarenes | copper | azoles | allylic alkylation | PALLADIUM | SUBSTITUTION | C-H BOND | ARYLATION | CHEMISTRY, MULTIDISCIPLINARY | CARBON-HYDROGEN | ASYMMETRIC INTRAMOLECULAR ALKYLATION | PHOSPHATES | ARYL | ALKENYLATION | CONJUGATE ADDITION | Hydrocarbons, Aromatic - chemistry | Copper - chemistry | Catalysis | Stereoisomerism | Alkylation | Stereoselectivity | Pyridines | Azoles | Aromatic compounds
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 09/2016, Volume 55, Issue 39, pp. 11859 - 11862
High enantioselectivity was achieved for the hydrogenation of azaindoles by using the chiral catalyst, which was prepared from [Ru(η3‐methallyl)2(cod)] and a... 
chemoselectivity | ruthenium | azaindoles | asymmetric catalysis | hydrogenation | ACID | QUINOLINES | RUTHENIUM-CATALYZED HYDROGENATION | HETEROAROMATIC-COMPOUNDS | CHEMISTRY, MULTIDISCIPLINARY | IRIDIUM CATALYSTS | INDOLES | DERIVATIVES | QUINOXALINES | 2,9-SUBSTITUTED 1,10-PHENANTHROLINES | ACCESS | Chemotherapy | Ruthenium | Catalysis | Enantiomers | Hydrogenation | Cancer
Journal Article
Angewandte Chemie (International ed. in English), ISSN 1433-7851, 5/2017, Volume 56, Issue 21, pp. 5821 - 5824
Vicinal stereocenters are found in many natural and unnatural compounds. Although metal-catalyzed cross-coupling reactions of unactivated alkyl electrophiles... 
cross-coupling | nickel | alkylation | asymmetric synthesis | zinc
Journal Article
Angewandte Chemie, ISSN 0044-8249, 05/2017, Volume 129, Issue 21, pp. 5915 - 5918
Vicinal stereocenters are found in many natural and unnatural compounds. Although metal‐catalyzed cross‐coupling reactions of unactivated alkyl electrophiles... 
Asymmetrische Synthesen | Kreuzkupplungen | Nickel | Alkylierungen | Zink | Seed Storage Proteins - chemistry | Nickel - chemistry | Stereoisomerism | Molecular Structure | Catalysis | Alkylation | Ethyl Chloride - chemistry | Stereoisomers
Journal Article
Chemistry Letters, ISSN 0366-7022, 12/2017, Volume 46, Issue 12, pp. 1814 - 1817
A wide range of benzyl carbonates reacted with dimethyl phosphonate or diphenylphosphine oxide in the presence of the palladium catalyst,... 
Palladium catalyst | Phosphorus nucleophiles | Benzylic substitution | ORGANIC-SYNTHESIS | ACID | ARYL MESYLATES | BOND FORMATION | CHEMISTRY, MULTIDISCIPLINARY | PHOSPHORORGANISCHE VERBINDUNGEN | CROSS-COUPLING REACTIONS | ALLYLIC PHOSPHINATION | NICKEL | HYPOPHOSPHOROUS COMPOUNDS | STEREOSELECTIVE-SYNTHESIS
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 05/2013, Volume 52, Issue 20, pp. 5350 - 5354
Skipping out: The title reaction using internal secondary allylic phosphates proceeded with excellent γ regioselectivity and E stereoselectivity to give... 
copper | homogeneous catalysis | synthetic methods | alkynes | allylic compounds | ALKYNYLCOPPER REAGENTS | SUBSTITUTION | ANNULATION | INTERNAL ALKYNES | REGIOSELECTIVITY | CHEMISTRY, MULTIDISCIPLINARY | REARRANGEMENT | O-ALKYNYLPHENOLS | CYCLOISOMERIZATION | 1,4-ENYNES | CONJUGATE ADDITION
Journal Article
Synlett, ISSN 0936-5214, 12/2017, Volume 28, Issue 19, pp. 2573 - 2576
Abstract The decarboxylation of benzyl fluorobenzoates has been developed by using the palladium catalyst prepared in situ from Pd(η 3 -allyl)Cp and bulky... 
cluster | diarylmethane | decarboxylation | benzylation | C-O activation | palladium catalyst | benzyl palladium intermediate | fluoroarene | SUBSTITUTION | CARBONATES | ACIDS | ARYLATION | BIARYL SYNTHESIS | CHEMISTRY, ORGANIC | COUPLING REACTIONS | HIV-1 INTEGRASE | POTASSIUM POLYFLUOROBENZOATES | INHIBITORS
Journal Article
Chemical Communications, ISSN 1359-7345, 07/2014, Volume 50, Issue 59, pp. 8010 - 8013
A nickel/N-heterocyclic carbene (NHC) catalysed carboxylation of aryl-, heteroaryl- and alkenylboronates, affording the corresponding carboxylic acids, has... 
