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chemistry, inorganic & nuclear (19) 19
chemistry, multidisciplinary (19) 19
chemistry, organic (19) 19
catalysis (17) 17
ligands (17) 17
palladium (12) 12
catalysts (11) 11
pyridine (11) 11
ligand (9) 9
nickel (9) 9
analysis (8) 8
carbenes (8) 8
complexes (8) 8
n-heterocyclic carbenes (8) 8
reactivity (8) 8
activation (7) 7
amines (7) 7
carbodicarbene (7) 7
chemistry (7) 7
coordination chemistry (7) 7
c‐c bond formation (7) 7
direct arylation (7) 7
bond (6) 6
bond activation (6) 6
selective alkenylation (6) 6
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alkaloids (5) 5
carben (5) 5
carbene (5) 5
catalysis, phase‐transfer catalysis (5) 5
chemical properties (5) 5
coupling (5) 5
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index medicus (4) 4
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organometallic compounds - chemistry (4) 4
polymerization (4) 4
silver (4) 4
structural implications (4) 4
acid catalysis (3) 3
bonding (3) 3
carbodicarbenes (3) 3
carbone (3) 3
catalytic application (3) 3
chemical reactions (3) 3
chemistry, physical (3) 3
cross-coupling (3) 3
gold (3) 3
homogeneous catalysis (3) 3
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materials science, multidisciplinary (3) 3
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n-heterocyclic carbene (3) 3
organocatalysis (3) 3
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usage (3) 3
2,6-diacetylpyridine (2) 2
2nd-row elements (2) 2
air (2) 2
aldehydes (2) 2
alkenes (2) 2
allen (2) 2
aryl halides (2) 2
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bearing (2) 2
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crystallography, x-ray (2) 2
density functionals (2) 2
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electronics (2) 2
electrons (2) 2
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Journal of the American Chemical Society, ISSN 0002-7863, 09/2010, Volume 132, Issue 34, pp. 11887 - 11889
Journal Article
ISSN 1359-7345, 3/2014, Volume 5, Issue 28, pp. 3671 - 3673
An efficient Pd-catalyzed cross-dehydrogenative coupling of heteroarenes with styrenes and other olefinic substrates has been developed. This alkenylation... 
Journal Article
Organometallics, ISSN 0276-7333, 11/2017, Volume 36, Issue 21, pp. 4287 - 4297
Palladium complexes supported with the mixed ligands carbodicarbene (CDC) and different phosphine ligands (PPh3, PTol3, and PCy3) were prepared, and their... 
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 04/2013, Volume 135, Issue 14, p. 5294
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 04/2013, Volume 135, Issue 14, pp. 5294 - 5297
Journal Article
Chemical Communications, ISSN 1359-7345, 04/2014, Volume 50, Issue 28, pp. 3671 - 3673
An efficient Pd-catalyzed cross-dehydrogenative coupling of heteroarenes with styrenes and other olefinic substrates has been developed. This alkenylation... 
H BOND ACTIVATION | FUNCTIONALIZATION | PALLADIUM | DIRECT ARYLATION | BENZOXAZOLES | AROMATIC SUBSTITUTION | METAL | CARBON-HYDROGEN BONDS | N-OXIDES | C3 ALKENYLATION | CHEMISTRY, MULTIDISCIPLINARY | Ligands | Coupling | Styrenes | Dehydrogenation | Heterocyclic compounds | Substrates
Journal Article
Organic Letters, ISSN 1523-7060, 10/2013, Volume 15, Issue 20, pp. 5358 - 5361
The first Ni-promoted prototype reaction based on the tandem C–H activation of heteroarenes with alkene isomerization is demonstrated, leading to the branched... 
DIRECT ARYLATION | OLEFINATION | NICKEL/LEWIS-ACID CATALYSIS | ALKYLATION | BOND FUNCTIONALIZATION | CHEMISTRY, ORGANIC | SELECTIVE ALKENYLATION | PYRIDINES | OXIDATIVE ADDITION | OLIGOMERIZATION | CARBON-HYDROGEN
Journal Article
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 12/2015, Volume 54, Issue 50, pp. 15207 - 15212
A simple and convergent synthetic strategy used to increase the diversity of the carbodicarbene ligand framework through incorporation of unsymmetrical pendant... 
organocatalysis | ligand design | carbodicarbenes | CO2 activation | carbene ligands | activation | COORDINATION CHEMISTRY | N-HETEROCYCLIC CARBENE | DATIVE BONDS | CATALYTIC METHYLATION | CHEMISTRY, MULTIDISCIPLINARY | STRUCTURAL IMPLICATIONS | REDUCTION | H BONDS | MAIN-GROUP COMPOUNDS | CARBON-DIOXIDE | B-H | Methylation | Analysis | Amines | Ligands
Journal Article
Organometallics, ISSN 0276-7333, 09/2006, Volume 25, Issue 20, pp. 4728 - 4730
Lithium hexamethyldisilazide (LiN(SiMe3)2) is an excellent precatalyst for the room-temperature guanylation of a variety of aryl amines with carbodiimides and... 
