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1. Full Text Iron‐Catalyzed Trifluoromethylation of Enamide
by Rey‐Rodriguez, Romain and Retailleau, Pascal and Bonnet, Pascal and Gillaizeau, Isabelle
Chemistry – A European Journal, ISSN 0947-6539, 02/2015, Volume 21, Issue 9, pp. 3572 - 3575
Herein the first example of the iron(II)‐catalyzed trifluoromethylation of enamide using mild and simple reaction conditions is reported. The method is... 
iron‐catalyzed reactions | trifluoromethylation | CH functionalization | synthetic methods | Togni’s reagent | Synthetic methods | Togni's reagent | Trifluoromethylation | C-H functionalization | Iron-catalyzed reactions | iron-catalyzed reactions | REAGENTS | ARYLATION | ARENES | BOND FORMATION | CF3SIME3 | CHEMISTRY, MULTIDISCIPLINARY | UNACTIVATED ALKENES | MEDICINAL CHEMISTRY | CH functionalization | PD(II)-CATALYZED ORTHO-TRIFLUOROMETHYLATION | HYDROTRIFLUOROMETHYLATION | FLUORINE | Amides - chemistry | Hydrocarbons, Fluorinated - chemistry | Molecular Structure | Catalysis | Methylation | Iron - chemistry | Strategy | Transformations | Tolerances | Fluorination | Functional groups | Chemical Sciences
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2. Full Text Elemental Sulfur as Reaction Medium for the Synthesis of Fused Nitrogen Heterocycles by Oxidative Coupling between Cycloalkanones and Nitrogen Nucleophiles
by Nguyen, Thanh Binh and Retailleau, Pascal
Advanced Synthesis & Catalysis, ISSN 1615-4150, 11/2017, Volume 359, Issue 21, pp. 3843 - 3847
Molten elemental sulfur was found to be an excellent reaction medium for oxidative coupling between bis‐aza nucleophiles and cycloalkanones to the fused diaza... 
Elemental sulfur | oxidative coupling | azaheterocycle | cycloalkanone | bis-aza-nucleophile | REAGENT | COMPLEX | DESIGN | QUINOXALINE DERIVATIVES | ANALOGS | CHEMISTRY, ORGANIC | 2-NITROCHALCONES | SINOMENINE | KETONES | CONDENSATION | CHEMISTRY, APPLIED | ACCESS | Sulfur | Sulfur compounds | Cyclohexanone | Oxidation | Coupling | Nucleophiles | Chemical synthesis | Functional groups | Organic chemistry | Chemical Sciences
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3. Full Text Sulfur‐Catalyzed Stereo and Regioselective Synthesis of Heteropropellanes via Oxidative Condensation of Cyclohexanones with 2‐Aminophenols
by Nguyen, Thanh Binh and Retailleau, Pascal
Advanced Synthesis & Catalysis, ISSN 1615-4150, 08/2019, Volume 361, Issue 15, pp. 3588 - 3592
Sulfur was found to be an excellent catalyst for the oxidative coupling of cyclohexanones with o‐aminophenols using DMSO as oxidant. A wide range of... 
sulfur catalysis | sulfur | DMSO | oxidative condensation | heteropropellane | ELEMENTAL SULFUR | CHEMISTRY, ORGANIC | PROPELLANES | CHEMISTRY, APPLIED | ACCESS | Sulfur | Sulfur compounds | Chemical synthesis | Functional groups | Organic chemistry | Chemical Sciences
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4. Full Text Sulfur‐Promoted Aminative Aromatization of 1,2,3,4‐Tetrahydrophenazines with Amines: Flexible Access to 1‐Aminophenazines
by Nguyen, Thanh Binh and Retailleau, Pascal
Advanced Synthesis & Catalysis, ISSN 1615-4150, 06/2018, Volume 360, Issue 12, pp. 2389 - 2393
Elemental sulfur was found to be an excellent reagent for promoting the aminative aromatization of 1,2,3,4‐tetrahydrophenazines with amines to provide a wide... 