TRANSFORMATION | HALIDES | ACIDS | ESTERS | COMPLEXES | CO2 | BOND | CARBON-DIOXIDE | CHEMISTRY, MULTIDISCIPLINARY | Carbon dioxide | Carboxylation | Transformations | Nickel | Carboxylic acids | Compatibility | Carbenes | Functional groups
Journal Article
ISSN 1359-7345, 6/2014, Volume 5, Issue 59, pp. 81 - 813
...ChemComm COMMUNICATION Nickel-catalysed carboxylation of organoboronates† Cite this: Chem. Commun., 2014, 50,8 0 1 0 Yusuke Makida, a Enrico Marelli... 
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 10/2014, Volume 136, Issue 39, pp. 13932 - 13939
The copper-catalyzed enantioselective allylic alkylation of terminal alkynes with primary allylic phosphates was developed by the use of a new chiral... 
REARRANGEMENT | REAGENTS | ASYMMETRIC CONJUGATE ADDITION | ALKOXY-NHC LIGANDS | SKIPPED ENYNES | PHOSPHATES | SUBSTITUTION-REACTIONS | EFFICIENT | CHEMISTRY, MULTIDISCIPLINARY | CARBON STEREOGENIC CENTERS | Phosphates | Copper compounds | Chemical properties
Journal Article
Organic Letters, ISSN 1523-7060, 12/2011, Volume 13, Issue 23, pp. 6312 - 6315
Copper-catalyzed γ-selective coupling between propargylic phosphates and alkylboron compounds (alkyl-9-BBN, prepared by hydroboration of alkenes with 9-BBN-H)... 
CHIRAL ALLENES | SUBSTITUTION | ALLYLIC PHOSPHATES | ASYMMETRIC-SYNTHESIS | ENANTIOSELECTIVE SYNTHESIS | ONE-POT SYNTHESIS | VINYLALLENES | CHEMISTRY, ORGANIC | STEREOSELECTIVE-SYNTHESIS | ARYLBORONIC ACIDS | 1,3-DISUBSTITUTED ALLENES
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 12/2008, Volume 130, Issue 51, pp. 17276 - 17277
Allyl−aryl coupling between allylic acetates and arylboronic acids took place in the presence of catalytic amounts of Pd(OAc)2, 1,10-phenanthroline, and AgSbF6... 
CHEMISTRY, MULTIDISCIPLINARY
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 03/2010, Volume 132, Issue 9, pp. 2895 - 2897
Journal Article
Organometallics, ISSN 0276-7333, 11/2013, Volume 32, Issue 21, pp. 6265 - 6270
Seven new air- and moisture-stable nickel complexes bearing flexible bulky NHC (N-heterocyclic carbene) ancillary ligands (NHC = IPr*, IPr*Tol, IPr*OMe, IPent)... 
N-HETEROCYCLIC CARBENE | CROSS-COUPLING REACTIONS | AMINATION | NOBEL LECTURE | NICKEL | C-N | CHEMISTRY, ORGANIC | BOND FORMATION | PRE-CATALYST | IPR-ASTERISK | ARYL CHLORIDES | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
The Journal of Organic Chemistry, ISSN 0022-3263, 04/2018, Volume 83, Issue 7, pp. 3829 - 3839
A chemoselective hydrogenation of isoquinoline carbocycles was achieved by using the catalyst prepared from Ru­(methallyl)2(cod) and trans-chelate chiral... 
QUINOLINE COMPOUNDS | BAYLIS-HILLMAN ADDUCTS | SELECTIVE HYDROGENATION | CHIRAL DIPHOSPHINE LIGANDS | ASYMMETRIC ALLYLIC AMINATION | N-HETEROAROMATIC COMPOUNDS | COMPLEXES | CHEMISTRY, ORGANIC | ALDOSTERONE SYNTHASE CYP11B2 | ELECTROPHILIC ATTACK | ANION-BINDING
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 05/2012, Volume 134, Issue 21, pp. 8982 - 8987
The stereochemical courses of the copper-catalyzed allyl–alkyl coupling between enantioenriched chiral allylic phosphates and alkylboranes were switchable... 
ORGANIC-SYNTHESIS | MEDIATED SUBSTITUTION-REACTIONS | STEREODIVERGENT CONSTRUCTION | SILANES | ARYL | STEREOSELECTIVE-SYNTHESIS | ALLYLSILANES | BEARING TERTIARY | CHEMISTRY, MULTIDISCIPLINARY | CARBON STEREOGENIC CENTERS | CONJUGATE ADDITION
Journal Article
Chemistry letters, ISSN 0366-7022, 01/2017, Volume 46, Issue 12, p. 1814
A wide range of benzyl carbonates reacted with dimethyl phosphonate or diphenylphosphine oxide in the presence of the palladium catalyst,... 
Dimethyl | Alkenes | Phosphonates | Esters | Palladium | Catalysis | Carbonates | Nucleophiles
Journal Article
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