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chemistry, inorganic & nuclear (29) 29
reactivity (25) 25
ligands (22) 22
chemistry, multidisciplinary (20) 20
boron (17) 17
carbenes (17) 17
chemistry (14) 14
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Angewandte Chemie (International ed.), ISSN 1433-7851, 2014, Volume 53, Issue 28, pp. 7360 - 7363
Utilizing a cyclic (alkyl)(amino)carbene (CAAC) as a ligand, neutral CAAC‐stabilized radicals containing a boryl functionality could be prepared by reduction... 
carbenes | structure elucidation | radicals | reduction | boron | ELECTRON SIGMA-BOND | ANION | BORYL RADICALS | DIBORENES | REACTIVITY | COORDINATION | BORANES | CHEMISTRY, MULTIDISCIPLINARY | REDUCTIONS | ALKYL AMINO CARBENES | GENERATION | Reduction | Boron | Mathematical analysis | X-rays | Inert | Derivatives | Density | Radicals | Adducts
Journal Article
Chemistry : a European journal, ISSN 0947-6539, 2015, Volume 21, Issue 32, pp. 11603 - 11609
The effect of ylide substitution at the α position to the carbene carbon (Cc) atom on the stability and σ‐donating ability of a number of cyclic carbenes has... 
electron donation | carbenes | ylides | boron | rhodium | OLEFIN METATHESIS CATALYSTS | STABLE CARBENES | N-HETEROCYCLIC CARBENES | CHEMISTRY, MULTIDISCIPLINARY | SILYLENES | P-4 | GENERATION | BEARING | LIGAND PROPERTIES | METAL-COMPLEXES | Energy gap | Orbitals | Stability | Rhodium | Mathematical analysis | Exploration | Carbenes | Carbon
Journal Article
ISSN 1359-7345, 5/2018, Volume 54, Issue 39, pp. 4975 - 4978
...: an insight from theory† Bitupon Borthakur, Sandeep Das and Ashwini K. Phukan Department of Chemical Sciences, Tezpur University, Napam – 784 028, Assam, India. E-mail... 
Journal Article
Advanced Synthesis and Catalysis, ISSN 1615-4150, 12/2018, Volume 360, Issue 23, pp. 4543 - 4561
Journal Article
ISSN 1477-9226, 10/2015, Volume 44, Issue 42, pp. 18656 - 18664
... and Ashwini K. Phukan* Theoretical calculations were carried out to understand the eff ect of annulation on the electronic and ligand properties of boron substituted N... 
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 2017, Volume 56, Issue 27, pp. 7975 - 7979
Although the metathesis of metal–boron double bonds with elemental chalcogenides is an established process, no similar reactivity has been observed with... 
borylenes | density functional calculations | iminoboranes | boron heterocycles | nitrenes | HYDROBORATION | INSERTION | BORON | REACTIVITY | PLATINUM | TERMINAL BORYLENE COMPLEXES | CHEMISTRY, MULTIDISCIPLINARY | CHEMISTRY | BASIS-SETS | ARYLBORYLENE COMPLEX | METAL-COMPLEXES | Nitrogen | Chalcogenides | Boron | Cycloaddition | Metathesis | Decomposition reactions | Chemical bonds
Journal Article
Chemistry : a European journal, ISSN 0947-6539, 2015, Volume 21, Issue 48, pp. 17191 - 17195
A series of agostic σ‐borane/borate complexes have been synthesized and structurally characterized from simple borane adducts. A room‐temperature reaction of... 
ruthenium | σ‐borates | heterocyclic carbene | agostic boranes | molybdenum | σ-borates
Journal Article
Chemistry : a European journal, ISSN 0947-6539, 2018, Volume 24, Issue 26, pp. 6843 - 6847
A family of doubly isonitrile‐stabilized terphenyl borylenes could be obtained by addition of three equivalents of isonitrile to the corresponding Cr and W... 
borylenes | imine ligands | boron | Lewis bases | transition-metal complexes | BORON BONDS | REACTIVITY | CHEMISTRY, MULTIDISCIPLINARY | MULTIPLE COMPLEXATION | ELEMENTS | INFRARED-SPECTRA | REDUCTION | LIGANDS | CARBENES | AMINOBORYLENE | Substitution reactions | Chromium | Carbon monoxide | Tungsten | Phosphines | Carbonyls
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 2014, Volume 53, Issue 12, pp. 3241 - 3244
Synthetic access to electron‐precise boron chains is hampered by the preferential formation of nonclassical structures. The few existing strategies for this... 
oxygen heterocycles | polyboranes | hydroboration | diborenes | sulfur heterocycles | METAL-PROMOTED REACTIONS | COMPLEX | COMPOUND | COORDINATION | BORANE | CHEMISTRY, MULTIDISCIPLINARY | DIBORANE | TRANSITION-METAL | BORON HYDRIDES | CHEMISTRY | Boron | Hydroboration | Synthesis | Coupling agents | Catalysts | Strategy | Reducing agents | Catalysis
Journal Article