C−H functionalization | aromatization | C−H amination | phenazine | elemental sulfur | C-H amination | PHENAZINES | CHEMISTRY, ORGANIC | CHEMISTRY, APPLIED | C-H functionalization | Sulfur compounds | Amines | Sulfur | Dehydrogenation | Reagents | Organic chemistry | Chemical Sciences
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5. Full Text Sulfur-Promoted Decarboxylative Sulfurative Hexamerization of Phenylacetic Acids: Direct Approach to Hexabenzylidyne Tetrasulfides
by Nguyen, Thanh Binh and Retailleau, Pascal
Organic Letters, ISSN 1523-7060, 2019, Volume 21, Issue 1, pp. 279 - 282
Organic chemistry | Chemical Sciences
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6. Full Text Gold‐Catalyzed Synthesis of Spirofused Indoloquinuclidines
by Glinsky‐Olivier, Nicolas and Retailleau, Pascal and Guinchard, Xavier
European Journal of Organic Chemistry, ISSN 1434-193X, 11/2018, Volume 2018, Issue 42, pp. 5823 - 5829
A novel series of spirofused indoloquinuclidines was obtained by a tandem Pictet–Spengler/AuI‐catalyzed cyclization sequence. By combining N‐propargyl... 
Alkaloids | Homogenous catalysis | Organocatalysis | Asymmetric catalysis | Spiro compounds | BRONSTED ACID CATALYSTS | COMPLEX | HYDROGENATION | PICTET-SPENGLER REACTION | TANDEM DEPROTECTION/CYCLIZATION | REACTIVITY | CHEMISTRY, ORGANIC | HYDROAMINATION | TETRAHYDRO-BETA-CARBOLINES | GOLD(I)-CATALYZED CARBOAMINATIONS | DEAROMATIZATION | Organic chemistry | Chemical Sciences
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7. Full Text An histidine covalent receptor and butenolide complex mediates strigolactone perception
by De Saint Germain, Alexandre and Clavé, Guillaume and Badet-Denisot, Marie-Ange and Pillot, Jean-Paul and Cornu, David and Le Caer, Jean-Pierre and Burger, Marco and Pelissier, Frank and Retailleau, Pascal and Turnbull, Colin and Bonhomme, Sandrine and Chory, Joanne and Rameau, Catherine and Boyer, François-Didier
Nature Chemical Biology, ISSN 1552-4450, 10/2016, Volume 12, Issue 10, pp. 787 - 794
Strigolactone plant hormones control plant architecture and are key players in both symbiotic and parasitic interactions. They contain an ABC tricyclic lactone... 
Peas - enzymology | Heterocyclic Compounds, 3-Ring - metabolism | Histidine - metabolism | Lactones - metabolism | 4-Butyrolactone - metabolism | Plant Growth Regulators - chemistry | Plant Proteins - chemistry | 4-Butyrolactone - chemistry | Ligands | Molecular Structure | Plant Proteins - metabolism | 4-Butyrolactone - analogs & derivatives | Histidine - chemistry | Plant Growth Regulators - metabolism | Peas - metabolism | Plant biology | Signal transduction | Enzymes | Biochemistry | Life Sciences | Vegetal Biology | Biochemistry, Molecular Biology | Chemical Sciences
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8. Full Text Catalytic Enantioselective Intermolecular Benzylic C(sp3)−H Amination
by Nasrallah, Ali and Boquet, Vincent and Hecker, Alexandra and Retailleau, Pascal and Darses, Benjamin and Dauban, Philippe
Angewandte Chemie International Edition, ISSN 1433-7851, 06/2019, Volume 58, Issue 24, pp. 8192 - 8196
A practical general method for asymmetric intermolecular benzylic C(sp3)−H amination has been developed by combining the pentafluorobenzyl sulfamate PfbsNH2... 
C−H functionalization | enantioselective synthesis | nitrene | amination | rhodium | CYTOCHROME-P450 | DIRHODIUM(II) | AMIDATION | NITRENE TRANSFER-REACTIONS | C-H functionalization | CHEMISTRY, MULTIDISCIPLINARY | INSERTIONS | AZIRIDINATIONS | BONDS | C-H AMINATION | Enantiomers | Amines | Rhodium | Amination | Catalysts | Catalysis | Substrates | Organic chemistry | Chemical Sciences
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9. Full Text Sulfur‐Promoted Synthesis of 2‐Aroylquinazolin‐4(3H)‐ones by Oxidative Condensation of Anthranilamide and Acetophenones
by Nguyen, Thanh Binh and Hou, Jing‐ya and Retailleau, Pascal
Advanced Synthesis & Catalysis, ISSN 1615-4150, 07/2019, Volume 361, Issue 14, pp. 3337 - 3341
A sulfur‐promoted three‐component reaction of isatoic anhydride, primary aliphatic or aromatic amines, and acetophenones leading to densely substituted... 
