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chemistry, inorganic & nuclear (122) 122
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chemistry (53) 53
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1. Full Text Catalytic Asymmetric Conjugate Addition/Oxidative Dearomatization Towards Multifunctional Spirocyclic Compounds
by Rudolph, Alena and Bos, Pieter H and Meetsma, Auke and Minnaard, Adriaan J and Feringa, Ben L
Angewandte Chemie International Edition, ISSN 1433-7851, 06/2011, Volume 50, Issue 26, pp. 5834 - 5838
Naphthol compounds bearing a pendant α,β‐unsaturated ester undergo a copper(I)‐catalyzed asymmetric conjugate addition/copper(II)‐mediated intramolecular... 
oxidation | asymmetric catalysis | conjugate addition | spiro compounds | dearomatization | CARBONYL-COMPOUNDS | DIMERIZATION | ENANTIOSELECTIVE OXIDATIVE DEAROMATIZATION | CHEMISTRY, MULTIDISCIPLINARY | PHENOLS | STEREOCENTERS | DIVERSITY | ALPHA,BETA-UNSATURATED ESTERS | DERIVATIVES | GRIGNARD-REAGENTS | ACCESS
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2. Full Text Highly Efficient Hydrosilylation of Alkenes by Organoyttrium Catalysts with Sterically Demanding Amidinate and Guanidinate Ligands
by Ge, Shaozhong and Meetsma, Auke and Hessen, Bart
Organometallics, ISSN 0276-7333, 07/2008, Volume 27, Issue 13, pp. 3131 - 3135
The sterically demanding guanidine ArNHC(NMe2)NAr (Ar = 2,6-diisopropylphenyl, HL) reacts with Y(CH2SiMe3)3(THF)2 to give the yttrium dialkyl complex... 
PLATINUM-CARBENE COMPLEXES | ETHYLENE | METALS | YTTRIUM ALKYL COMPLEXES | HYDRIDES | CHEMISTRY | OLEFIN HYDROSILYLATION | LANTHANIDE | HYDROSILATION | ETHENE POLYMERIZATION | CHEMISTRY, ORGANIC | CHEMISTRY, INORGANIC & NUCLEAR
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3. Full Text Towards Redox-Driven Unidirectional Molecular Motion
by Logtenberg, Hella and Areephong, Jetsuda and Bauer, Jurica and Meetsma, Auke and Feringa, Ben L and Browne, Wesley R
Chemphyschem, ISSN 1439-4235, 06/2016, Volume 17, Issue 12, pp. 1895 - 1901
Redox-driven molecular motion is an attractive alternative to light-driven processes. Here, the ability of an overcrowded alkene-based unimolecular... 
ROTATION | DITHIENYLCYCLOPENTENES | electrochemistry | photochromism | ELECTRO | DIRECTION | To be checked by Faculty | SWITCHES | cyclic voltammetry | electrochromism | SINGLE STEREOGENIC CENTER | molecular switching | MOTORS | EFFICIENCY | PHYSICS, ATOMIC, MOLECULAR & CHEMICAL | CHEMISTRY, PHYSICAL | Electrochemistry | Chemical properties | Electrolysis | Olefins | Analysis
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4. Full Text Highly Enantioselective Synthesis of 3‐Substituted Furanones by Palladium‐Catalyzed Kinetic Resolution of Unsymmetrical Allyl Acetates
by Mao, Bin and Ji, Yining and Fañanás‐Mastral, Martín and Caroli, Giuseppe and Meetsma, Auke and Feringa, Ben L
Angewandte Chemie International Edition, ISSN 1433-7851, 03/2012, Volume 51, Issue 13, pp. 3168 - 3173
Resolving the issue: A near‐perfect Pd‐catalyzed kinetic resolution of 1,3‐disubstituted unsymmetrical allylic acetates uses silyl enol ethers as nucleophiles... 
