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Nature communications, ISSN 2041-1723, 2017, Volume 8, Issue 1, p. 15022
Organoboranes are some of the most synthetically valuable and widely used intermediates in organic and pharmaceutical chemistry. Their synthesis, however, is... 
FUNCTIONALIZATION | LITHIUM BORYL | ANION | DIANION | MULTIDISCIPLINARY SCIENCES | CENTERED NUCLEOPHILE | COMPLEXES | REACTIVITY | CHEMISTRY | BORYLLITHIUM | B BONDS
Journal Article
Nature chemistry, ISSN 1755-4330, 2010, Volume 2, Issue 12, pp. 1056 - 1061
Journal Article
Inorganic Chemistry, ISSN 0020-1669, 04/2015, Volume 54, Issue 7, pp. 3702 - 3710
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 2011, Volume 50, Issue 40, pp. 9456 - 9458
New bonds for the uranyl: The controlled conversion of an uranyl oxo group ([UO2]+) into covalently bonded UOH and UOSi groups is described for pentavalent... 
actinides | uranyl hydroxide | oxo functionalization | pentavalent uranyl | schiff‐base macrocycle | schiff-base macrocycle | OXYGEN-EXCHANGE | CATALYSIS | ACTIVATION | INFRARED-SPECTROSCOPY | CHEMISTRY, MULTIDISCIPLINARY | FUNCTIONALIZATION | DICATION | REDUCTION | LIGAND | LEWIS-ACID COORDINATION | HYDROXIDE
Journal Article
Angewandte Chemie (International ed.), 12/2017, Volume 56, Issue 51, p. 16363
Reactions of a magnesium-based pinacolatoboryl nucleophile with the electrophilic organoboranes, 9-BBN and Ph B, provide facile B-B' single bond formation.... 
Journal Article
Chemical science (Cambridge), ISSN 2041-6520, 07/2019, Volume 10, Issue 27, pp. 6672 - 6682
Reactions of the β-diketiminato magnesium diboranate derivative, [(BDI)Mg{pinB(n-Bu)Bpin}] (BDI = HC{(Me)CNDipp}2; Dipp = 2,6-i-Pr2C6H3), with N,N′-dialkyl and... 
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 05/2015, Volume 21, Issue 21, pp. 7690 - 7694
Journal Article
CHEMICAL COMMUNICATIONS, ISSN 1359-7345, 08/2019, Volume 55, Issue 61, pp. 9035 - 9038
Reaction of a magnesium diboranate complex with triphenylphosphine oxide provides a terminal magnesium boryl, which is itself a potent reagent for the... 
NUCLEOPHILIC BORON | ANION | RHODIUM(I) BORYL COMPLEX | HETEROCYCLIC CARBENE ANALOG | REACTIVITY | STRUCTURAL-CHARACTERIZATION | BOND FORMATION | DIBORON COMPOUNDS | GALLYL COMPLEXES | CHEMISTRY, MULTIDISCIPLINARY | GALLIUM
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 12/2017, Volume 56, Issue 51, pp. 16363 - 16366
Reactions of a magnesium‐based pinacolatoboryl nucleophile with the electrophilic organoboranes, 9‐BBN and Ph3B, provide facile B−B′ single bond formation.... 
boranes | diborane | magnesium | main-group chemistry | boryl groups | METAL-PROMOTED REACTIONS | NUCLEOPHILIC BORON | HYDRIDE ABSTRACTION | ORGANIC-SYNTHESIS | SINGLE | CARBORANES | CHEMISTRY, MULTIDISCIPLINARY | BORYLLITHIUM | HYDROBORANE | CHEMISTRY | Chemical tests and reagents | Isomerization | Organoboranes | Diborane | Magnesium | Bonding | Thermal stability | Communications | Communication
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 2018, Volume 57, Issue 33, pp. 10688 - 10691
Reactions of readily accessible magnesium‐centered pinacolatoboryl nucleophiles with [(Ph2B)2O] result in B−O bond activation of the diphenylborinic anhydride.... 