anthranilamide | sulfur | acetophenone, DMSO | oxidative condensation | DMSO | ONE-POT SYNTHESIS | O-AMINOBENZAMIDES | CHEMISTRY, ORGANIC | QUINAZOLINE DERIVATIVES | ELEMENTAL SULFUR | KETONES | acetophenone | AMINES | REDOX CONDENSATION | INHIBITORS | CHEMISTRY, APPLIED | ACCESS | CYCLIZATION | Sulfur | Sulfur compounds | Aromatic amines | Substitutes | Anhydrides | Amines | Oxidation | Cascade chemical reactions | Condensation | Aliphatic compounds | Organic chemistry | Chemical Sciences
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10. Full Text Cooperative Activating Effect of Tertiary Amine/DMSO on Elemental Sulfur: Direct Access to Thioaurones from 2′-Nitrochalcones under Mild Conditions
by Nguyen, Thanh Binh and Retailleau, Pascal
Organic Letters, ISSN 1523-7060, 01/2018, Volume 20, Issue 1, pp. 186 - 189
A new mode for the activation of elemental sulfur is reported. In the presence of both DMSO and a tertiary aliphatic amine (triethylamine or... 
CHEMISTRY, ORGANIC | THIOFLAVONES | REDOX CONDENSATION | 2-NITROCHALCONES | HEMITHIOINDIGO PHOTOSWITCHES | DERIVATIVES | Organic chemistry | Chemical Sciences
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11. Full Text DIPEA-Promoted Reaction of 2‑Nitrochalcones with Elemental Sulfur: An Unusual Approach to 2‑Benzoylbenzothiophenes
by Nguyen, Thanh Binh and Retailleau, Pascal
Organic Letters, ISSN 1523-7060, 09/2017, Volume 19, Issue 18, pp. 4858 - 4860
DIPEA was found to be an excellent sulfur activator to promote the reaction of 2-nitrochalcones with elemental sulfur. A wide range of 2-benzoylbenzothiophenes... 
CATALYZED REDOX CONDENSATION | NITROARENES | AMINES | ARYLATION | CHEMISTRY, ORGANIC | O-HALONITROBENZENES | FLUORODENITRATION | SUBSTITUTED NITROBENZENES | EFFICIENT | ARYLBORONIC ACIDS | ACCESS | Organic chemistry | Chemical Sciences
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12. Full Text Redox-Neutral Access to Sultams from 2‑Nitrochalcones and Sulfur with Complete Atom Economy
by Nguyen, Thanh Binh and Retailleau, Pascal
Organic Letters, ISSN 1523-7060, 07/2017, Volume 19, Issue 14, pp. 3879 - 3882
A catalyst-free, redox-neutral, and completely atom-economical synthesis of sultams by simply heating 2-nitrochalcones with elemental sulfur in 3-picoline or... 
ELEMENTAL SULFUR | ORGANIC-SYNTHESIS | ROOM-TEMPERATURE | SULFONYL AZIDES | CONDENSATION REACTION | AMIDE SYNTHESIS | 3-COMPONENT REACTION | CHEMISTRY, ORGANIC | O-HALONITROBENZENES | BOND FORMATION | ALIPHATIC-AMINES | Organic chemistry | Chemical Sciences
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13. Full Text Elemental Sulfur/DMSO‐Promoted Multicomponent One‐pot Synthesis of Malonic Acid Derivatives from Maleic Anhydride and Amines
by Nguyen, Le Anh and Retailleau, Pascal and Nguyen, Thanh Binh
Advanced Synthesis & Catalysis, ISSN 1615-4150, 06/2019, Volume 361, Issue 12, pp. 2864 - 2869
Malonic acid derivatives could be conveniently prepared with high degree of functional flexibility via redox condensation reactions between anhydride maleic,... 
multicomponent reactions | sulfur | decarboxylation | DMSO | oxidative condensation | ROUTE | 3-COMPONENT REACTION | CHEMISTRY, ORGANIC | DECARBOXYLATIVE THIOAMIDATION | REDOX CONDENSATION | BENZOXAZOLES | ALIPHATIC-AMINES | CHEMISTRY, APPLIED | FACILE | EFFICIENT | ACCESS | Sulfur compounds | Amines | Maleic anhydride | Anhydrides | Derivatives | Sulfur | Ring opening | Organic chemistry | Chemical Sciences
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14. Full Text Tuning the Structure of Phosphahelicenes for Targeted Applications in Enantioselective Phosphine Organocatalysis
by Aillard, Paul and Gicquel, Maxime and Yavari, Keihann and Retailleau, Pascal and Voituriez, Arnaud and Marinetti, Angela
European Journal of Organic Chemistry, ISSN 1434-193X, 11/2018, Volume 2018, Issue 42, pp. 5853 - 5860
The use of phosphahelicenes as nucleophilic organocatalysts for [3+2] cyclization reactions between allenoates and 2‐benzylidenemalononitriles has been... 
