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Journal of the American Chemical Society, ISSN 0002-7863, 09/2017, Volume 139, Issue 38, pp. 13318 - 13329
In order to quantify the electrophilic reactivities of common Michael acceptors, we measured the kinetics of the reactions of monoacceptor-substituted ethylenes (H2CCH-Acc, 1) and styrenes (PhCHCH-Acc, 2... 
Journal Article
Chemical communications (Cambridge, England), ISSN 1359-7345, 05/2012, Volume 48, Issue 37, pp. 4504 - 4506
...-Michael additions to enals. 
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 10/2016, Volume 55, Issue 41, pp. 12664 - 12667
...=−12.09, ESF is among the strongest Michael acceptors in our comprehensive electrophilicity scale, which explains its excellent performance in reactions with many nucleophiles... 
ylides | reaction kinetics | electrophilic aromatic substitution | electrophilicity | linear free-energy relationships | Chemical reaction, Rate of | Substitution reactions | Fluoride | Aromatic compounds | Pyrroles | Pyridinium | Reaction kinetics | Fluorides | Kinetics | Nucleophiles | Photometry
Journal Article
2005, 1st ed., ISBN 9781591472100, xiii, 273 p., [4] p. of plates
Book
Angewandte Chemie (International ed.), ISSN 1433-7851, 12/2019, Volume 59, Issue 4, pp. 1455 - 1459
Tropylium bromide undergoes noncatalyzed, regioselective additions to a large variety of Michael acceptors... 
reaction mechanisms | halogens | tropylium | Michael acceptors | synthetic methods | Organic chemistry | Quantum chemistry | Alkenes | Chemical attack | Phosphine | Esters | Chemical reactions | Phosphines | Acrylic esters | Adducts | Index Medicus
Journal Article
Topics in catalysis, ISSN 1022-5528, 04/2018, Volume 61, Issue 7-8, pp. 585 - 590
2-Cinnamoylimidazolium ions 4 have been synthesized by treatment of 2-cinnamoylimidazoles 8 with methyl triflate. They were characterised by NMR and mass... 
Nucleophilic carbenes | Reactivity | Electrophilicity | Kinetics | Organocatalysis | Physical Sciences | Chemistry | Chemistry, Physical | Chemistry, Applied | Science & Technology | Rate constants | Parameters | Nuclear magnetic resonance--NMR | Correlation analysis | Reaction kinetics | Fluorides | Ethers | Nucleophiles | X ray analysis | Chemical synthesis | Photometry
Journal Article
ISSN 1359-7345, 4/2012, Volume 48, Issue 37, pp. 454 - 456
... ). Unfavourable proton shifts from the imidazolium unit to the enamine fragment in the adduct 3 account for the failure of imidazoles to take part in iminium-activated aza-Michael additions to enals... 
Journal Article
Topics in catalysis, ISSN 1022-5528, 06/2018, Volume 61, Issue 7-8, p. 585
To access, purchase, authenticate, or subscribe to the full-text of this article, please visit this link: http://dx.doi.org/10.1007/s11244-018-0914-5... 
Analysis | Nuclear magnetic resonance spectroscopy | Catalysis | Mass spectrometry
Journal Article
Angewandte Chemie, ISSN 1521-3757, 12/2019, Volume 132, Issue 4, pp. 1471 - 1475
Tropylium bromide undergoes noncatalyzed, regioselective additions to a large variety of Michael acceptors... 
Halogene | Michael-Akzeptoren | Synthesemethoden | Reaktionsmechanismen | Tropylium | Organic chemistry | Quantum chemistry | Alkenes | Chemical attack | Phosphine | Esters | Chemical reactions | Phosphines | Acrylic esters | Adducts
Journal Article
Monatsschrift Kinderheilkunde, ISSN 0026-9298, 09/2019, Volume 167, Issue 9, pp. 838 - 840
Journal Article
Angewandte Chemie, ISSN 0044-8249, 10/2016, Volume 128, Issue 41, pp. 12854 - 12858
...‐Parameter von ESF gemäß der Korrelation lg k20 °C=sN(N + E) zu bestimmen. Mit E=−12.09 gehört ESF zu den stärksten Michael‐Akzeptoren in unserer Substanzklassen... 
Reaktionskinetik | Lineare Freie-Enthalpie-Beziehungen | Elektrophile aromatische Substitutionen | Elektrophilie | Ylide
Journal Article
The New England journal of medicine, ISSN 1533-4406, 07/2015, Volume 373, Issue 3, pp. 232 - 242
Journal Article
Angewandte Chemie, ISSN 0044-8249, 10/2016, Volume 128, Issue 41, p. 12854
...] der Korrelation lgk.sub.20[degrees]C=s.sub.N(N + E) zu bestimmen. Mit E=-12.09 gehort ESF zu den starksten Michael-Akzeptoren in unserer Substanzklassen-ubergreifenden... 
Photometry
Journal Article
Computers in human behavior, ISSN 0747-5632, 04/2017, Volume 69, pp. 371 - 380
The main aim of gamification, i.e. the implementation of game design elements in real-world contexts for non-gaming purposes, is to foster human motivation and... 
Self-determination theory | Psychological need satisfaction | Game design elements | Motivation | Simulation | Gamification | Psychology, Multidisciplinary | Psychology, Experimental | Social Sciences | Psychology | Psychological research | Analysis | Studies | Psychological aspects | Avatars | Human performance | Electronic & video games | Psychological effects
Journal Article