COORDINATION CHEMISTRY | REACTION-RATES | LITHIUM HEXAMETHYLDISILAZIDE | MEDIATED KETONE ENOLIZATION | ESTER-INTERCHANGE REACTION | MAIN-GROUP | COMPLEXES | INTRAMOLECULAR HYDROAMINATION | CHEMISTRY, ORGANIC | POLYMERIZATION | METAL ALKOXIDE CLUSTERS | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Chemical Communications, ISSN 1359-7345, 07/2012, Volume 48, Issue 53, pp. 6702 - 6704
An amino-linked nitrogen heterocyclic carbene (amino-NHC), 1-tBu, has been shown to mediate carbon-carbon coupling through the direct C-H functionalization of... 
SINGLE-ELECTRON-TRANSFER | PHENOL ETHERS | ALKOXIDES | ARYL HALIDES | NUCLEOPHILIC-SUBSTITUTION | ORGANOCATALYSIS | BUTOXIDE | UNACTIVATED ARENES | C-H ACTIVATION | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
ISSN 1477-9226, 9/2016, Volume 45, Issue 36, pp. 14327 - 14334
The preparation and characterization of a series of divalent 3d transition metal complexes supported by a tridentate planar bis(iminopyridine) ligand are... 
Journal Article
ISSN 1359-7345, 11/2015, Volume 51, Issue 96, pp. 1714 - 1717
para -CH activation of pyridine with allylbenzene is described by Ni/Al cooperative catalysis in combination with a bulkier NHC ligand and a Lewis acid,... 
Journal Article
Organic Letters, ISSN 1523-7060, 09/2014, Volume 16, Issue 18, pp. 4826 - 4829
The catalytic method features a cooperative interaction between Ni and Al imparting remote C–H alkenylation at the C5 position of imidazo[1,5-a]pyridine with... 
FUNCTIONALIZATION | HETEROARENES | OLEFINATION | HETEROCYCLIC CARBENE LIGANDS | ACID CATALYSIS | CHEMISTRY, ORGANIC | SELECTIVE ALKENYLATION | UNACTIVATED ARENES | N-OXIDES | CATALYZED DIRECT ARYLATION | MARINE SPONGE
Journal Article
Chemical Communications, ISSN 1359-7345, 2015, Volume 51, Issue 96, pp. 17104 - 17107
para-CH activation of pyridine with allylbenzene is described by Ni/Al cooperative catalysis in combination with a bulkier NHC ligand and a Lewis acid, leading... 
BOND ACTIVATION | SELECTIVE ALKENYLATION | RH(I)-CATALYZED DIRECT ARYLATION | CHEMISTRY, MULTIDISCIPLINARY | ALKYLATION | H ACTIVATION
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 09/2017, Volume 139, Issue 36, pp. 12830 - 12836
An investigation of carbodicarbenes, the less explored member of the carbenic complex/ligand family has yielded unexpected electronic features and concomitant... 
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 02/2015, Volume 54, Issue 8, pp. 2420 - 2424
Journal Article
Chemical Communications: Chem Comm, ISSN 1359-7345, 03/2014, Volume 50, Issue 33, pp. 4344 - 4346
Synthesis of guanidine-linked NHC can be achieved easily through reacting amino-NHC with carbodiimide. Subsequently, guanidine-NHC Ag and Cu complexes were... 
Synthesis (chemistry) | Hydroboration | Synthesis | Catalysts | Guanidines | Catalysis | Carbodiimides | Alkynes
Journal Article
Organometallics, ISSN 0276-7333, 01/2012, Volume 31, Issue 2, pp. 637 - 643
Journal Article
ChemCatChem, ISSN 1867-3880, 04/2018, Volume 10, Issue 7, pp. 1476 - 1476
The Front Cover shows the carbodicarbene, which is a new family member in the class of low‐valent carbon (0) compounds that bear two free electron lone pairs.... 
ligand design | carbone | homogeneous catalysis | carbodicarbene | carbene
Journal Article
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