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catalysis (10) 10
chemistry, multidisciplinary (10) 10
chemical synthesis (7) 7
palladium (7) 7
chemistry (6) 6
chemistry, organic (6) 6
ligands (6) 6
sulfone (6) 6
sulfones (6) 6
triarylmethanes (6) 6
arylation (5) 5
carbenes (5) 5
analysis (4) 4
carben (4) 4
chemical properties (4) 4
fullerenes (4) 4
heterocyclic compounds (4) 4
index medicus (4) 4
nanoparticles (4) 4
organoboron compounds (4) 4
thiols (4) 4
arylboronic acids (3) 3
c-60 (3) 3
copper (3) 3
cross-coupling reactions (3) 3
c‐c bond formation (3) 3
gold (3) 3
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homogeneous catalysis (3) 3
molecular structure (3) 3
optical properties (3) 3
organic chemistry (3) 3
palladium - chemistry (3) 3
phenyl sulfone (3) 3
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secondary (3) 3
self-assembled monolayers (3) 3
sequential arylation (3) 3
synthesis (3) 3
triarylmethane (3) 3
unsymmetrical triarylmethanes (3) 3
acids (2) 2
acyclic or carbocyclic compounds (2) 2
alcohols (2) 2
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anchors (2) 2
apparatus therefor (2) 2
aromatic compounds (2) 2
aryl bromides (2) 2
aryl halides (2) 2
asymmetric arylation (2) 2
biocompatibility (2) 2
boronic esters (2) 2
c-h bonds (2) 2
catalysis, phase‐transfer catalysis (2) 2
chemistry, physical (2) 2
clusters (2) 2
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cross coupling (2) 2
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design (2) 2
detection (2) 2
direct alpha-arylation (2) 2
electron-rich arenes (2) 2
enantioselective synthesis (2) 2
equilibrium acidities (2) 2
esters (2) 2
etching (2) 2
exchange (2) 2
fullerenes - chemistry (2) 2
gel electrophoresis (2) 2
general methods of organic chemistry (2) 2
halides (2) 2
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metallurgy (2) 2
methane - analogs & derivatives (2) 2
methane - chemistry (2) 2
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6,8-diazabicyclo[3.2.2]nonanes (1) 1
6,8-diazabicyclo[3.2.2]nonenes (1) 1
activation (1) 1
active alkyl bromides (1) 1
acyclic, carbocyclic or heterocyclic compounds containingelements other than carbon, hydrogen, halogen, oxygen, nitrogen,sulfur, selenium or tellurium (1) 1
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Angewandte Chemie International Edition, ISSN 1433-7851, 05/2017, Volume 56, Issue 22, pp. 6198 - 6202
Journal Article
ACS Catalysis, ISSN 2155-5435, 08/2015, Volume 5, Issue 8, pp. 4734 - 4742
Triarylmethanes and related compounds are fascinating molecules because of their structural and physical properties, many potential applications in organic... 
enantioselectivity | enantiospecificity | triarylmethane | transition metal catalysis | arylation | C-H BOND | TERT-BUTYL SULFONES | CHEMISTRY, PHYSICAL | ASYMMETRIC ARYLATION | CROSS-COUPLING REACTIONS | ALLYLIC BORONIC ESTERS | SEQUENTIAL ARYLATION | SUBSTITUTED UNSYMMETRICAL BIARYLS | EQUILIBRIUM ACIDITIES | ELECTRON-RICH ARENES | GRIGNARD-REAGENTS
Journal Article
ISSN 1477-0520, 8/2019, Volume 17, Issue 31, pp. 73 - 733
Herein, we report the transition-metal free, pyridine-catalyzed desulfonative borylation of benzyl sulfones with bis(pinacolato)diboron (B 2 pin 2 ). A variety... 
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 07/2007, Volume 129, Issue 26, pp. 8080 - 8081
Journal Article
Organic & Biomolecular Chemistry, ISSN 1477-0520, 01/2019, Volume 17, Issue 31, pp. 7300 - 7303
Herein, we report the transition-metal free, pyridine-catalyzed desulfonative borylation of benzyl sulfones with bis(pinacolato)diboron (B2pin2). A variety of... 
Pyridines | Transition metals | Sulfonamides | Esters | Ring opening | Sulfones
Journal Article
Chemistry Letters, ISSN 0366-7022, 8/2019, Volume 48, Issue 8, pp. 975 - 977
The synthesis of azole-containing triarylmethanes via the Cu-catalyzed desulfonylative reaction of benzhydryl sulfone derivatives with azoles is described.... 
Cu catalysis | Desulfonylative cross-coupling | CHEMISTRY, MULTIDISCIPLINARY | TRIARYLMETHANES | Triarylmethane | ARYLATION | Coupling (molecular) | Cross coupling | Copper | Heterocyclic compounds | Substrates | Sulfones
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 01/2014, Volume 53, Issue 3, pp. 601 - 601
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 02/2019, Volume 25, Issue 8, pp. 1923 - 1926
A new method for the synthesis of benzhydryl amines from the reaction of readily available sulfone derivatives with amines is described. The Cu‐catalyzed... 
carbenes | catalysis | copper | desulfonylative amination | sulfones | PALLADIUM | REAGENTS | IMINES | TOSYLHYDRAZONES | AMIDATION | ASYMMETRIC ARYLATION | CHEMISTRY, MULTIDISCIPLINARY | H AMINATION | DERIVATIVES | REDUCTIVE AMINATION | Amines | Amination | Chemical synthesis | Substrates | Sulfones
Journal Article
Nature Communications, ISSN 2041-1723, 04/2016, Volume 7, Issue 1, pp. 11065 - 11065
The Suzuki-Miyaura cross-coupling is one of the most often utilized reactions in the synthesis of pharmaceutical compounds and conjugated materials. In its... 
