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Angewandte Chemie International Edition, ISSN 1433-7851, 12/2013, Volume 52, Issue 49, pp. 12915 - 12919
Not a trace: Borylation of the nitrogen in nitrogen heterocycles or anilines provides a traceless directing group for subsequent catalytic CH borylation.... 
catalysis | CH activation | anilines | borylation | nitrogen heterocycles | C - H activation | ACTIVATION | CH activation | IRIDIUM | ARENES | SILICA | CHEMISTRY, MULTIDISCIPLINARY | INSIGHTS | Boron Compounds - chemistry | Pyrroles - chemistry | Aniline Compounds - chemistry | Catalysis | Boron Compounds - chemical synthesis | Indoles - chemistry | C–H activation | N-heterocycles
Journal Article
The Journal of Organic Chemistry, ISSN 0022-3263, 12/2009, Volume 74, Issue 23, pp. 9199 - 9201
Ir-catalyzed C−H borylation is found to be compatible with Boc protecting groups. Thus, pyrroles, indoles, and azaindoles can be selectively functionalized at... 
CHEMISTRY, ORGANIC | ROOM-TEMPERATURE | ESTERS | BONDS | Boron Compounds - chemistry | Formic Acid Esters | Heterocyclic Compounds - chemistry | Boranes - chemistry | Aza Compounds - chemistry | Pyrroles - chemistry | Catalysis | Iridium | Indoles - chemistry | Chemical properties | Structure | Heterocyclic compounds | Indole | Pyrrole
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 05/2013, Volume 135, Issue 20, pp. 7572 - 7582
Journal Article
Organic Letters, ISSN 1523-7060, 10/2005, Volume 7, Issue 22, pp. 5087 - 5090
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 07/2003, Volume 125, Issue 26, pp. 7792 - 7793
An efficient one-pot C−H activation/borylation/oxidation protocol for the preparation of phenols is described. This method is particularly attractive for the... 
Oxidation-Reduction | Phenols - chemical synthesis | Boranes - chemistry
Journal Article
Polyhedron, ISSN 0277-5387, 11/2018, Volume 155, pp. 189 - 193
Condensation reaction of two different chlorosilanes with the tetrasilanol of double-decker shaped silsesquioxane was performed. The reaction resulted in a... 
Asymmetric | Double-decker shaped silsesquioxane (DDSQ) | Separation | Synthesis | HPLC | CHAIN | POSS | CRYSTALLOGRAPHY | CHROMATOGRAPHY | CIS | CHEMISTRY, INORGANIC & NUCLEAR | Chemical synthesis | Analysis | High performance liquid chromatography
Journal Article
Chemical Communications, ISSN 1359-7345, 11/2010, Volume 46, Issue 41, pp. 7724 - 7726
Experiment and theory favour a model of C-H borylation where significant proton transfer character exists in the transition state. 
FUNCTIONALIZATION | ACTIVATION | MECHANISM | BONDS | COMPLEXES | AROMATIC BORYLATION | CHEMISTRY, MULTIDISCIPLINARY | DIBORON | Boron - chemistry | Stereoisomerism | Molecular Conformation | Models, Molecular | Ligands | Hydrogen - chemistry | Iridium - chemistry | Carbon - chemistry | Electrons
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 07/2012, Volume 134, Issue 28, pp. 11350 - 11353
The NHBoc group affords ortho selective C–H borylations in arenes and alkenes. Experimental and computational studies support an outer sphere mechanism where... 
ACTIVATION | BENZYNE CYCLIZATION | REAGENTS | HETEROCYCLES | ARENES | COMPLEXES | BOND FUNCTIONALIZATION | INTERMEDIATE | CHEMISTRY, MULTIDISCIPLINARY | DIBORON | Boron Compounds - chemistry | Models, Molecular | Catalysis | Hydrogen Bonding | Iridium - chemistry | Chemical properties | Iridium | Hydrogen bonding | Olefins | Analysis | Alkylation
Journal Article
Organic Letters, ISSN 1523-7060, 02/2011, Volume 13, Issue 4, pp. 584 - 587
Journal Article
ACS Catalysis, ISSN 2155-5435, 07/2018, Volume 8, Issue 7, pp. 6216 - 6223
High ortho selectivity for Ir-catalyzed C–H borylations (CHBs) of anilines results when B2eg2 (eg = ethylene glycolate) is used as the borylating reagent in... 
hydrogen bonding | C-H activation | ortho functionalization | aniline | computational chemistry | METALATION | IRIDIUM | ARENES | CHEMISTRY, PHYSICAL | INDOLES | CATALYZED ORTHO-BORYLATION | PHENOLS | SUBSTRATE | BOND ACTIVATION | LIGAND | ARYLAMINES | C–H activation
Journal Article
Organic Letters, ISSN 1523-7060, 04/2016, Volume 18, Issue 7, pp. 1554 - 1557
Bismuth­(III) acetate is a safe, inexpensive, and selective facilitator of sequential protodeboronations, which when used in conjunction with Ir-catalyzed... 
FUNCTIONALIZATION | CHEMISTRY, ORGANIC | ACTIVATION | C-H BORYLATION | AMINO-ACIDS | INSIGHTS | Bismuth - chemistry | Boron Compounds - chemistry | Acetates - chemistry | Molecular Structure | Catalysis | Indoles - chemistry
Journal Article
The Journal of Organic Chemistry, ISSN 0022-3263, 02/2005, Volume 70, Issue 3, pp. 841 - 846
Polymethylhydrosiloxane (PMHS) made hypercoordinate by KF(aq) allows Me3SnH to be recycled during a Pd(0)-catalyzed hydrostannation/Stille cascade. Starting... 
POLYMETHYLHYDROSILOXANE PMHS | HALIDES | NATURAL-PRODUCT | PALLADIUM | ORGANOTIN HYDRIDES | PRACTICAL METHOD | CHEMISTRY, ORGANIC | ARYL | REACTION MIXTURES | ORGANIC ELECTROPHILES | GENERAL-METHOD | Tin compounds | Chemical reactions | Fluorine compounds | Research | Chemical properties
Journal Article
ORGANIC LETTERS, ISSN 1523-7060, 08/2019, Volume 21, Issue 16, pp. 6388 - 6392
By modifying ligand steric and electronic profiles it is possible to C-H borylate ortho or meta to substituents in aromatic and heteroaromatic compounds, where... 
CHEMISTRY, ORGANIC | ACTIVATION | ARENES | INSIGHTS
Journal Article
Journal of Organic Chemistry, ISSN 0022-3263, 08/2015, Volume 80, Issue 16, pp. 8341 - 8353
Ir-catalyzed deborylation can be used to selectively deuterate aromatic and heteroaromatic substrates. Combined with the selectivities of Ir-catalyzed C-H... 
DIRECTING GROUPS | IRIDIUM COMPLEXES | PROTODEBORONATION | ARENES | BONDS | CHEMISTRY, ORGANIC | EXCHANGE | REGIOSELECTIVITY | CYCLOOCTADIENE | ARYLBORONIC ACIDS | BORYLATION | Boron Compounds - chemistry | Deuterium - chemistry | Esters | Boronic Acids - chemistry | Molecular Structure | Catalysis | Indoles - chemistry | Boronic Acids - chemical synthesis
Journal Article
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