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ISSN 1477-9226, 11/2010, Volume 39, Issue 45, pp. 1833 - 1836
We have used dispersion-corrected DFT (DFT-D) together with solvation to examine possible mechanisms for reaction of PhX (X = Cl, Br, I) with Pd(P t Bu 3 ) 2... 
Journal Article
Dalton Transactions, ISSN 1477-9226, 09/2011, Volume 40, Issue 35, pp. 9034 - 9041
A range of chiral resorcinol bis(phosphite) and phosphite-phosphinite ligands were produced and their propensity to form palladium PCP-pincer complexes... 
FUNCTIONALIZATION | SUZUKI | SULFONIMINES | COUPLING REACTIONS | NITRILES | ISOCYANOACETATE | CATALYZED ALLYLATION | CONDENSATION | DERIVATIVES | ARYL CHLORIDES | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Journal Article
Organometallics, ISSN 0276-7333, 02/2014, Volume 33, Issue 3, pp. 702 - 714
The four isomers of 9-butylphosphabicyclo[3.3.1]nonane, s-PhobPBu, where Bu = n-butyl, sec-butyl, isobutyl, tert-butyl, have been prepared. Seven isomers of... 
Journal Article
Journal of Molecular Catalysis A: Chemical, ISSN 1381-1169, 2010, Volume 324, Issue 1-2, pp. 48 - 55
Computational study of the full catalytic cycle for the coupling of phenylbromide with morpholine (amination), catalysed by Pd(P Bu ) complex, related to... 
Ligand effects | C-N coupling | Palladium catalysis | Computational
Journal Article
Dalton Transactions, ISSN 1477-9226, 09/2011, Volume 40, Issue 35, pp. 9042 - 9050
The reactions of a range of chiral resorcinol monophosphite ligands with [PdCl2(NCMe)(2)] was investigated in order to establish whether the meta-hydroxyl... 
ORTHOPALLADATED TRIARYLPHOSPHITE COMPLEXES | ALPHA,BETA-UNSATURATED KETONES | HIGHLY-ACTIVE CATALYSTS | COUPLING REACTIONS | PHOSPHITE COMPLEXES | PALLADIUM COMPLEXES | PLATINACYCLIC CATALYSTS | ARYL CHLORIDES | ARYLBORONIC ACIDS | EFFICIENT CATALYSTS | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Dalton Transactions, ISSN 1477-9226, 07/2011, Volume 40, Issue 27, pp. 7137 - 7146
The homodiphosphanes CgP-PCg (1) and PhobP-PPhob (2) and the heterodiphosphanes CgP-PPhob (3), CgP-PPh2 (4a), CgP-P(o-Tol)(2) (4b), CgP-PCy2 (4c),... 
CROSS-COUPLING REACTIONS | MONODENTATE CHIRAL PHOSPHINE | CATALYZED HYDROFORMYLATION | ASYMMETRIC-SYNTHESIS | INTERNAL ALKENES | NUCLEAR-MAGNETIC-RESONANCE | COMPLEXES | BICYCLIC PHOSPHINES | METATHESIS | P-P BONDS | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Angewandte Chemie, ISSN 0044-8249, 12/2017, Volume 129, Issue 51, pp. 16581 - 16584
Reactions of a magnesium‐based pinacolatoboryl nucleophile with the electrophilic organoboranes, 9‐BBN and Ph3B, provide facile B−B′ single bond formation.... 
Hauptgruppenchemie | Borane | Diborane | Borylgruppen | Magnesium | Chemical tests and reagents | Isomerization | Organoboranes
Journal Article
The New England Journal of Medicine, ISSN 0028-4793, 04/2013, Volume 368, Issue 16, pp. 1554 - 1557
To the Editor: In their report on the Cytoreductive Therapy in Polycythemia Vera (CYTO-PV) study, Marchioli et al. (Jan. 3 issue) 1 provide prospective... 
