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1. Full Text Iridium Complexes Containing Mesoionic C Donors: Selective C(sp3)H versus C(sp2)H Bond Activation, Reactivity Towards Acids and Bases, and Catalytic Oxidation of Silanes and Water
by Petronilho, Ana and Woods, James A and Mueller‐Bunz, Helge and Bernhard, Stefan and Albrecht, Martin
Chemistry – A European Journal, ISSN 0947-6539, 11/2014, Volume 20, Issue 48, pp. 15775 - 15784
Metalation of a C2‐methylated pyridylimidazolium salt with [IrCp*Cl2]2 affords either an ylidic complex, resulting from C(sp3)H bond activation of the... 
iridium | oxidation | CH activation | mesoionic ligand | carbene | stability | Mesoionic ligand | Carbene | Oxidation | Stability | Iridium | Ch activation | KETONE HYDROSILYLATION | COORDINATION CHEMISTRY | N-HETEROCYCLIC CARBENE | IMIDAZOLYLIDENE-PYRIDYLIDENE LIGANDS | PALLADIUM COMPLEXES | OLEFIN METATHESIS | TRANSITION-METALS | CHEMISTRY, MULTIDISCIPLINARY | H ACTIVATION | C-H activation | MECHANISTIC INSIGHTS | IMIDAZOLIUM SALTS | Oxidation-Reduction | Pyridines - chemistry | Stereoisomerism | Triazoles - chemistry | Imidazoles - chemistry | Models, Molecular | Coordination Complexes - chemistry | Ligands | Organometallic Compounds - chemistry | Imidazolidines - chemistry | Molecular Structure | Catalysis | Iridium - chemistry | Catalytic oxidation | Acids | Aqueous solutions | Exchange | Silanes | Catalysts | Activation | Bonding
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2. Full Text Extended Reaction Scope of Thiamine Diphosphate Dependent Cyclohexane‐1,2‐dione Hydrolase: From CC Bond Cleavage to CC Bond Ligation
by Loschonsky, Sabrina and Wacker, Tobias and Waltzer, Simon and Giovannini, Pier Paolo and McLeish, Michael J and Andrade, Susana L. A and Müller, Michael
Angewandte Chemie International Edition, ISSN 1433-7851, 12/2014, Volume 53, Issue 52, pp. 14402 - 14406
ThDP‐dependent cyclohexane‐1,2‐dione hydrolase (CDH) catalyzes the CC bond cleavage of cyclohexane‐1,2‐dione to 6‐oxohexanoate, and the asymmetric benzoin... 
tertiary alcohols | enzyme catalysis | protein engineering | asymmetric synthesis | benzoin condensation | Protein engineering | Asymmetric synthesis | Enzyme catalysis | Tertiary alcohols | Benzoin condensation | KETO-ENOL TRANSFORMATION | 1,2-CYCLOHEXANEDIONE | CATALYSIS | ASYMMETRIC-SYNTHESIS | HYDROXY KETONES | MEND | CHEMISTRY, MULTIDISCIPLINARY | MEMBER | BACILLUS-SUBTILIS | ENZYME FAMILY | Hydrolases - metabolism | Catalytic Domain | Hydrolases - genetics | Pyruvic Acid - chemistry | Biocatalysis | Cyclohexanones - chemistry | Thiamine Pyrophosphate - chemistry | Thiamine Pyrophosphate - metabolism | Benzoin - chemistry | Cyclohexanones - metabolism | Carbon - chemistry | Azoarcus - enzymology | Pyruvic Acid - metabolism | Hydrolases - chemistry | Amino Acid Substitution | Pyruvates | Mutations | Enzymes | Asymmetry | Condensing | Cleavage | Bonding | Benzoin | Alcohols
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3. Full Text Recent Developments in Enzymatic Asymmetric CC Bond Formation
by Müller, Michael
Advanced Synthesis & Catalysis, ISSN 1615-4150, 11/2012, Volume 354, Issue 17, pp. 3161 - 3174
Some of the recent developments in enzymatic asymmetric CC bond formation are described in this review. The close relationship of biocatalysis and... 
