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ACS Catalysis, ISSN 2155-5435, 02/2015, Volume 5, Issue 2, pp. 776 - 787
We describe a combined experimental and computational study into the scope, regioselectivity, and mechanism of the catalytic hydrodefluorination (HDF) of... 
ruthenium | DFT | hydrodefluorination | catalysis | pentafluoropyridine | mechanism | N-heterocyclic carbenes | COMPLEX | ENERGY | PERFLUOROARENES | CHEMISTRY, PHYSICAL | TRIFLUOROTOLUENES | FLUOROARENES | CARBON-FLUORINE BONDS | FLUOROAROMATICS | BASIS-SETS | POLARIZATION FUNCTIONS
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 11/2018, Volume 57, Issue 47, pp. 15500 - 15504
Journal Article
Angewandte Chemie - International Edition, ISSN 1433-7851, 2016, Volume 55, Issue 50, pp. 15539 - 15543
The synthesis of the Cu-borate complexes [(6Mes)Cu(HBR3)] featuring the unusual [HBEt3](-) (5) and [HB(C6F5)(3)](-) (6) ligands is described. Experimental and... 
N-heterocyclic carbene | Lewis acids | copper | hydride ligand | DFT calculations | Copper | Hydride ligand | STABILITY | HYDROSILYLATION | REACTIVITY | ALKYNES | CHEMISTRY, MULTIDISCIPLINARY | HYDRIDE | ABSTRACTION | LIGANDS | REDUCTION | CRYSTALLOGRAPHIC CHARACTERIZATION | CHEMISTRY
Journal Article
Chemical Communications, ISSN 1359-7345, 2018, Volume 54, Issue 74, pp. 10443 - 10446
A catalytic hydrophosphination route to 1,1-diphosphines is yet to be reported: these narrow bite angle pro-ligands have been used to great effect as ligands... 
DIPHOSPHINE LIGANDS | HYDROGENATION | PLATINUM(II) COMPLEXES | RHODIUM CATALYSTS | MOLECULAR-STRUCTURES | INTERMOLECULAR HYDROACYLATION | BOND FORMATION | CONVENIENT | ALKYNES | CHEMISTRY, MULTIDISCIPLINARY | EPOXIDATION
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 05/2016, Volume 22, Issue 21, pp. 7158 - 7162
A β‐diketiminato magnesium alkyl complex, [CH{C(Me)NDipp}2}MgnBu] (Dipp=2,6‐iPr2C6H3), was shown to be an effective pre‐catalyst for the first reported... 
magnesium | hydroboration | synthetic methods | allosterism | COMPLEXES | ALKALINE-EARTH CATALYSIS | SELECTIVE REDUCTION | DIMERS | CARBON-DIOXIDE | CHEMISTRY, MULTIDISCIPLINARY | Analysis | Catalysis | Magnesium | Hydroboration | Equivalence | Catalysts | Boranes | Evolution | Carbodiimides
Journal Article
Science, ISSN 0036-8075, 12/2017, Volume 358, Issue 6367, pp. 1168 - 1171
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 02/2017, Volume 56, Issue 6, pp. 1515 - 1519
Journal Article
Dalton transactions (Cambridge, England : 2003), ISSN 1477-9226, 12/2015, Volume 44, Issue 45, pp. 19597 - 19605
The room temperature reaction of C6F6 or C6F5H with [Ru(IEt2Me2)2(PPh3)2H2] (; IEt2Me2 = 1,3-diethyl-4,5-dimethylimidazol-2-ylidene) generated a mixture of the... 
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 08/2018, Volume 57, Issue 33, pp. 10688 - 10691
Reactions of readily accessible magnesium‐centered pinacolatoboryl nucleophiles with [(Ph2B)2O] result in B−O bond activation of the diphenylborinic anhydride.... 
boranes | magnesium | diboranes | boron | main group chemistry | METAL-PROMOTED REACTIONS | B-B SINGLE | REACTIVITY | BOND FORMATION | CARBORANES | BORANE | CHEMISTRY, MULTIDISCIPLINARY | ALPHA,BETA-UNSATURATED CONJUGATED COMPOUNDS | BORYLLITHIUM | BORON HYDRIDES | CHEMISTRY | Chemical tests and reagents | Anhydrides | Boron | Diborane | Metathesis | Magnesium | Chemical synthesis | Nucleophiles
Journal Article
Chemical Communications, ISSN 1359-7345, 08/2015, Volume 51, Issue 64, pp. 12807 - 12810
A catalytic meta-selective C-H functionalization of 2-phenylpyridines using a range of tertiary halides is described. The protocol is simple to perform and... 
ACTIVATION | OLEFINATION | ALKYLATION | ARYLATION | BONDS | SECONDARY | CHEMISTRY, MULTIDISCIPLINARY | Pyridines - chemistry | Molecular Conformation | Models, Molecular | Catalysis | Hydrogen - chemistry | Isomerism | Carbon - chemistry
Journal Article
Inorganic Chemistry, ISSN 0020-1669, 05/2017, Volume 56, Issue 10, pp. 5976 - 5983
The β-diketiminato magnesium amidoboranes [HC­{(Me)­CNDipp}2Mg­(NMe2BH2NMe2·BH3)] and [HC­{(t-Bu)­CNDipp}2Mg­(NMe2·BH3)] are readily converted to the... 
CATALYSIS | MAGNESIUM | HYDROBORATION | IMINES | CALCIUM | ESTERS | CO2 | B(C6F5)-CATALYZED HYDROSILATION | DIALKYLAMINE-BORANES | CARBON-DIOXIDE | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Nature Communications, ISSN 2041-1723, 04/2017, Volume 8, Issue 1, p. 15022
Organoboranes are some of the most synthetically valuable and widely used intermediates in organic and pharmaceutical chemistry. Their synthesis, however, is... 
FUNCTIONALIZATION | LITHIUM BORYL | ANION | DIANION | MULTIDISCIPLINARY SCIENCES | CENTERED NUCLEOPHILE | COMPLEXES | REACTIVITY | CHEMISTRY | BORYLLITHIUM | B BONDS
Journal Article