kinetic resolution | palladium | silyl enol ethers | γ‐butenolides | allyl acetates | γ-butenolides | butenolides | SUBSTITUTION | ASYMMETRIC-SYNTHESIS | CARBONATES | SILYL KETENE ACETALS | ACYCLIC KETONES | CHEMISTRY, MULTIDISCIPLINARY | LIGANDS | ALKYLATION REACTIONS | STEREOSELECTIVE-SYNTHESIS | SULFUR NUCLEOPHILES | Synthesis | Reaction kinetics | Palladium | Nucleophiles | Ethers | Scaffolds | Acetates
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5. Full Text Fine Tuning of the Rotary Motion by Structural Modification in Light-Driven Unidirectional Molecular Motors
by Vicario, Javier and Walko, Martin and Meetsma, Auke and Feringa, Ben L
Journal of the American Chemical Society, ISSN 0002-7863, 04/2006, Volume 128, Issue 15, pp. 5127 - 5135
The introduction of bulky substituents at the stereogenic center of light-driven second-generation molecular motors results in an acceleration of the speed of... 
ROTATION | SPEED | ACCELERATION | AUTONOMOUS MOVEMENT | ROTOR | CATALYTIC NANOMOTORS | LINEAR ROTAXANE DIMER | DYNAMIC-BEHAVIOR | OVERCROWDED ALKENES | SHUTTLE | DEVICES | CHEMISTRY, MULTIDISCIPLINARY | Mechanical properties | Molecular electronics | Research | Nanotechnology | Electric motors
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6. Full Text Supramolecular homobimetallic bis-diorganotin(IV) complexes of ditopic oxygen nitrogen donor ligand: Synthesis, spectroscopic characterization, crystal structure and biological screening
by Shujah, Shaukat and Ali, Saqib and Khalid, Nasir and Meetsma, Auke
Journal of the iranian chemical society, ISSN 1735-207X, 12/2017, Volume 14, Issue 12, pp. 2567 - 2578
Six new homobimetallic bis-diorganotin(IV) complexes: [Me2Sn](2)L (1), [Et2Sn](2)L (2), [n-Bu2Sn](2)L (3), [Ph2Sn](2)L (4), [Oct(2)Sn](2)L (5) and... 
DESIGN | Antifungal | OXIDE | DIOXIDE | Cytotoxicity | Supramolecular | Antibacterial | ANGLE | Homobimetallic | ORGANOTIN(IV) COMPLEXES | C-13 | PSEUDOMONAS | SCHIFF-BASE | ANTIMICROBIAL ACTIVITY | 4-COORDINATE | Biochemistry, general | Chemistry | Analytical Chemistry | Physical Chemistry | Inorganic Chemistry | Organic Chemistry | CHEMISTRY, MULTIDISCIPLINARY
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7. Full Text Light-Controlled Supramolecular Helicity of a Liquid Crystalline Phase Using a Helical Polymer Functionalized with a Single Chiroptical Molecular Switch
by Pijper, Dirk and Jongejan, Mahthild G. M and Meetsma, Auke and Feringa, Ben L
Journal of the American Chemical Society, ISSN 0002-7863, 04/2008, Volume 130, Issue 13, pp. 4541 - 4552
Control over the preferred helical sense of a poly(n-hexyl isocyanate) (PHIC) by using a single light-driven molecular motor, covalently attached at the... 
SCREW-SENSE INVERSION | ROTATION | MACROMOLECULAR STEREOCHEMISTRY | STEREOGENIC CENTER | AMPLIFICATION | CIRCULARLY-POLARIZED LIGHT | CHIRAL POLYISOCYANATES | INFORMATION | TWIST SENSE | AMORPHOUS AZOBENZENE POLYMER | CHEMISTRY, MULTIDISCIPLINARY | Temperature | Nitriles - radiation effects | Stereoisomerism | Macromolecular Substances - radiation effects | Solutions - radiation effects | Crystallization | Solutions - chemistry | Toluene - chemistry | Macromolecular Substances - chemistry | Ultraviolet Rays | Nitriles - chemistry | Molecular Structure | Toluene - radiation effects | Photochemistry | Chirality | Isomerization | Analysis | Polymer liquid crystals | Research | Chemical properties | Structure | Photochromic materials
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8. Full Text Coexisting ferromagnetic and ferroelectric order in a CuCl 4-based organic-inorganic hybrid
by Polyakov, Alexey O and Arkenbout, Anne H and Baas, Jacob and Blake, Graeme R and Meetsma, Auke and Caretta, Antonio and Van Loosecht, Paul H.M and Palstra, Thomas T.M
Chemistry of materials, ISSN 0897-4756, 01/2012, Volume 24, Issue 1, pp. 133 - 139
We investigate the structural, magnetic, and dielectric properties of the organic-inorganic hybrid material CuCl 4(C 6H 5CH 2CH 2NH 3) 2 and demonstrate that... 