biomimetic synthesis | C1 building blocks | biocatalysis | biosynthesis | CC coupling | C-C coupling | building blocks | CATALYTIC PROMISCUITY | ACTIVE-SITE | HYDROXYNITRILE LYASE | ALPHA-AMINO ACIDS | ESCHERICHIA-COLI | CHEMISTRY, ORGANIC | 4-HYDROXY-4-METHYL-2-OXOGLUTARATE ALDOLASE | CHEMOENZYMATIC SYNTHESIS | BERBERINE BRIDGE ENZYME | CHEMICAL-SYNTHESIS | CHEMISTRY, APPLIED | C-1 building blocks | 3-HYDROXY-3-METHYLGLUTARYL-COA SYNTHASE | Enzymes | Asymmetry | Transformations | Methylation | Aldolase | Carbon | Bonding | Radicals
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4. Full Text C–H Activation of 2,4,6-Triphenylphosphinine: Synthesis and Characterization of the First Homoleptic Phosphinine–Iridium(III) Complex fac-[Ir(C^P)3]
by Broeckx, Leen E. E and Delaunay, Wylliam and Latouche, Camille and Lutz, Martin and Boucekkine, Abdou and Hissler, Muriel and Müller, Christian
Inorganic Chemistry, ISSN 0020-1669, 10/2013, Volume 52, Issue 19, pp. 10738 - 10740
Access to homoleptic phosphinine-based coordination compounds of d6 metals has so far remained elusive. We report here on the preparation and full... 
Journal Article | COORDINATION CHEMISTRY | ROOM-TEMPERATURE | PHOSPHININES | PHOSPHORESCENCE | CYCLOMETALATED IRIDIUM(III) COMPLEXES | POLYDENTATE | DERIVATIVES | SOLID-STATE | CHEMISTRY, INORGANIC & NUCLEAR | Usage | Influence | Research | Iridium | Chemical properties | Chemical synthesis | Crystallography | Hydrogen bonding | or physical chemistry | Chemical Sciences | Theoretical and
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5. Full Text Asymmetric synthesis of (S)-phenylacetylcarbinol – closing a gap in C–C bond formation
by Sehl, Torsten and Bock, Saskia and Marx, Lisa and Maugeri, Zaira and Walter, Lydia and Westphal, Robert and Vogel, Constantin and Menyes, Ulf and Erhardt, Martin and Müller, Michael and Pohl, Martina and Rother, Dörte and Skolan för bioteknologi (BIO) and KTH and Industriell bioteknologi
Green Chemistry, ISSN 1463-9262, 2017, Volume 19, Issue 2, pp. 380 - 384
(S)-Phenylacetylcarbinol [(S)-PAC] and its derivatives are valuable intermediates for the synthesis of various active pharmaceutical ingredients (APIs), but... 
Naturvetenskap | Natural Sciences | Kemi | Chemical Sciences
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6. Full Text Shwachman-Bodian-Diamond syndrome (SBDS) protein deficiency impairs translation re-initiation from C/EBPα and C/EBPβ mRNAs
by In, Kyungmin and Zaini, Mohamad A and Müller, Christine and Warren, Alan J and von Lindern, Marieke and Calkhoven, Cornelis F
Nucleic acids research, ISSN 0305-1048, 2016, Volume 44, Issue 9, pp. 4134 - 4146
Mutations in the Shwachman-Bodian-Diamond Syndrome (SBDS) gene cause Shwachman-Diamond Syndrome (SDS), a rare congenital disease characterized by bone marrow... 
