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Chemistry : a European journal, ISSN 0947-6539, 2014, Volume 20, Issue 32, pp. 9858 - 9861
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 2015, Volume 54, Issue 50, pp. 15084 - 15088
Hückel π aromaticity is typically a domain of carbon‐rich compounds. Only very few analogues with non‐carbon frameworks are currently known, all involving the... 
density functional therory | boron | multiple bonding | aromaticity
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 2014, Volume 53, Issue 28, pp. 7360 - 7363
Utilizing a cyclic (alkyl)(amino)carbene (CAAC) as a ligand, neutral CAAC‐stabilized radicals containing a boryl functionality could be prepared by reduction... 
carbenes | structure elucidation | radicals | reduction | boron | ELECTRON SIGMA-BOND | ANION | BORYL RADICALS | DIBORENES | REACTIVITY | COORDINATION | BORANES | CHEMISTRY, MULTIDISCIPLINARY | REDUCTIONS | ALKYL AMINO CARBENES | GENERATION | Reduction | Boron | Mathematical analysis | X-rays | Inert | Derivatives | Density | Radicals | Adducts
Journal Article
Chemistry : a European journal, ISSN 0947-6539, 2016, Volume 22, Issue 39, pp. 13927 - 13934
A comprehensive study of the reactivity of Lewis bases with dihalodiboranes(4) is presented. Diaryldihalodiboranes provide rearranged monoadducts when treated... 
boranes | carbenes | Lewis adducts | borenium cations | diboranes | ORGANIC-SYNTHESIS | ROOM-TEMPERATURE | BORON | H BOND | N-HETEROCYCLIC CARBENES | DIBORON COMPOUNDS | CHEMISTRY, MULTIDISCIPLINARY | ALPHA,BETA-UNSATURATED CONJUGATED COMPOUNDS | ASYMMETRIC INDUCTION | ARYL HALIDES | RHODIUM-CATALYZED HYDROBORATION | Reduction | Salts | Activation | Carbenes | Adducts | Lewis base | Halides
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 2013, Volume 52, Issue 40, pp. 10657 - 10660
The chain gang: By treatment of an iron bis(borylene) complex with PCy3 and subsequent stepwise substitution of a CO ligand by PMe3, a catenated 1D OC‐B‐B‐CO... 
iron | carbonyl | catenation | phosphine | borylene | Iron | Iron and steel industry | Chains | Ligands | Carbon monoxide | Analogue
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 02/2017, Volume 23, Issue 9, pp. 2179 - 2184
2,3‐Bis(dimethylamino)‐substituted B2N2C2 heterocycles underwent selective dimethylamino/hydride exchange with either one or two equivalents of BH3⋅SMe2 to... 
hydride ligands | diboranes | heterocycles | isomerization | ring contraction | DIMETHYLAMINOBORON HYDRIDES | B2H4 | HYDROBORATION | REACTIVITY | CHEMISTRY, MULTIDISCIPLINARY | BORYLLITHIUM | DIBORANE COMPOUND | CHEMISTRY | ENERGIES | DERIVATIVES | BORYLATION | Exchange | Equivalence | Heat exchange | Isomerization | Irradiation | Hydrides | Contracts | Phosphines
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 2011, Volume 50, Issue 46, pp. 10847 - 10850
CC coupling of 1,7‐dibromoperylene bisimide with sterically hindered 2,6‐di‐tert‐butylphenol by a carbon nucleophilic substitution reaction in the absence of... 
dyes/pigments | chromophores | halochromism | near‐infrared absorption | CC coupling | C-C coupling | near-infrared absorption | SOLAR-CELLS | BOND-LENGTH ALTERNATION | SUBSTITUENTS | CHEMISTRY, MULTIDISCIPLINARY | EMERGING APPLICATIONS | BODIPY DYES | SRN1 REACTIONS | FLUORESCENT | ELECTRON-TRANSFER | CHEMISTRY | PHTHALOCYANINES
Journal Article
Chemistry : a European journal, ISSN 0947-6539, 2013, Volume 19, Issue 27, pp. 8797 - 8805
We herein report detailed investigations into the interaction of Lewis acidic fluoroboranes, for example BF2Pf (Pf=perfluorophenyl) and BF2ArF... 
Lewis acids | density functional calculations | fluoroboranes | transition metals | SIGMA-BOND | ACTIVATION | BORON-TRIFLUORIDE | TRANSITION-METAL-COMPLEXES | BU-T | METALLABORATRANE | OXIDATIVE ADDITION | BORANE | CHEMISTRY, MULTIDISCIPLINARY | BORYL COMPLEXES | PAIRS | Platinum | Lewis acid | Ethene | Boranes | Mathematical models | Lewis base | Adducts
Journal Article
Chemistry : a European journal, ISSN 0947-6539, 2019, Volume 25, Issue 72, pp. 16544 - 16549
Abstract The reactivity of a diruthenium tetrahydride complex towards three selected dihydroboranes was investigated. The use of [DurBH2] (Dur=2,3,5,6-Me4C6H)... 
ruthenium | boron | B−H activation | dehydrocoupling | transition metal | Bonding strength | Chains | Boron | Covalent bonds | Communications | Communication
Journal Article
Journal Article
Chemistry : a European journal, ISSN 0947-6539, 2013, Volume 19, Issue 40, pp. 13396 - 13401
Chemical single‐electron reduction of 1‐mesityl‐2,3,4,5‐tetraphenylborole (3) gave a stable radical anion [CoCp*2][3] as shown in earlier investigations.... 
zwitterions | radical ions | fulvene complexes | boron | boroles | ACTIVATION | MOLECULAR-STRUCTURE | REACTIVITY | CHEMISTRY, MULTIDISCIPLINARY | RAY CRYSTAL-STRUCTURE | PENTAARYLBOROLES | METAL FULVENE COMPLEXES | REDUCTION CHEMISTRY | C-F | 1-CHLORO-2,3,4,5-TETRAPHENYLBOROLE | COBALT | Surface active agents | Cobalt | Analysis | Olefins | Reduction | Anions | Heat treatment | Mathematical analysis | Oxidation | Derivatives | Radicals | Borates
Journal Article