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The Journal of Organic Chemistry, ISSN 0022-3263, 09/2017, Volume 82, Issue 18, pp. 9824 - 9831
A cascade visible-light photocatalytic difluoroalkylation and intramolecular cyclization reaction has been developed for the synthesis of difluoroalkylated... 
BROMOLACTONIZATIONS | FUNCTIONALIZATION | UNSATURATED CARBOXYLIC-ACIDS | IODIDES | PHARMACEUTICALS | CHEMISTRY, ORGANIC | LACTONIZATION | OXYTRIFLUOROMETHYLATION | PERFLUOROALKYLATION | POLYFLUOROALKYL HALIDES | TRIFLUOROMETHYLATION | Research | Chemical properties | Ring formation (Chemistry) | Cascade reactions | Alkylation | Lactones | Photochemistry
Journal Article
Organic Letters, ISSN 1523-7060, 05/2017, Volume 19, Issue 10, pp. 2536 - 2539
A Ni-catalyzed reductive cross-coupling reaction between two electrophiles, amides and aryl iodides, has been developed. This work is the first example using... 
HALIDES | FUNCTIONALIZATION | PALLADIUM | KETONE SYNTHESIS | SECONDARY ALKYL BROMIDES | NICKEL CATALYSIS | ESTERS | COMPLEXES | CHLORIDES | CHEMISTRY, ORGANIC | CLEAVAGE
Journal Article
The Journal of Organic Chemistry, ISSN 0022-3263, 03/2015, Volume 80, Issue 6, pp. 3151 - 3158
A metal-free cyclization reaction of 2-isocyanobiphenyls with amide derivatives by using tert-butyl peroxybenzoate (TBPB) as oxidant was developed, which... 
2-ISOCYANOBIPHENYLS | ACTIVATION | PHENANTHRIDINE DERIVATIVES | DEHYDROGENATIVE-COUPLING CDC | TERTIARY-AMINES | SIMPLE ALKANES | CHEMISTRY, ORGANIC | TERMINAL ALKYNES | HYDROGEN-PEROXIDE | ALIPHATIC-AMINES | C-H BONDS | Chemical properties | Ring formation (Chemistry) | Research | Hydrogen bonding | Amino compounds
Journal Article
The Journal of Organic Chemistry, ISSN 0022-3263, 10/2016, Volume 81, Issue 19, pp. 9470 - 9475
A thiolation initiated cascade reaction of aryl alkynoates has been developed with thiol as a coupling partner. This radical process has been demonstrated to... 
ACTIVATED ALKYNES | DIFUNCTIONALIZATION | REARRANGEMENT | ALKENES | CYCLOADDITION | TRIFLUOROMETHYLTHIOLATION | RADICAL CYCLIZATION | THIOPHENOLS | CHEMISTRY, ORGANIC | HYDROTHIOLATION | DISULFIDES | Usage | Thiols | Analysis | Carboxylation | Chemical bonds | Chemical properties | Cascade reactions
Journal Article
PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, ISSN 0027-8424, 04/2019, Volume 116, Issue 18, pp. 8721 - 8727
Journal Article
Organic Letters, ISSN 1523-7060, 11/2017, Volume 19, Issue 21, pp. 5900 - 5903
An efficient photoredox-catalyzed alkylation/lactonization reaction of unsaturated carboxylic acids by using alkyl N-hydroxyphthalimide esters as alkylation... 
ELECTRON-TRANSFER | PHASE-TRANSFER | COPPER CATALYSIS | LIGHT | CHEMISTRY, ORGANIC | QUATERNARY CARBONS | REDOX-ACTIVE ESTERS | ALKENOIC ACIDS | GAMMA-LACTONES | ENANTIOSELECTIVE IODOLACTONIZATION | DECARBOXYLATIVE ALKYNYLATION
Journal Article
Organic Letters, ISSN 1523-7060, 06/2015, Volume 17, Issue 11, pp. 2724 - 2727
A metal-free hydroxyalkylation-initiated radical six-membered heterocycle formation reaction of N-allylbenzamide is developed. This reaction proceeds through... 
FUNCTIONALIZATION | ALCOHOLS | ALKENES | ACID | LIGANDS | C BOND FORMATION | COUPLING REACTION | CHEMISTRY, ORGANIC | ADJACENT | DERIVATIVES | CATALYSTS
Journal Article
Green Chemistry, ISSN 1463-9262, 07/2016, Volume 18, Issue 14, pp. 3935 - 3939
A sunlight-initiated radical conversion of aryl alkynoates to 3-iodocoumarins has been achieved using N-iodosuccinimide as the iodine source without the use of... 
Iodination | Pathways | Aromatic compounds | Decarboxylation | X-rays | Derivatives | Conversion | Radicals
Journal Article
Green Chemistry, ISSN 1463-9262, 2016, Volume 18, Issue 14, pp. 3935 - 3939
A sunlight-initiated radical conversion of aryl alkynoates to 3-iodocoumarins has been achieved using N-iodosuccinimide as the iodine source without the use of... 