ferroelectric | Materials Chemistry | multiferroic | ferromagnetic | Chemistry(all) | Chemical Engineering(all) | metal-oxide framework | organic-inorganic hybrid
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9. Full Text Synthesis, spectroscopic characterization, X-ray structure, DFT calculations, and antimicrobial studies of diorganotin (IV) complexes of monotopic oxygen nitrogen donor Schiff base
by Shujah, Shaukat and Ali, Saqib and Khalid, Nasir and Alam, Mohammad Jane and Ahmad, Shabbir and Meetsma, Auke
Chemical papers, ISSN 0366-6352, 04/2018, Volume 72, Issue 4, pp. 903 - 919
Seven new diorganotin(IV) complexes, [Me2SnL] (1), [Et2SnL] (2), [(n-Bu2SnL] (3), [Ph2SnL] (4), [(n-Oct(2)SnL] (5), [tert-Bu2SnL] (6), and [n-BuClSnL] (7) have... 
Antifungal | ACID | Activity | Cytotoxicity | ANGLE | DFT calculations | DNA | ORGANOTIN(IV) DERIVATIVES | Diorganotin(IV) complexes | Antibacterial activity | AGENTS | DENSITY-FUNCTIONAL THEORY | ELECTRONIC-STRUCTURE | Biochemistry, general | Biotechnology | Materials Science, general | Medicinal Chemistry | Chemistry | Chemistry/Food Science, general | Industrial Chemistry/Chemical Engineering | CHEMISTRY, MULTIDISCIPLINARY | Fourier transforms | Chemical analysis | Nuclear magnetic resonance--NMR | Fungicides | Molecular structure | Toxicity | X ray spectroscopy | X-ray diffraction | Nitrogen | Coupling (molecular) | Single crystals | Microorganisms | Imines | E coli | Mathematical analysis | Ligands | Dichlorides | Chemical synthesis | Mass spectrometry | Carbon 13 | Crystal structure | Structural analysis
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10. Full Text Spectroscopic and Magnetic Properties of a Series of μ-Cyano Bridged Bimetallic Compounds of the Type MII−NC−FeIII (M = Mn, Co, and Zn) Using the Building Block [FeIII(CN)5imidazole]2
by Tchouka, Heloïse and Meetsma, Auke and Browne, Wesley R
Inorganic Chemistry, ISSN 0020-1669, 11/2010, Volume 49, Issue 22, pp. 10557 - 10570
In this contribution, we describe the preparation and single-crystal X-ray diffraction of a new building block for bimetallic solid state materials. X-ray... 
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11. Full Text Coexisting Ferromagnetic and Ferroelectric Order in a CuCl4-based Organic–Inorganic Hybrid
by Polyakov, Alexey O and Arkenbout, Anne H and Baas, Jacob and Blake, Graeme R and Meetsma, Auke and Caretta, Antonio and van Loosdrecht, Paul H. M and Palstra, Thomas T. M
Chemistry of Materials, ISSN 0897-4756, 01/2012, Volume 24, Issue 1, pp. 133 - 139
We investigate the structural, magnetic, and dielectric properties of the organic–inorganic hybrid material CuCl4(C6H5CH2CH2NH3)2 and demonstrate that... 
