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The Journal of Organic Chemistry, ISSN 0022-3263, 10/2014, Volume 79, Issue 20, pp. 9899 - 9906
Journal Article
Chemical Reviews, ISSN 0009-2665, 07/2017, Volume 117, Issue 13, pp. 9247 - 9301
Catalytic transformation of ubiquitous C–H bonds into valuable C–N bonds offers an efficient synthetic approach to construct N-functionalized molecules. Over... 
INTRAMOLECULAR C(SP)-H AMINATION | NITROGEN-CONTAINING HETEROCYCLES | UNACTIVATED C(SP)-H BONDS | AEROBIC OXIDATIVE AMINATION | VISIBLE-LIGHT PHOTOREDOX | O-BENZOYL-HYDROXYLAMINES | NITRENE TRANSFER-REACTIONS | BENZYLIC METHYLENE GROUPS | CARBON-HYDROGEN BONDS | CHEMISTRY, MULTIDISCIPLINARY | N BOND-FORMATION
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 1900, Volume 137, Issue 13, pp. 4534 - 4542
Mechanistic investigations on the Cp*Rh­(III)-catalyzed direct C–H amination reaction led us to reveal the new utility of 1,4,2-dioxazol-5-one and its... 
SULFONYL AZIDES | AROMATIC KETONES | COUPLING REACTIONS | NATURAL-PRODUCTS | INTERMOLECULAR AMIDATION | ATOM-TRANSFER | N BOND FORMATION | SYNTHETIC ROUTE | CARBON-NITROGEN BONDS | FORMING REACTIONS | CHEMISTRY, MULTIDISCIPLINARY | Chemical reactions | Ruthenium | Chemical properties | Research
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 08/2017, Volume 23, Issue 46, pp. 11147 - 11152
Described herein is a mechanism‐based approach to develop a versatile C−H amidation protocol under IrIII catalysis. Reaction kinetics of a key C−N coupling... 
iridium | density functional calculations | amination | C−N coupling | transition states | Chemical reaction, Rate of | Analysis | Catalysis | Coupling (molecular) | Decarboxylation | Computer applications | Reaction kinetics | Catalytic activity | Kinetics | Nitrogen | Substrates
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 02/2014, Volume 136, Issue 6, pp. 2492 - 2502
Direct C–H amination of arenes offers a straightforward route to aniline compounds without necessitating aryl (pseudo)halides as the starting materials. The... 
INTRAMOLECULAR AMIDATION | CONVENIENT SYNTHESIS | INDUCED REDUCTIVE ELIMINATIONS | INTERMOLECULAR AMINATION | ANILINE DERIVATIVES | HETEROCYCLE SYNTHESIS | IMIDOMETAL COMPLEXES | N BOND FORMATION | ARYL AZIDES | ORGANIC AZIDES | CHEMISTRY, MULTIDISCIPLINARY | Azides | Usage | Research | Rhodium | Dynamics | Analysis
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 10/2016, Volume 138, Issue 42, pp. 14020 - 14029
The mechanism of the Ir­(III)- and Rh­(III)-mediated C–N coupling reaction, which is the key step for catalytic C–H amidation, was investigated in an... 
ROOM-TEMPERATURE | SULFONYL AZIDES | NITROGEN-SOURCE | SANDWICH IRIDIUM COMPLEX | OXYGEN-ATOM TRANSFER | NITRENE TRANSFER-REACTIONS | CARBON-HYDROGEN BONDS | DISSOCIATIVE MECHANISM | CHEMISTRY, MULTIDISCIPLINARY | C-H AMINATION | N-HETEROCYCLES | Azoles (Class of compounds) | Stoichiometry | Usage | Amides | Chemical reactions | Research | Chemical properties
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 01/2014, Volume 136, Issue 3, pp. 1125 - 1131
We report herein a new strategy of the Ru-catalyzed intramolecular olefin hydrocarbamoylation for the regiodivergent synthesis of five- and six-membered... 
HOMOGENEOUS HYDROGENATION | ALKYNE HYDROACYLATION | N-SUBSTITUTED FORMAMIDES | ENANTIOSELECTIVE SYNTHESIS | ATOM ECONOMY | CARBON-MONOXIDE | IODIDE PROMOTERS | ARYL HALIDES | INTERMOLECULAR HYDROACYLATION | RUTHENIUM COMPLEXES | CHEMISTRY, MULTIDISCIPLINARY | Oxidation-reduction reaction | Usage | Ruthenium | Analysis
Journal Article
Nature Chemistry, ISSN 1755-4330, 02/2018, Volume 10, Issue 2, pp. 218 - 224
Direct arylation of C-H bonds is in principle a powerful way of preparing value-added molecules that contain carbon-aryl fragments. Unfortunately, currently... 
MILD | ACTIVATION | CROSS-COUPLING REACTION | MECHANISM | TRANSMETALATION | COMPLEXES | ARYL SILANES | SALTS | ARYLSILANES | CHEMISTRY, MULTIDISCIPLINARY | PHOTOREDOX CATALYSIS | Coupling (molecular) | Cross coupling | Aromatic compounds | Chemical bonds | Chemical reactions | Density functional theory | Oxidation | Catalysis | Iridium | Substrates | Intermediates
Journal Article
Science, ISSN 0036-8075, 03/2018, Volume 359, Issue 6379, pp. 1016 - 1021
Intramolecular insertion of metal nitrenes into carbon-hydrogen bonds to form gamma-lactam rings has traditionally been hindered bycompeting isocyanate... 