boranes | magnesium | diboranes | boron | main group chemistry | METAL-PROMOTED REACTIONS | B-B SINGLE | REACTIVITY | BOND FORMATION | CARBORANES | BORANE | CHEMISTRY, MULTIDISCIPLINARY | ALPHA,BETA-UNSATURATED CONJUGATED COMPOUNDS | BORYLLITHIUM | BORON HYDRIDES | CHEMISTRY | Chemical tests and reagents | Anhydrides | Boron | Diborane | Metathesis | Magnesium | Chemical synthesis | Nucleophiles
Journal Article
Dalton transactions : an international journal of inorganic chemistry, ISSN 1477-9226, 2018, Volume 47, Issue 21, pp. 7300 - 7305
Reactions of β-diketiminato magnesium diboronate complexes with 4-dimethylaminopyridine or diborane reagents provide terminal boryl or triborane anions,... 
ORGANIC-SYNTHESIS | DEPROTONATION | LITHIUM BORYL | ANION | REACTIVITY | CHEMISTRY | METAL BORYL COMPLEXES | ALPHA,BETA-UNSATURATED CONJUGATED COMPOUNDS | BORYLLITHIUM | BORON-CENTERED NUCLEOPHILE | CHEMISTRY, INORGANIC & NUCLEAR | Diborane | Anions | Magnesium | Molecular chains | Constitution
Journal Article
Organometallics, ISSN 0276-7333, 12/2018, Volume 37, Issue 23, pp. 4457 - 4464
The diboranate derivative, [HC­{(Me)­CNDipp}2Mg­{pinBB­(n-Bu)­pin}], resulting from treatment of a β-diketiminato magnesium n-butyl derivative with the... 
DEPROTONATION | ACTIVATION | BORON | REDUCTION | COMPLEXES | REACTIVITY | CHEMISTRY | CHEMISTRY, ORGANIC | BOND FORMATION | HYDROSILATION | BIS(PENTAFLUOROPHENYL)BORANE | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 05/2020
Oxoborane carbamate and carboxylate analogues result from the in situ trapping of [BO 2 ] -  produced by elimination of 2,3-dimethyl-2-butene from a... 
Journal Article
ISSN 1477-9226, 5/2018, Volume 47, Issue 21, pp. 73 - 735
... Diborane heterolysis: breaking and making B–B bonds at magnesium† Anne-Frédérique Pécharman, Michael S. Hill * and Mary F. Mahon Reaction of the dimeric β-diketiminato... 
Journal Article
Angewandte Chemie, ISSN 1521-3757, 2018, Volume 130, Issue 33, pp. 10848 - 10851
Reactions of readily accessible magnesium‐centered pinacolatoboryl nucleophiles with [(Ph2B)2O] result in B−O bond activation of the diphenylborinic anhydride.... 
Hauptgruppenchemie | Borane | Diborane | Magnesium | Bor | Chemical tests and reagents | Anhydrides | Boron | Metathesis | Chemical synthesis | Nucleophiles
Journal Article
Dalton transactions : an international journal of inorganic chemistry, ISSN 1477-9226, 2010, Volume 39, Issue 14, pp. 3501 - 3508
The synthesis of the mono-uranyl complex [UO2(THF)(H2LMe)] of a ditopic Schiff-base pyrrole macrocycle is described and is shown to adopt a Pacman wedge-shaped... 
URANIUM | GEOMETRIES | DESIGN | ACID | PROPERTY | STEREOGNOSTIC COORDINATION CHEMISTRY | OXO | NP(V) | PENTAVALENT URANYL | ACTINYL IONS | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Angewandte Chemie, ISSN 0044-8249, 12/2017, Volume 129, Issue 51, pp. 16581 - 16584
Reactions of a magnesium‐based pinacolatoboryl nucleophile with the electrophilic organoboranes, 9‐BBN and Ph3B, provide facile B−B′ single bond formation.... 
Hauptgruppenchemie | Borane | Diborane | Borylgruppen | Magnesium | Chemical tests and reagents | Isomerization | Organoboranes
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 2009, Volume 48, Issue 16, pp. 2964 - 2968
A question of coordination mode: Two new borane compounds are prepared. They act as bifunctional ligands as illustrated by their reaction with ruthenium... 
hydrides | bifunctional ligands | ruthenium | boron | agostic interactions | Physics | Chemical Physics
Journal Article