ferroelectric | HALIDES | multiferroic | ferromagnetic | PHASE-TRANSITIONS | CRYSTAL-STRUCTURES | MAGNETIC-PROPERTIES | organic-inorganic hybrid | metal-oxide framework | PEROVSKITES | AMMONIUM ROCHELLE SALT | MULTIFERROICS | PHASE | MATERIALS SCIENCE, MULTIDISCIPLINARY | CHEMISTRY, PHYSICAL
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12. Full Text Antimicrobial efficiency of diorganotin(IV) bis-[3-(4-chlorophenyl)-2-methylacrylate]
by Muhammad, Niaz and Ali Shah, Naseer and Ali, Saqib and Wadood, Abdul and Ghufran, Mehreen and Rashid Khan, Muhammad and Siddiq, Pakiza and Shujah, Shaukat and Meetsma, Auke
Journal of Coordination Chemistry, ISSN 0095-8972, 10/2018, Volume 71, Issue 20, pp. 3315 - 3329
Four new diorganotin(IV) carboxylates, [n-Bu 2 SnL 2 ] (1), [Et 2 SnL 2 ] (2), [Me 2 SnL 2 ] (3) and [n-Oct 2 SnL 2 ] (4), where L =... 
crystal structure | antifungal | antibacterial | molecular docking | Organotin | CARBOXYLATES | CHEMISTRY, INORGANIC & NUCLEAR | ORGANOTIN(IV) COMPLEXES | NMR | C-13 | SPECTROSCOPIC CHARACTERIZATION | CHEMISTRY | DNA INTERACTION | CATALYTIC-ACTIVITY | DERIVATIVES | Chemical analysis | Nuclear magnetic resonance--NMR | Fungicides | Coordination numbers | Antimicrobial agents | Hydrophobicity | Infrared analysis | Hydrogen bonding | Molecular docking | Proteins | Single crystals | Chelation | Carboxylates
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13. Full Text One Ligand Fits All:  Cationic Mono(amidinate) Alkyl Catalysts over the Full Size Range of the Group 3 and Lanthanide Metals
by Bambirra, Sergio and Bouwkamp, Marco W and Meetsma, Auke and Hessen, Bart
Journal of the American Chemical Society, ISSN 0002-7863, 08/2004, Volume 126, Issue 30, pp. 9182 - 9183
Using a sterically demanding amidinate ancillary ligand and an in situ alkylation procedure, neutral mono(amidinate) dialkyl and cationic mono(amidinate)... 
ACTIVATION | ETHYLENE-POLYMERIZATION | MOLECULAR-STRUCTURE | RARE-EARTH-METALS | COMPLEXES | OLEFIN POLYMERIZATION | BETA-DIKETIMINATO LIGANDS | SILYLMETHYL | X-RAY CRYSTAL | ETHENE POLYMERIZATION | CHEMISTRY, MULTIDISCIPLINARY | Rare earth metals | Ligands | Research | Chemical properties | Molecular structure | Analysis
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14. Full Text Monoanionic fac-κ3 Ligands Derived from 6-Amino-1,4-diazepine:  Ligand Dependence of Stability and Catalytic Activity of Their Scandium Alkyl Derivatives
by Ge, Shaozhong and Meetsma, Auke and Hessen, Bart
Organometallics, ISSN 0276-7333, 10/2007, Volume 26, Issue 22, pp. 5278 - 5284
Two new monoanionic fac-κ3 tridentate ligands [6-RN-1,4,6-trimethyl-1,4-diazepine]- (R = CH3, L 1; R = PhMe2Si, L 2) were prepared. Reactions of ligands HL 1... 
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15. Full Text Lanthanum Tribenzyl Complexes as Convenient Starting Materials for Organolanthanum Chemistry
by Bambirra, Sergio and Meetsma, Auke and Hessen, Bart
Organometallics, ISSN 0276-7333, 07/2006, Volume 25, Issue 14, pp. 3454 - 3462
Simple tribenzyl complexes of lanthanum, [La(CH2C6H4-4-R)3(THF)3] (R = H (1a), Me (1b)), were prepared in a remarkably straightforward fashion from LaBr3(THF)4... 
