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Organometallics, ISSN 0276-7333, 12/2010, Volume 29, Issue 23, pp. 6298 - 6307
An osmium-promoted assembly of two allylamine molecules and gem-disubstituted allenes to afford π-allyl ligands with a diamine pendant substituent is reported.... 
ORGANOMETALLIC COMPOUNDS | MOLECULAR-STRUCTURE | ALPHA-ALKENYLPHOSPHINE | INSERTION REACTIONS | INTRAMOLECULAR HYDROAMINATION | X-RAY | CHEMISTRY, ORGANIC | TERMINAL ALKYNES | DIHYDRIDE-OSMIUM(IV) COMPLEX | GEMINAL DEHYDROGENATION | HYDROGEN MIGRATION | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 07/2007, Volume 129, Issue 28, pp. 8850 - 8859
Complex [OsH(CCCPh2)(CH3CN)2(P i Pr3)2]BF4 (1) reacts with primary and secondary alcohols to give the corresponding dehydrogenated alcohols and the... 
ONE-POT SYNTHESIS | NUCLEOPHILIC-ADDITION REACTIONS | TRANSITION-METAL | OLEFIN METATHESIS REACTIONS | RUTHENIUM COMPLEXES | TERMINAL ALKYNES | CARBENE COMPLEXES | UNSATURATED ETA-CARBON LIGANDS | CARBYNE COMPLEXES | CHEMISTRY, MULTIDISCIPLINARY | RAY CRYSTAL-STRUCTURE
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 04/2006, Volume 128, Issue 14, pp. 4596 - 4597
Complex OsH2Cl2(P i Pr3)2 promotes the C−H activation of 2-vinylpyridine and subsequently couples the activated substrate with a second 2-vinylpyridine and two... 
TRANSFORMATION | DEHYDROGENATION | LIGANDS | MOLECULAR-STRUCTURE | ALPHA-ALKENYLPHOSPHINE | COMPLEXES | REACTIVITY | CATALYTIC-ACTIVITY | ALKYNES | DERIVATIVES | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
Organometallics, ISSN 0276-7333, 05/2017, Volume 36, Issue 9, pp. 1848 - 1859
Four different pincer ligands, which prove that the disposition of the donor atoms in pincer ligands allows them to develop a marked ability to form less... 
H BOND ACTIVATION | PALLADIUM(II) PYRAZOLIN-4-YLIDENES | ELECTROPHOSPHORESCENT DEVICES | EMITTING ELECTROCHEMICAL-CELLS | MOLECULAR-ORBITAL METHODS | HETEROCYCLIC CARBENE COMPLEXES | POP-PINCER OSMIUM | N-H | CHEMISTRY, ORGANIC | CYCLOMETALATED PLATINUM(II) COMPLEX | HIGH-EFFICIENCY | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Inorganic Chemistry, ISSN 0020-1669, 04/2018, Volume 57, Issue 7, pp. 3720 - 3730
The preparation and photophysical properties of heteroleptic iridium­(III) complexes containing a dianionic C,C,C,C-tetradentate ligand and a cyclometalated... 
H BOND ACTIVATION | IR(III) COMPLEXES | ANCILLARY LIGANDS | TRANSITION-METAL-COMPLEXES | CYCLOMETALATED COMPLEXES | TETRA-NHC LIGANDS | TRANSFER HYDROGENATION | N-HETEROCYCLIC CARBENES | HEME ANALOG | BISCARBENE COMPLEXES | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Organometallics, ISSN 0276-7333, 12/1997, Volume 16, Issue 26, pp. 5826 - 5835
EHT-MO Calculations on the model cation [Ru(η5-C5H5)(CCCH2)(CO)(PH3)]+ (1a) suggest that 23% and 31% of the LUMO and 26% of the HOMO of... 
RUTHENIUM(II) COMPLEXES | FISCHER CARBENE COMPLEXES | ORGANOMETALLIC CHEMISTRY | CHEMISTRY, ORGANIC | VINYLIDENE | CHROMIUM | BOND | CARBYNE COMPLEXES | DERIVATIVES | MOLECULAR-ORBITAL CALCULATIONS | RAY CRYSTAL-STRUCTURE | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Organometallics, ISSN 0276-7333, 07/2018, Volume 37, Issue 13, pp. 2014 - 2017
The redox-assisted C­(sp)–C­(sp3) bond activation of alkylnitriles coordinated to osmium­(II) dihydride fragments has been performed with an osmium­(VI)... 
TRANSFER HYDROCYANATION | RHODIUM | NICKEL | ORGANONITRILES | COMPLEXES | CHEMISTRY | CHEMISTRY, ORGANIC | CARBON-CARBON BONDS | INTERCONVERSION | ACETONITRILE | CLEAVAGE | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Organometallics, ISSN 0276-7333, 03/2004, Volume 23, Issue 6, pp. 1340 - 1348
The hexahydride complex OsH6(PiPr3)2 (1) activates the C−Hα bond of aldehydes. In toluene under reflux, the reactions with benzaldehyde,... 
HOMOGENEOUS CATALYSTS | AROMATIC KETONES | ALKYL | MOLECULAR-STRUCTURE | SELECTIVE DIMERIZATION | BOND-FORMING REACTIONS | ESTERS | REACTIVITY | CHEMISTRY, ORGANIC | DIHYDROGEN COMPLEXES | HOMOLEPTIC LANTHANIDE AMIDES | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Organometallics, ISSN 0276-7333, 04/2002, Volume 21, Issue 9, pp. 1841 - 1848
The Cβ−Cγ bond of the allenylidene ligand of [Ru(η5-C5H5)(CCCPh2)(CO)(PiPr3)]BF4 (1) adds dienes such as isoprene, cyclopentadiene, and 1,3-cyclohexadiene.... 