MEDICINE, GENERAL & INTERNAL | Thrombosis - etiology | Humans | Hematocrit | Phlebotomy | Cardiovascular Diseases - mortality | Female | Hydroxyurea - therapeutic use | Male | Antineoplastic Agents - therapeutic use | Polycythemia Vera - therapy | Polycythemia vera | Hydroxyurea | Polycythemia | Patients
Journal Article
Chemical communications (Cambridge, England), 01/2020, Volume 56, Issue 3, p. 336
The reaction of diphenyltin dihydride with LiAlH4 gives access to a set of charged tin cages as their lithium salts. Variation in the ratio of reactants... 
Journal Article
Dalton Transactions, ISSN 1477-9226, 05/2011, Volume 40, Issue 19, pp. 5316 - 5323
Reaction of [Pd(PPh3)(4)] with 1,1-dichloro-2,3-diarylcyclopropenes gives complexes of the type cis-[PdCl2(PPh3)(C-3(Ar)(2))] (Ar = Ph 5, Mes 6). Reaction of... 
DENSITY | DIAMINOCYCLOPROPENYLIDENE | HETEROCYCLIC CARBENES | TRANSITION-METAL-COMPLEXES | CARBOCYCLIC CARBENE | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Organometallics, ISSN 0276-7333, 03/2009, Volume 28, Issue 5, pp. 1476 - 1479
Rhodium(III) cyclopropenylidene complexes of the type [RhCl3(PPh3)2(2,3-di(aryl)cyclopropenylidene)] (Aryl = C6H5, 4-C6H4F) are synthesized via oxidative... 
CHEMISTRY, ORGANIC | N-HETEROCYCLIC CARBENES | TRANSITION-METAL-COMPLEXES | COUPLING CATALYSIS | PALLADIUM COMPLEXES | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Chemical communications (Cambridge, England), ISSN 1359-7345, 01/2010, Volume 46, Issue 1, pp. 100 - 102
An efficient, classical resolution of the versatile P-ligand intermediate 6-phospha-2,4,8-trioxa-adamantane (CgPH) is described and the rhodium complex of the... 
Catalysis | Asymmetry | Catalysts | Rhodium | Hydrogenation | Phosphines
Journal Article
Chemical Communications, ISSN 1359-7345, 2010, Volume 46, Issue 1, pp. 100 - 102
An efficient, classical resolution of the versatile P-ligand intermediate 6-phospha-2,4,8-trioxa-adamantane (CgPH) is described and the rhodium complex of the... 
COORDINATION CHEMISTRY | SUZUKI | CROSS-COUPLING REACTIONS | PHOSPHINE | LIGANDS | MECHANISM | PALLADIUM COMPLEXES | ALPHA-ARYLATION | ADAMANTANES | MONODENTATE | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 03/2020, Volume 59, Issue 10, pp. 3928 - 3932
A seven‐membered N,N′‐heterocyclic potassium alumanyl nucleophile is introduced and utilised in the metathetical synthesis of Mg−Al and Ca−Al bonded... 
magnesium | calcium | potassium | alumanyl | density functional theory | Magnesium | Calcium | Indicator species | Aluminum | Potassium
Journal Article
Dalton Transactions (Print Edition), ISSN 1477-9226, 01/2011, Volume 40, Issue 35, pp. 9034 - 9041
A range of chiral resorcinol bis(phosphite) and phosphite-phosphinite ligands were produced and their propensity to form palladium PCP-pincer complexes... 
Residues | Asymmetry | Benzaldehyde | Ligands | Catalytic activity | Palladium | Tuning | Crystal structure
Journal Article
Dalton Transactions (Print Edition), ISSN 1477-9226, 01/2011, Volume 40, Issue 35, pp. 9042 - 9050
The reactions of a range of chiral resorcinol monophosphite ligands with [PdCl2(NCMe)2] was investigated in order to establish whether the meta-hydroxyl... 
Diffraction | Asymmetry | Equivalence | Chlorides | Benzaldehyde | X-rays | Ligands | Hydrogen bonding
Journal Article
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