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Angewandte Chemie (International ed.), ISSN 1433-7851, 2018, Volume 57, Issue 46, pp. 15276 - 15281
A doubly base‐stabilised diborane based on a benzylphosphine linker was prepared by a salt elimination reaction between 2‐LiC6H4CH2PCy2⋅Et2O and B2Br4. This... 
low-valent compounds | chelates | cycloaddition | boron | DFT calculations | REACTIVITY | GENERATION | DIALUMENE-BENZENE ADDUCT | BOND | CHEMISTRY, MULTIDISCIPLINARY | EQUIVALENT | Thermodynamics | Chelates | Isomerization | Butadiene | Diborane | Dienes | Isomers | Isoprene
Journal Article
ISSN 1359-7345, 5/2016, Volume 52, Issue 43, pp. 75 - 78
Herein, we describe the selective formation of a stable neutral spiroborate radical by one-electron oxidation of the corresponding tetraorganoborate salt... 
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 2016, Volume 55, Issue 1, pp. 436 - 440
An electron‐rich monovalent boron compound is used as a Lewis base to prepare adducts with Group 13 Lewis acids using both its boron and nitrogen sites. The... 
Lewis adducts | alanes | gallanes | boron | dative bonding | COMPLEXES | REACTIVITY | COORDINATION | TERPHENYL | ADDUCT | 1,3,2,5-DIAZADIBORININE | CHEMISTRY, MULTIDISCIPLINARY | REDUCTION | CHEMISTRY | RADICAL-ANION | DERIVATIVES | Nitrogen
Journal Article
Chemical communications (Cambridge, England), ISSN 1359-7345, 2016, Volume 52, Issue 43, pp. 7005 - 7008
Oxidation of a tetraorganoborate salt leads to selective formation of the corresponding zwitterionic radical rather than carbon–carbon bond formation of the... 
ACETYLENES | ANION | TETRAPHENYLBORATE ION | LIGHT | ELECTROOXIDATION | BORA-AROMATIC SYSTEMS | CONVENIENT | IODINE | PHOTOCHEMISTRY | GENERATION | CHEMISTRY, MULTIDISCIPLINARY | Solid state | Spectroscopy | Computation | Formations | Cations | Oxidation | Radicals | Borates
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 01/2016, Volume 55, Issue 1, p. 436
An electron-rich monovalent boron compound is used as a Lewis base to prepare adducts with Group 13 Lewis acids using both its boron and nitrogen sites. The... 
Boron | Lewis acid | Acids | Boron compounds | Lewis base | Adducts
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 12/2016, Volume 138, Issue 49, pp. 16140 - 16147
The combination of Pt0 complexes and indium trihalides leads to compounds that form equilibria in solution between their In–X oxidative addition (OA) products... 
SIGMA-BOND | ARYL HALIDES | ISOMERIZATION | ONLY LEWIS PAIRS | REACTIVITY | BASICITY | DIHYDRIDE-TRANSFER | REDUCTIVE ELIMINATION | CHEMISTRY, MULTIDISCIPLINARY | PLATINUM COMPLEXES | H ACTIVATION | Density functionals | Oxidation-reduction reaction | Usage | Chemical properties | Halides | Isomerization
Journal Article
Chemical communications (Cambridge, England), ISSN 1359-7345, 2016, Volume 52, Issue 27, pp. 4898 - 4901
Two surprising new outcomes of the reaction of Lewis bases with dihalodiboranes(4) are presented. Two surprising new outcomes of the reaction of Lewis bases... 
NUCLEOPHILIC BORON | ORGANIC-SYNTHESIS | ACTIVATION | BORATION | ASYMMETRIC INDUCTION | OPTICAL-PROPERTIES | REACTIVITY | 3-COORDINATE ORGANOBORON COMPOUNDS | DIBORON COMPOUNDS | CHEMISTRY, MULTIDISCIPLINARY | ALPHA,BETA-UNSATURATED CONJUGATED COMPOUNDS | Organic chemistry | Electronic properties | Diborane | Boron | Lewis base | Adducts
Journal Article
Angewandte Chemie, ISSN 1521-3757, 2018, Volume 130, Issue 46, pp. 15498 - 15503
Ein doppelt basenstabilisiertes Diboran, mit Benzylphosphan, wurde mittels einer Salzeliminierung zwischen 2‐LiC6H4CH2PCy2⋅Et2O und B2Br4 dargestellt. Diese... 
Cycloaddition | DFT-Rechnungen | Bor | Niedervalente Verbindungen | Chelat-Gruppen
Journal Article
Arkivoc, ISSN 1551-7012, 11/2012, Volume 2012, Issue 7, pp. 294 - 313
Microwave irradiation of a thiophenol or alkyl thiol (1 equiv.) and an aryl halide (1 equiv.) in 2-propanol at 120 degrees C for three hours in the presence of... 
Sulfides | Copper | Microwaves | Ullmann condensation | microwaves | SYSTEM | HEATING ELEMENTS | NUCLEOPHILIC-SUBSTITUTION | ARYLATION | CHEMISTRY, ORGANIC | THIOLS | ARYL HALIDES | copper | INHIBITORS | EFFICIENT | DERIVATIVES | sulfides
Journal Article
Angewandte Chemie, ISSN 0044-8249, 01/2016, Volume 128, Issue 1, p. 447
Die Verwendung einer elektronenreichen, monovalenten Borspezies erlaubt die Bildung von Addukten mit Gruppe-13-Lewis-Säuren, wobei sowohl Bor als auch... 
Journal Article
Angewandte Chemie, ISSN 0044-8249, 01/2016, Volume 128, Issue 1, pp. 447 - 451
Die Verwendung einer elektronenreichen, monovalenten Borspezies erlaubt die Bildung von Addukten mit Gruppe‐13‐Lewis‐Säuren, wobei sowohl Bor als auch... 
Lewis‐Addukte | Gallane | Alane | Dative Bindungen | Bor
Journal Article
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