ORGANOSCANDIUM COMPLEXES | POLYMERIZATION CATALYSTS | RARE-EARTH-METALS | INTRAMOLECULAR HYDROAMINATION | YTTRIUM COMPLEXES | UNPROTECTED AMINO OLEFINS | CYCLOPENTADIENYL LIGAND | X-RAY CRYSTAL | C-H ACTIVATION | ALKYL COMPLEXES | CHEMISTRY, ORGANIC | CHEMISTRY, INORGANIC & NUCLEAR
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16. Full Text Electron-deficient iron alkyl complexes supported by diimine ligand (Ph2CN)2C2H4: Evidence for reversible ethylene binding
by Volbeda, Jeroen and Meetsma, Auke and Bouwkamp, Marco W
Organometallics, ISSN 0276-7333, 01/2009, Volume 28, Issue 1, pp. 209 - 215
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17. Full Text A redesign of light-driven rotary molecular motors
by Pollard, Michael M and Meetsma, Auke and Feringa, Ben L
Organic and Biomolecular Chemistry, ISSN 1477-0520, 2008, Volume 6, Issue 3, pp. 507 - 512
Structural modification of unidirectional light-driven rotary molecular motors in which the naphthalene moieties are exchanged for substituted phenyl moieties... 
SPEED | ACCELERATION | ROTOR | MOTION | UNIDIRECTIONAL ROTATION | CHEMISTRY, ORGANIC | STRUCTURAL MODIFICATION | Naphthalenes - chemistry | Magnetic Resonance Spectroscopy | Stereoisomerism | Crystallography, X-Ray | Alkenes - chemical synthesis | Rotation | Spectrophotometry, Ultraviolet | Alkenes - chemistry | Thermodynamics | Light | Mechanics | Hexanes - chemistry | Kinetics
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18. Full Text Polar Nature of (CH3NH3)3Bi2I9 Perovskite-Like Hybrids
by Kamminga, Machteld E and Stroppa, Alessandro and Picozzi, Silvia and Chislov, Mikhail and Zvereva, Irina A and Baas, Jacob and Meetsma, Auke and Blake, Graeme R and Palstra, Thomas T. M
Inorganic Chemistry, ISSN 0020-1669, 01/2017, Volume 56, Issue 1, pp. 33 - 41
High-quality single crystals of perovskite-like (CH3NH3)3Bi2I9 hybrids have been synthesized, using a layered-solution crystal-growth technique. The large... 
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19. Full Text MHz Unidirectional Rotation of Molecular Rotary Motors
by Klok, Martin and Boyle, Nicola and Pryce, Mary T and Meetsma, Auke and Browne, Wesley R and Feringa, Ben L
Journal of the American Chemical Society, ISSN 0002-7863, 08/2008, Volume 130, Issue 32, pp. 10484 - 10485
A combination of cryogenic UV−vis and CD spectroscopy and transient absorption spectroscopy at ambient temperature is used to study a new class of... 
ACCELERATION | MACHINES | SWITCHES | DYNAMICS | STATE | STRUCTURAL MODIFICATION | DRIVEN | TETRAPHENYLETHYLENE | CHEMISTRY, MULTIDISCIPLINARY | Cyclopentanes - chemistry | Cold Temperature | Solutions | Circular Dichroism | Rotation | Spectrophotometry, Ultraviolet | Molecular dynamics | Absorption spectra | Dynamics | Analysis
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20. Binding of copper(ii) polypyridyl complexes to DNA and consequences for DNA-based asymmetric catalysis
by Draksharapu, Apparao and Boersma, Arnold J and Leising, Miriam and Meetsma, Auke and Browne, Wesley R and Roelfes, Gerard
Dalton Transactions, ISSN 1477-9226, 02/2015, Volume 44, Issue 8, pp. 3647 - 3655
The interaction between salmon testes DNA (st-DNA) and a series of Cu super(II) polypyridyl complexes, i.e.[Cu(dmbpy)(NO sub(3)) sub(2)] (1) (dmbpy =... 
Binding | Bridging | Deoxyribonucleic acid | Dichroism | Ligands | Nitrates | Grooves | Intercalation
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