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Chemistry : a European journal, ISSN 1521-3765, 2020, Volume 26, Issue 13, pp. 2883 - 2889
The synthesis of rhodium complexes with weakly binding highly fluorinated benzene ligands is described: 1,2,3‐F3C6H3, 1,2,3,4‐F4C6H2 and 1,2,3,4,5‐F5C6H are... 
catalysis | phosphine | x-ray | fluoroarene | rhodium | SIGMA-ALKANE COMPLEX | CRYSTAL-STRUCTURE | OXIDATIVE ADDITION | CHEMISTRY, MULTIDISCIPLINARY | SOLID-STATE | RHODIUM CATALYSTS | LIGANDS | INTERMOLECULAR HYDROACYLATION | BOND ACTIVATION | C-F | ETA-4-HEXAFLUOROBENZENE COMPLEXES | Alkenes | Rhodium | Benzene | Cations | Catalysis | Chemical synthesis | Aldehydes | Fluorination | Full Paper | Full Papers
Journal Article
ISSN 1477-9226, 2/2019, Volume 48, Issue 9, pp. 2948 - 2952
.../dalton Structural diversity in a homologous series of donor free alkali metal complexes bearing a sterically demanding triazenide† Alasdair I. McKay *‡ and Marcus L... 
Journal Article
Journal Article
ISSN 1477-9226, 1/2019, Volume 48, Issue 5, pp. 1591 - 1594
A spectroscopic study of the decomposition of a Lewis base adduct of indane is reported. The outcomes of this study have prompted the synthesis of the... 
Journal Article
Emergency Medicine Journal, ISSN 1472-0205, 12/2019, Volume 36, Issue 12, p. 777
Troponin rise in patients with atrial fibrillation may be falsely attributed to oxygen demand-supply mismatch rather than acute atherothrombotic events... 
Electrocardiography | Cardiac arrhythmia | Sinuses | Patients | Mortality
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 07/2017, Volume 139, Issue 29, pp. 10142 - 10149
Journal Article
European journal of inorganic chemistry, ISSN 1434-1948, 2017, Volume 2017, Issue 38-39, pp. 4533 - 4540
Journal Article
Angewandte Chemie, ISSN 0044-8249, 2018, Volume 130, Issue 17, pp. 4622 - 4627
Crabtree's catalyst was encapsulated inside the pores of the sulfonated MIL‐101(Cr) metal–organic framework (MOF) by cation exchange. This hybrid catalyst is... 
Verkapselung | Crabtree-Katalysator | Hydrierungen | Allylalkohole | Metall-organische Gerüste | Hydrogenation | Isomerization | Alcohols | Encapsulation | Cation exchange | Stability | Alkenes | Catalysts | Cation exchanging | Selectivity | Substrates | Pathways | Chromium | Catalysis | Metal-organic frameworks
Journal Article
ISSN 2040-3364, 12/2019, Volume 11, Issue 47, pp. 2288 - 22889
The reactions between silver salts and borohydrides produce a rich set of products that range from discrete mononuclear compounds through to silver... 
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 11/2018, Volume 140, Issue 44, pp. 14958 - 14970
Solid/gas single-crystal to single-crystal (SC–SC) hydrogenation of appropriate diene precursors forms the corresponding σ-alkane complexes [Rh­(Cy2P­(CH2) n... 
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 01/2016, Volume 138, Issue 1, pp. 281 - 288
In seeking to create more-stable transition metal–alkane complexes, we generated cationic alkane complexes of the type [(HEB)­Re­(CO)2­(alkane)]­[Al­(ORf)4]... 
COORDINATION CHEMISTRY | DIHYDROGEN | METHANE | NMR-SPECTROSCOPY | AB-INITIO | GAS-PHASE | SIGMA-COMPLEXES | C-H ACTIVATION | BINDING | CHEMISTRY, MULTIDISCIPLINARY | SOLID-STATE
Journal Article
Organometallics, ISSN 0276-7333, 01/2017, Volume 36, Issue 1, pp. 22 - 25
Addition of H2 to the precursor [Rh­(Cyp2PCH2­CH2PCyp2)­(η2:η2-C7H8)]­[BArF 4] gives the σ-alkane complex [Rh­(Cyp2PCH2­CH2PCyp2)­(η2:η2-C7H12)]­[BArF 4] by a... 
Journal Article
Chemical science (Cambridge), ISSN 2041-6520, 2017, Volume 8, Issue 9, pp. 6014 - 6029
Solid-state molecular organometallic catalysis (SMOM-cat): synthetic routes, unique structural motifs, mobility in the solid-state and very active gas/solid... 
IRIDIUM PINCER COMPLEXES | OXIDE CLUSTERS | ALKENE ISOMERIZATION | COORDINATION POLYMER | VAPOR REACTION | METAL-ORGANIC FRAMEWORKS | SIGMA-ALKANE COMPLEX | OLEFIN-METATHESIS | CATIONIC RHODIUM COMPLEXES | C-H ACTIVATION | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 07/2019, Volume 141, Issue 29, pp. 11700 - 11712
The non-oxidative catalytic dehydrogenation of light alkanes via C–H activation is a highly endothermic process that generally requires high temperatures... 
Journal Article