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Angewandte Chemie - International Edition, ISSN 1433-7851, 08/2015, Volume 54, Issue 35, pp. 10276 - 10279
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 08/2015, Volume 54, Issue 35, pp. 10276 - 10279
A general procedure for the catalytic preparation of dibenzosiloles functionalized at one or both benzene rings starting from readily available ortho‐silylated... 
regioselectivity | homogeneous catalysis | SiH bond activation | microwave chemistry | electrophilic substitution | POLYMERS | RU-S BONDS | ASYMMETRIC-SYNTHESIS | COMPLEXES | SILOLES | 2+2+2 CYCLOADDITION | CHEMISTRY, MULTIDISCIPLINARY | H BOND ACTIVATION | Si-H bond activation | CHEMISTRY | SILAFLUORENES | DERIVATIVES | Substitution reactions | Sulfur compounds | Catalysis | Benzene | Analysis | Hydrocarbons
Journal Article
Angewandte Chemie (International Edition), ISSN 1433-7851, 08/2015, Volume 54, Issue 35, pp. 10276 - 10279
A general procedure for the catalytic preparation of dibenzosiloles functionalized at one or both benzene rings starting from readily available ortho-silylated... 
Catalysts | Chlorine | Benzene | Polymerization | Tolerances | Catalysis | Ethers | Bonding
Journal Article
Organometallics, ISSN 0276-7333, 02/2017, Volume 36, Issue 4, pp. 767 - 776
A protocol for the catalytic synthesis of indole-fused benzosiloles starting from 2-aryl-substituted indoles and dihydrosilanes is reported. Compared to known... 
RU-S BONDS | ACTIVATION | REGIOSELECTIVE DIRECT ARYLATION | ASYMMETRIC-SYNTHESIS | DEHYDROGENATIVE SILYLATION | STABILIZED SILYLIUM IONS | HYDROSILANES | CHEMISTRY, ORGANIC | SILOLES | 2+2+2 CYCLOADDITION | ANCILLARY LIGAND | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 07/2018, Volume 57, Issue 27, pp. 8301 - 8305
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 07/2018, Volume 57, Issue 29, pp. 9176 - 9179
An efficient method for the benzenium‐ion‐mediated cleavage of inert Si−C(sp3) bonds is reported. Various tetraalkylsilanes can thus be converted into the... 
density functional calculations | silylium ions | protonation | Brønsted acids | carboranes | TETRAMETHYLSILANE | ANIONS | BrOnsted acids | AUXILIARY BASIS-SETS | ACTIVATION | SILICON | SUBSTITUENTS | CHEMISTRY, MULTIDISCIPLINARY | SUPERACIDS | ORGANOSILICON COMPOUNDS | Silicon compounds | Structure | Crystals | Cleavage | Ions | Carborane
Journal Article
Chemical Science, ISSN 2041-6520, 01/2018, Volume 9, Issue 25, pp. 5600 - 5607
An in-depth experimental and theoretical study of the substituent exchange reaction of silylium ions is presented. Apart from the substitution pattern at the... 
Ion exchanging | Substitution reactions | Carborane | Chemical synthesis | Ion pairs
Journal Article
Accounts of Chemical Research, ISSN 0001-4842, 05/2017, Volume 50, Issue 5, pp. 1258 - 1269
Cooperative catalysis has attracted tremendous attention in recent years, emerging as a key strategy for the development of novel atom-economic and... 
THIOLATO-COMPLEXES | DIHYDROGEN ACTIVATION | NIFE HYDROGENASE | FUNCTIONAL MODELS | REACTIVITY | H-2 | C-H SILYLATION | CHEMISTRY, MULTIDISCIPLINARY | RU-S COMPLEX | ANCILLARY LIGAND | BASE
Journal Article
Angewandte Chemie, ISSN 0044-8249, 08/2015, Volume 127, Issue 35, p. 10414
  Es wird uber eine allgemeine Reaktionsvorschrift zur katalytischen Synthese von an einem oder beiden Benzolringen funktionalisierten Dibenzosilolen... 
Journal Article
Angewandte Chemie, ISSN 0044-8249, 08/2015, Volume 127, Issue 35, pp. 10414 - 10418
Es wird über eine allgemeine Reaktionsvorschrift zur katalytischen Synthese von an einem oder beiden Benzolringen funktionalisierten Dibenzosilolen berichtet,... 
Regioselektivität | Si‐H‐Bindungsaktivierung | Homogene Katalyse | Elektrophile Substitutionen | Mikrowellenchemie
Journal Article
Angewandte Chemie (International ed. in English), 08/2015, Volume 54, Issue 35, p. 10276
A general procedure for the catalytic preparation of dibenzosiloles functionalized at one or both benzene rings starting from readily available ortho-silylated... 
Journal Article
Chemical Science, ISSN 2041-6520, 2018, Volume 9, Issue 25, pp. 5600 - 5607
An in-depth experimental and theoretical study of the substituent exchange reaction of silylium ions is presented. Apart from the substitution pattern at the... 
FRUSTRATED LEWIS PAIR | CATALYSIS | R3SI | DIHYDROGEN ACTIVATION | BONDS | WEAKLY COORDINATING ANIONS | LEAVING-GROUP-APPROACH | EXCHANGE | CHEMISTRY, MULTIDISCIPLINARY | CATIONS | ACIDITY
Journal Article
Angewandte Chemie, ISSN 0044-8249, 07/2018, Volume 130, Issue 29, pp. 9317 - 9320
Es wird über eine effiziente Methode zur benzeniumionvermittelten Spaltung reaktionsträger Si‐C(sp3)‐Bindungen berichtet. Damit werden verschiedene... 
Silyliumionen | Brønsted-Säuren | Protonierung | Carborane | Dichtefunktionalrechnungen | Protons
Journal Article
Angewandte Chemie, ISSN 0044-8249, 07/2018, Volume 130, Issue 27, pp. 8433 - 8437
Aromatenstabilisierte Silyliumionen reagieren mit Kohlenmonoxid und eben nicht Kohlenmonoxidaddukte von Silyliumionen mit Aromaten. Dieser Mechanismus ist... 
Silyliumionen | Carborane | Elektrophile aromatische Substitution | Kohlenmonoxid | Lewis-Säuren
Journal Article
ChemInform, ISSN 0931-7597, 12/2015, Volume 47, Issue 3, pp. no - no
A facile protocol is developed for the microwave assisted conversion of ortho‐silylated biphenyls into dibenzosiloles, including dichloro‐substituted... 
organo‐silicon compounds | ring closure reactions, annulation reactions | catalysis, phase‐transfer catalysis | microwave chemistry, sonochemistry, mechanochemistry | Benzene | Catalysis
Journal Article
04/2015, 1, ISBN 9783700176992
Treibhausgasemissionen führen zu deutlicher globaler Erwärmung. Die globalen Treibhausgasemissionen (THG-Emissionen) steigen weiterhin entlang des „Business As... 
Book Chapter
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