ACTIVATED ALKYNES | NATURAL SUNLIGHT | GREEN & SUSTAINABLE SCIENCE & TECHNOLOGY | METAL-FREE CONDITIONS | VISIBLE-LIGHT PHOTOCATALYSIS | RADICAL CYCLIZATION | AEROBIC OXIDATION | DUAL-CATALYSIS | ALPHA-KETO ACIDS | CHEMISTRY, MULTIDISCIPLINARY | COUMARINS | PHOTOREDOX CATALYSIS
Journal Article
Organic Letters, ISSN 1523-7060, 11/2015, Volume 17, Issue 22, pp. 5524 - 5527
A cascade oxidative difunctionalization reaction of alkynoates for the construction of trisubstituted olefins has been developed. The process undergoes... 
ACTIVATED ALKYNES | FUNCTIONALIZATION | ACIDS | C BOND FORMATION | RADICAL CYCLIZATION | CONSTRUCTION | CHEMISTRY, ORGANIC | IONIC LIQUID | DERIVATIVES | FRIEDEL-CRAFTS ALKENYLATION | COUMARINS
Journal Article
Organic Letters, ISSN 1523-7060, 02/2016, Volume 18, Issue 4, pp. 712 - 715
An efficient cascade trifunctioalization reaction of alkynoates with N-iodosuccinimide has been developed which proceeds through iodination, aryl migration,... 
ACTIVATED ALKYNES | 1,1-DIBROMOALKENES | ARYL ALDEHYDES | COPPER-CATALYZED SYNTHESIS | ACIDS | RADICAL CYCLIZATION | CHEMISTRY, ORGANIC | SELECTIVE SYNTHESIS | IONIC LIQUID | FRIEDEL-CRAFTS ALKENYLATION | HIGHLY EFFICIENT
Journal Article
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, ISSN 0002-7863, 04/2019, Volume 141, Issue 16, pp. 6726 - 6739
Historically accessed through two-electron, anionic chemistry, ketones, alcohols, and amines are of foundational importance to the practice of organic... 
NICKEL | CARBONYL ADDITION | BOND FORMATION | STYRENE | REDOX-ACTIVE ESTERS | CHEMISTRY, MULTIDISCIPLINARY | ANHYDRIDE | N-(ACYLOXY)PHTHALIMIDES | ALKYL-HALIDES | GRIGNARD
Journal Article
Proceedings of the National Academy of Sciences of the United States, ISSN 0027-8424, 04/2019, Volume 116, Issue 18, p. 8721
The union of two powerful transformations, directed C-H activation and decarboxylative cross-coupling, for the enantioselective synthesis of vicinally... 
Chemical bonds | Carboxylic acids | Chemical properties | Research | Chemical research
Journal Article
Tetrahedron Letters, ISSN 0040-4039, 07/2015, Volume 56, Issue 27, pp. 4128 - 4130
A facile catalyst-free intramolecular cyclization reaction of N-allylbenzothioamide was developed affording thiazoles and thiazolines as products with good... 
N-Allylbenzothioamide | Thiazoline | Cyclization | Catalyst-free | Thiazole | ASYMMETRIC-SYNTHESIS | CHEMISTRY, ORGANIC | IDENTIFICATION | DISCOVERY | CROSS-COUPLING REACTIONS | OXAZOLE | POTENT | HETEROCYCLES | PRODRUGS | PHORBOXAZOLE B | INHIBITORS
Journal Article
Angewandte Chemie, ISSN 0044-8249, 10/2018, Volume 130, Issue 44, pp. 14768 - 14773
The direct union of primary, secondary, and tertiary carboxylic acids with a chiral glyoxylate‐derived sulfinimine provides rapid access into a variety of... 
Bibliotheksynthese | Synthesemethoden | Aminosäuresynthese | Redoxaktive Ester | Decarboxylierende radikalische Addition | Amino acids | Synthesis | Organic chemistry | Carboxylic acids | Chemical synthesis | Modular structures
Journal Article
Chemical Science, ISSN 2041-6520, 05/2020, Volume 11, Issue 19, pp. 4939 - 4947
Redox-active esters (RAEs) as alkyl radical precursors have demonstrated great advantages for C–C bond formation. A decarboxylative cross-coupling method is... 
Journal Article
ACS Catalysis, ISSN 2155-5435, 08/2018, Volume 8, Issue 8, pp. 7489 - 7494
Journal Article
Chemical Science, ISSN 2041-6520, 01/2020, Volume 11, Issue 19, pp. 4939 - 4947
Redox-active esters (RAEs) as alkyl radical precursors have demonstrated great advantages for C–C bond formation. A decarboxylative cross-coupling method is... 
Silanes | Cross coupling | Chemical engineering | Esters | Ligands | Chemical reactions | Carboxylic acids | Copper | Aliphatic compounds | Covalent bonds | Alkynes | Photoexcitation
Journal Article
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