ALKENES | ENANTIOSELECTIVE SYNTHESIS | RETENTION | STRATEGY | MULTIDISCIPLINARY SCIENCES | ESTERS | SECONDARY | SINGLE-ELECTRON TRANSMETALATION | INVERSION | DIBORATION | BORYLATION
Journal Article
Nature Communications, ISSN 2041-1723, 12/2019, Volume 10, Issue 1, pp. 1 - 7
α-Fluoromethylarenes are common substructures in pharmaceuticals and agrochemicals, with the introduction of fluorine often resulting in improved biological... 
Substructures | Agricultural chemicals | Cross coupling | Biological effects | Synthesis | Agrochemicals | Bioactive compounds | Fluorine | Fluorination | Biological activity
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 03/2011, Volume 133, Issue 8, pp. 2402 - 2405
An aziridine moiety on the fullerene core can serve as an acid-triggered reacting template for the controlled synthesis of a range of functionalized fullerenes... 
ORGANOBORON COMPOUNDS | ORGANO(HYDRO)FULLERENES | CYCLOADDITION | EPOXIDE | REGIOCHEMISTRY | REGIOSELECTIVE SYNTHESIS | CHEMISTRY | C-60 | CATALYST | CHEMISTRY, MULTIDISCIPLINARY | RADICAL REACTIONS | Ligands | Molecular Structure | Fullerenes - chemistry | Aziridines - chemistry | Aziridines | Chemical properties | Chemical synthesis | Analysis | Electric properties
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 01/2018, Volume 140, Issue 1, pp. 78 - 81
We describe the development of a nickel-catalyzed Suzuki-Miyaura cross-coupling of tertiary benzylic and allylic sulfones with arylboroxines. A variety of... 
ENANTIOSELECTIVE SYNTHESIS | ACIDS | PHENYL SULFONE | TRIARYLMETHANES | CONSTRUCTION | CARBON STEREOCENTERS | SECONDARY | BORONIC ESTERS | CHEMISTRY, MULTIDISCIPLINARY | GRIGNARD-REAGENTS | ALKYL-HALIDES
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 10/2009, Volume 131, Issue 42, pp. 15112 - 15113
Journal Article
Chemistry - A European Journal, ISSN 0947-6539, 05/2009, Volume 15, Issue 19, pp. 4735 - 4735
Journal Article
Organic Letters, ISSN 1523-7060, 07/2017, Volume 19, Issue 14, pp. 3715 - 3718
The Pd-catalyzed desulfonative cross-coupling reaction of benzylic sulfone derivatives with 1,3-oxazoles via a deprotonative pathway has been developed. Broad... 
DIARYLMETHANES | HALIDES | UNSYMMETRICAL TRIARYLMETHANES | ALDIMINES | DIARYL | PHENYL SULFONE | SEQUENTIAL ARYLATION | ARENES | CHEMISTRY, ORGANIC | DIARYLMETHYLAMINES
Journal Article
Chemistry - A European Journal, ISSN 0947-6539, 05/2009, Volume 15, Issue 19, pp. 4760 - 4764
Palladium can tailor fullerenes: Palladium catalysts enable a number of C-H bond transformations of organo(hydro)fullerene. In addition to anticipated coupling... 
C-C cleavage | C-C coupling | Fullerenes | Palladium | Homogeneous catalysis | RETRO-CYCLOADDITION REACTION | X-RAY-STRUCTURE | fullerenes | ADDITION PATTERN | CHEMISTRY, MULTIDISCIPLINARY | homogeneous catalysis | FULLERENE FUNCTIONALIZATION | LIQUID-CRYSTALS | CONICAL MOLECULES | CHEMISTRY | palladium | NANOTUBES | C-60 | RADICAL REACTIONS
Journal Article
Nature Chemistry, ISSN 1755-4330, 05/2019, Volume 11, Issue 5, pp. 419 - 425
Magic-number gold nanoclusters are atomically precise nanomaterials that have enabled unprecedented insight into structure-property relationships in... 
NANOPARTICLES | CATALYSIS | SELF-ASSEMBLED MONOLAYERS | ELECTROCATALYTIC CO2 REDUCTION | LIGANDS | STABILIZATION | STABILITY | COPPER | SULFUR INTERFACE | CHEMISTRY, MULTIDISCIPLINARY | ANCHORS | Chemical reduction | Gold | Stability | Carbon dioxide | Bonding strength | Clusters | Ligands | Nanomaterials | Catalysis | Carbenes | Nanotechnology
Journal Article
Organic Letters, ISSN 1523-7060, 05/2016, Volume 18, Issue 10, pp. 2339 - 2342
A scandium-triflate-catalyzed arylative desulfonation of diarylmethyl phenyl sulfones with arenes and heteroarenes was established. A variety of both sulfone... 
UNSYMMETRICAL TRIARYLMETHANES | ALDIMINES | DESIGN | METHANES | SEQUENTIAL ARYLATION | CHEMISTRY | CHEMISTRY, ORGANIC | FLUORESCEIN | DERIVATIVES | THIOPHENE | PROBES
Journal Article
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