Allenes | Cyclization | Enantioselectivity | Organocatalysis | Helicenes | Phosphines | GOLD-CATALYSIS | ONE-POT SYNTHESIS | CHEMISTRY, ORGANIC | FUNCTIONALIZED CYCLOPENTENES | 2+2+2 CYCLOADDITION | MOLECULES | PROMOTED 3+2 ANNULATIONS | CYCLIZATION STRATEGY | DELTA-ACETOXY ALLENOATES | CATALYTIC ASYMMETRIC-SYNTHESIS | DERIVATIVES | Enantiomers | Organic chemistry | Chemical Sciences
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15. Full Text Highly Diastereo‐ and Enantioselective Synthesis of Cyclohepta[b]indoles by Chiral‐Phosphoric‐Acid‐Catalyzed (4+3) Cycloaddition
by Gelis, Coralie and Levitre, Guillaume and Merad, Jérémy and Retailleau, Pascal and Neuville, Luc and Masson, Géraldine
Angewandte Chemie International Edition, ISSN 1433-7851, 09/2018, Volume 57, Issue 37, pp. 12121 - 12125
A highly enantio‐ and diastereoselective formal (4+3) cycloaddition of 1,3‐diene‐1‐carbamates with 3‐indolylmethanols in the presence of a chiral phosphoric... 
(4+3) cycloaddition | heterocycles | hydrogen bonds | chiral phosphoric acids | cyclohepta[b]indoles | 3+2 CYCLIZATION | CASCADE REACTIONS | 3-INDOLYLMETHANOLS | DEFICIENT ALLYLIC ALCOHOLS | ONE-POT | NATURAL-PRODUCTS | CHEMISTRY, MULTIDISCIPLINARY | INDOLE | DIELS-ALDER REACTION | STEREOSELECTIVE-SYNTHESIS | BRONSTED-ACID | Phosphates | Carbamates | Phosphoric acid | Enantiomers | Hydrogen | Stereoselectivity | Cycloaddition | Carbamates (tradename) | Acids | Catalysis | Indoles | Chemical synthesis | Organic chemistry | Chemical Sciences
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16. Full Text Sulfurative self-condensation of ketones and elemental sulfur: a three-component access to thiophenes catalyzed by aniline acid-base conjugate pairsElectronic supplementary information (ESI) available. CCDC 1571217. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c7gc03437g
by Nguyen, Thanh Binh and Retailleau, Pascal
ISSN 1463-9262, 1/2018, Volume 2, Issue 2, pp. 387 - 39
A sulfurative self-condensation method for constructing thiophenes 2 by a reaction between ketones 1 and elemental sulfur is reported. This reaction, which is... 
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17. Full Text Methyl ketone break-and-rebuild: a strategy for full α-heterofunctionalization of acetophenonesElectronic supplementary information (ESI) available. See DOI: 10.1039/c7gc02558k
by Nguyen, Thanh Binh and Retailleau, Pascal
ISSN 1463-9262, 11/2017, Volume 19, Issue 22, pp. 5371 - 5374
The Willgerodt reaction under iron-catalyzed aerobic conditions was found to be an excellent tool for full α-heterofunctionalization of acetophenones with... 
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18. Full Text Elemental Sulfur-Promoted Oxidative Rearranging Coupling between o‑Aminophenols and Ketones: A Synthesis of 2‑Alkyl benzoxazoles under Mild Conditions
by Nguyen, Thanh Binh and Retailleau, Pascal
Organic Letters, ISSN 1523-7060, 07/2017, Volume 19, Issue 14, pp. 3887 - 3890
In the presence of N-methylpiperidine, elemental sulfur was found to act as excellent oxidant in promoting oxidative rearranging coupling between... 
H BOND ACTIVATION | ORGANIC-CHEMISTRY | PALLADIUM | EFFICIENT CATALYST | MEDIATED SYNTHESIS | CHEMISTRY, ORGANIC | REDOX CONDENSATION | BENZIMIDAZOLES | BENZOTHIAZOLES | HIGHLY EFFICIENT | CATALYZED DIRECT ALKYLATION | Organic chemistry | Chemical Sciences
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