OXIDATION | ALKENES | AMIDO TRANSFER | AMINES | BOND AMINATION | MULTIDISCIPLINARY SCIENCES | PORPHYRINS | COMPLEXES | RUTHENIUM | ARYL AZIDES | AMINATION REACTIONS | Catalysts | Migration | Insertion | Amino acids | Amides | Carboxylic acids | Nitrogen | Hydrogen bonding | Hydrogen bonds | Chemical bonds | Density functional theory | Iridium | Catalysis | Carbonyls | Organic compounds
Journal Article
Organic Process Research and Development, ISSN 1083-6160, 08/2015, Volume 19, Issue 8, pp. 1024 - 1029
Journal Article
Chemical Reviews, ISSN 0009-2665, 07/2017, Volume 117, Issue 13, p. 9247
Catalytic transformation of ubiquitous C-H bonds into valuable C-N bonds offers an efficient synthetic approach to construct N-functionalized molecules. Over... 
Molecules | Hydrogen bonds | Catalysts | Amination | Metals | Hydrocarbons | Chemical bonds | Selectivity | Catalysis | Carbon | Scaffolds | Direct conversion
Journal Article
Chemistry - A European Journal, ISSN 0947-6539, 08/2017, Volume 23, Issue 46, pp. 11147 - 11152
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 10/2018, Volume 57, Issue 41, pp. 13565 - 13569
Two mechanistic pathways, that is, electrocyclization and electrophilic aromatic substitution, are operative in most intramolecular C−H amination reactions... 
iridium | reaction mechanisms | C−H amidation | spirocompounds | rearrangements | DIENONE-PHENOL REARRANGEMENT | CATALYZED SYNTHESIS | CHEMISTRY, MULTIDISCIPLINARY | N-ACYLNITRENIUM IONS | INDOLES | FUNCTIONALIZATION | BOND ACTIVATION | ARYL AZIDES | C-H AMINATION | C-H amidation | Substitution reactions | Analysis | Catalysis | Iridium | Amination | Computer applications | Organic compounds
Journal Article
CHEMISTRY-A EUROPEAN JOURNAL, ISSN 0947-6539, 08/2017, Volume 23, Issue 46, pp. 11147 - 11152
Described herein is a mechanism-based approach to develop a versatile C-H amidation protocol under Ir-III catalysis. Reaction kinetics of a key C-N coupling... 
ACTIVATION | FUNCTIONAL MOLECULES | BOND-FORMING REACTIONS | INTERMOLECULAR AMIDATION | CARBON-HYDROGEN BONDS | CHEMISTRY, MULTIDISCIPLINARY | C(SP)H BONDS | iridium | density functional calculations | transition states | AMIDO TRANSFER | C-N coupling | NITROGEN-SOURCE | AMINO-ACIDS | amination
Journal Article
Organic Process Research & Development, ISSN 1083-6160, 08/2015, Volume 19, Issue 8, pp. 1024 - 1029
The practical aspects of Cp*Rh­(III)-catalyzed direct C–H amidation with 1,4,2-dioxazol-5-ones were investigated on the operational safety, use of green... 
MILD | FUNCTIONALIZATION | AMINATION | ACTIVATION | METAL-FREE CONDITIONS | HYDROXAMIC ACIDS | NITROGEN-SOURCE | CHEMISTRY, ORGANIC | N BOND FORMATION | ACYL AZIDES | CHEMISTRY, APPLIED | PHOTOLYSIS
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 09/2019, Volume 141, Issue 38, pp. 15356 - 15366
Engineering site-selectivity is highly desirable especially in C-H functionalization reactions. We report a new catalyst platform that is highly selective for... 
Journal Article
Sensors (Switzerland), ISSN 1424-8220, 03/2014, Volume 14, Issue 3, pp. 5333 - 5353
Calibration between color camera and 3D Light Detection And Ranging (LIDAR) equipment is an essential process for data fusion. The goal of this paper is to... 
Sensor fusion | Calibration matrix | 3D point clouds | Camera calibration | Calibration board | 3D LIDAR | ELECTROCHEMISTRY | CHEMISTRY, ANALYTICAL | INSTRUMENTS & INSTRUMENTATION | calibration matrix | camera calibration | calibration board | sensor fusion | EXTRINSIC CALIBRATION | Boards | Color | Lidar | Cameras | Sensors | Calibration | Light detection and ranging | Three dimensional
Journal Article
Science of the Total Environment, ISSN 0048-9697, 06/2018, Volume 626, pp. 1236 - 1242
Journal Article
Nano Convergence, ISSN 2196-5404, 12/2019, Volume 6, Issue 1, pp. 1 - 17
There have been tremendous efforts to develop new synthetic methods for creating novel nanoparticles (NPs) with enhanced and desired properties. Among the many... 
Heterostructure | Materials Science | Chemical transformation | Shape control | Nanotechnology and Microengineering | Phase control | Nanocrystal synthesis | Nanoscale Science and Technology | Nanotechnology | Composition control | Chalcogenides | Nanoparticles | Ion exchanging | Anion exchanging | Cation exchanging | Perovskites | Chemical synthesis
Journal Article
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