ORGANOMETALLIC COMPOUNDS | CUMULENYLIDENE | BF4 | X-RAY | REACTIVITY | CHEMISTRY, ORGANIC | ACETYLIDE COMPLEXES | VINYLIDENE COMPLEXES | (C=C=CPH2)(CO)(PPR3I)>BF4 | UNSATURATED ETA-CARBON LIGANDS | CYCLOHEPTATRIENYLVINYLIDENE COMPLEXES | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Organometallics, ISSN 0276-7333, 11/2018, Volume 37, Issue 21, pp. 3770 - 3779
Complexes [Ir­(μ-Cl)­(η2-C8H14)2]2 (1) and [Ir­(μ-Cl)­(η4-C8H12)]2 (2) promote the pyridyl-directed ortho-CH and ortho-CBr activations of the phenyl... 
PALLADIUM | RHODIUM | COUPLING REACTIONS | HYDROGEN-TRANSFER | DEHALOGENATION | REACTIVITY | CHEMISTRY, ORGANIC | CRYSTAL-STRUCTURES | HALIDE OXIDATIVE ADDITION | ARYL CHLORIDES | SELECTIVE ADDITION | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Organometallics, ISSN 0276-7333, 01/2017, Volume 36, Issue 1, pp. 114 - 128
The C–Cl bond cis oxidative addition of 12 chloroarenes, including chlorobenzene, chlorotoluenes, chlorofluorobenzenes, and di- and trichlorobenzenes to... 
ACTIVATION | O-P LIGAND | INTERMOLECULAR ALKENE | CHEMISTRY, ORGANIC | WILKINSONS CATALYST | MECHANISTIC INSIGHT | H BONDS | S-SUBSTITUTED ALDEHYDES | REDUCTIVE ELIMINATION | PHOSPHINE COMPLEXES | ARYL CHLORIDES | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Organometallics, ISSN 0276-7333, 11/2011, Volume 30, Issue 21, pp. 5710 - 5715
The bis(dihydrogen) complex [OsTp(η2-H2)2(PiPr3)]BF4 (1; Tp = hydridotris(pyrazolyl)borate) reacts with ethylene under 2 atm of the gas to afford... 
CATALYZED ADDITION | AROMATIC KETONES | ALPHA-ALKENYLPHOSPHINE | SPECTROSCOPIC CHARACTERIZATION | RUTHENIUM COMPLEXES | CHEMISTRY, ORGANIC | TERMINAL ALKYNES | DIHYDRIDE-DIHYDROGEN | PROTON-TRANSFER | DIHYDROGEN COMPLEXES | BASIC METALS | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Journal of Organometallic Chemistry, ISSN 0022-328X, 2011, Volume 696, Issue 25, pp. 3911 - 3923
Journal Article
Organometallics, ISSN 0276-7333, 01/2003, Volume 22, Issue 1, pp. 162 - 171
Journal Article
Organometallics, ISSN 0276-7333, 01/2006, Volume 25, Issue 3, pp. 693 - 705
The vinylidene complex Os(η5-C5H5)Cl(CCHPh)(PiPr3) (1) reacts with MeMgCl to give the osmaindene (2), which isomerizes into the exo-allyl compound... 
ORGANOMETALLIC CONFORMATIONAL EQUILIBRIA | HYDRIDO-VINYLIDENE COMPLEX | ONE-POT SYNTHESIS | COUPLING REACTIONS | ALPHA-ALKENYLPHOSPHINE | X-RAY | DIHYDROGEN COMPLEX | CHEMISTRY, ORGANIC | TERMINAL ALKYNES | OXIDATIVE ADDITION | TRANSITION-METAL BOND | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Organometallics, ISSN 0276-7333, 06/2016, Volume 35, Issue 11, pp. 1597 - 1600
Metal-mediated direct C–H bond activation at the 8-position of quinolines, which is the essential step for the functionalization of this bond, is promoted by... 
NH-TAUTOMERIZATION | FUNCTIONALIZATION | HYDROGENATION | HETEROCYCLES | LIGANDS | TRIOSMIUM CLUSTERS | REACTIVITY | CHEMISTRY, ORGANIC | COORDINATION | RUTHENIUM | POLYHYDRIDE COMPLEXES | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Organometallics, ISSN 0276-7333, 07/2004, Volume 23, Issue 15, pp. 3627 - 3639
The hexahydride complex OsH6(PiPr3)2 (1) reacts with 2-vinylpyridine to give the trihydride derivative (2). The β- and γ-positions of the pyridine ring are... 
TRANSITION-METAL HYDRIDES | IONIC HYDROGENATIONS | AROMATIC KETONES | AGOSTIC INTERACTIONS | NMR-SPECTROSCOPY | CARBONYL HYDRIDES | X-RAY | CHEMISTRY, ORGANIC | DIHYDROGEN COMPLEXES | LOW-TEMPERATURE | H ACTIVATION | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
ORGANOMETALLICS, ISSN 0276-7333, 10/2019, Volume 38, Issue 19, pp. 3707 - 3718
The study of the reactions of IrH5((PPr3)-Pr-i)(2) (1) with 2,6-diphenylpyridine and 2-phenoxy-6-phenylpyridine and the photophysical characterization of some... 
IR(III) COMPLEXES | DEHYDROGENATION | DIHYDROGEN | PINCER COMPLEXES | DEHYDROPOLYMERIZATION | CHEMISTRY, ORGANIC | COORDINATION | BOND ACTIVATION | QUANTUM EFFICIENCY | REDUCTIVE ELIMINATION | C-H | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
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