GENE SBDS | CELLS | EIF6 RELEASE | CONTROL REPORTER SYSTEM | BIOCHEMISTRY & MOLECULAR BIOLOGY | C-MYC | MITOTIC SPINDLE | ACUTE MYELOID-LEUKEMIA | BINDING | RIBOSOMAL-SUBUNIT | HEMATOPOIETIC STEM | CCAAT-Enhancer-Binding Proteins - metabolism | Exocrine Pancreatic Insufficiency - genetics | Proteins - physiology | Exocrine Pancreatic Insufficiency - metabolism | Gene Expression | CCAAT-Enhancer-Binding Protein-beta - genetics | Humans | RNA, Messenger - genetics | Gene Expression Regulation | Neutrophils - physiology | Bone Marrow Diseases - metabolism | Peptide Chain Initiation, Translational | Lipomatosis - genetics | RNA, Messenger - metabolism | Lipomatosis - metabolism | Proto-Oncogene Proteins c-myc - metabolism | Bone Marrow Diseases - genetics | CCAAT-Enhancer-Binding Protein-beta - metabolism | 5' Untranslated Regions | Cell Line, Tumor | Cell Differentiation | Proto-Oncogene Proteins c-myc - genetics | CCAAT-Enhancer-Binding Proteins - genetics | Gene regulation, Chromatin and Epigenetics
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7. Full Text Manufacturing porcine islets: culture at 22 °C has no advantage above culture at 37 °C: a gene expression evaluation
by Mueller, Kate R and Martins, Kyra V and Murtaugh, Michael P and Schuurman, Henk‐Jan and Papas, Klearchos K
Xenotransplantation, ISSN 0908-665X, 11/2013, Volume 20, Issue 6, pp. 418 - 428
Background The manufacturing process of islets includes a culture step which was originally introduced to ease the logistics of procedures in preparing the... 
lymphocyte markers | temperature | cytokines | chemokines | porcine islets | apoptotic markers | islet culture | Lymphocytes - metabolism | Gene Expression | Temperature | Humans | Oxygen Consumption | Islets of Langerhans - immunology | Genetic Markers | Islets of Langerhans Transplantation - methods | Chemokines - genetics | Islets of Langerhans Transplantation - immunology | Animals | Heterografts | Lymphocytes - immunology | Lymphokines - genetics | Islets of Langerhans - metabolism | Female | Tissue Culture Techniques - methods | Sus scrofa - immunology | Tissue and Organ Harvesting - methods | Gene expression | Swine | Genes | Production processes
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8. Full Text Extended Reaction Scope of Thiamine Diphosphate Dependent Cyclohexane‐1,2‐dione Hydrolase: From CC Bond Cleavage to CC Bond Ligation
by Loschonsky, Sabrina and Wacker, Tobias and Waltzer, Simon and Giovannini, Pier Paolo and McLeish, Michael J and Andrade, Susana L. A and Müller, Michael
Angewandte Chemie, ISSN 0044-8249, 12/2014, Volume 126, Issue 52, pp. 14630 - 14634
ThDP‐dependent cyclohexane‐1,2‐dione hydrolase (CDH) catalyzes the CC bond cleavage of cyclohexane‐1,2‐dione to 6‐oxohexanoate, and the asymmetric benzoin... 
Protein engineering | Benzoinkondensation | Enzymkatalyse | Tertiäre Alkohole | Asymmetrische Synthese | Pyruvates | Mutations | Asymmetry | Benzaldehyde | Cleavage | Diphosphates | Bonding | Benzoin | Alcohols
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9. Full Text Nickel‐Catalyzed C−H Chalcogenation of Anilines
by Müller, Thomas and Ackermann, Lutz
Chemistry – A European Journal, ISSN 0947-6539, 09/2016, Volume 22, Issue 40, pp. 14151 - 14154
The C−H thiolation of aniline derivatives was accomplished with a versatile nickel(II) catalyst under ligand‐free conditions. The robust nature of the nickel... 
selenylation | reaction mechanisms | nickel | C−H activation | sulfenylation | AZOLES | C(SP)-H BONDS | ACTIVATION | PYRIDINE | BOND FUNCTIONALIZATION | DIRECT THIOLATION | CHEMISTRY, MULTIDISCIPLINARY | DIRECT ALKYLATION | DIRECTING GROUPS | C-H activation | ALKENYLATION | Aniline | Nickel | Catalysis | Functional anatomy | Catalysts | Activation | Robustness | Derivatives | Strategy | Ligands | Tolerances | Activation analysis
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