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Organometallics, ISSN 0276-7333, 12/2019, Volume 38, Issue 24, pp. 4578 - 4584
Journal Article
CHEMICAL COMMUNICATIONS, ISSN 1359-7345, 07/2019, Volume 55, Issue 56, pp. 8087 - 8089
The first magnesium-based dithiolene, 2, was prepared by reaction of the lithium dithiolene radical, 1, with 2-mesitylmagnesium bromide. Reaction of 2 with... 
CHEMISTRY | CRYSTAL | LIGANDS | CHEMISTRY, MULTIDISCIPLINARY | SPECTROSCOPIC PROPERTIES
Journal Article
Dalton Transactions, ISSN 1477-9226, 2019, Volume 48, Issue 11, pp. 3543 - 3546
The redox chemistry of the first stable anionic dithiolene radical 1(center dot) was investigated by both reactivity and cyclic voltammetry studies. While... 
RAY-ABSORPTION SPECTROSCOPY | LIGANDS | NICKEL DITHIOLENES | DENSITY-FUNCTIONAL THEORY | COVALENCY | CATION | METAL-COMPLEXES | ELECTRONIC-STRUCTURE | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Dalton Transactions, ISSN 1477-9226, 03/2016, Volume 45, Issue 14, pp. 5941 - 5944
Reaction of the anionic N-heterocyclic dicarbene (NHDC), [:C{[N(2,6-Pr super(i) sub(2)C sub(6)H sub(3))] sub(2)CHCLi}] sub(n) (1), with SiCl sub(4) gives the... 
Hexanes | Computation | Halides | Cations | Carbenes | Carbon | Bonding
Journal Article
Dalton Transactions, ISSN 1477-9226, 05/2017, Volume 46, Issue 17, pp. 5508 - 5512
While the 1 : 1 reaction of C4-trichlorosilyl-functionalized N-heterocyclic carbene (NHC) (2) with [( eta 5-C5H4Li)2Fe]3[TMEDA]2 (3) gives... 
Single crystals | Complexation | Synthesis (chemistry) | Synthesis | Ligands | NMR spectroscopy | Carbenes | X ray diffraction
Journal Article
ISSN 1359-7345, 7/2019, Volume 55, Issue 56, pp. 887 - 889
The first magnesium-based dithiolene, 2 , was prepared by reaction of the lithium dithiolene radical, 1&z.rad; , with 2-mesitylmagnesium bromide. Reaction of 2... 
Journal Article
Inorganic Chemistry, ISSN 0020-1669, 11/2014, Volume 53, Issue 22, pp. 11815 - 11832
This Award Article targets the evolving, yet surprisingly fruitful, chemistry of N-heterocyclic carbenes with low-oxidation-state main-group elements.... 
B=B DOUBLE-BOND | ELECTRON-SPIN-RESONANCE | DISILYNE RSISIR R | MOLECULAR-STRUCTURE | GALLIUM TRIPLE BOND | LOW-VALENT SILICON | BORYL-SUBSTITUTED DISILENES | DENSITY-FUNCTIONAL THEORY | BERYLLIUM BOROHYDRIDE | IN-THE-BOX | CHEMISTRY, INORGANIC & NUCLEAR | Awards | Organometallic compounds | Allotropes | Historic | Ligands | Evolution | Beryllium borohydrides | Carbenes
Journal Article
Angewandte Chemie - International Edition, ISSN 1433-7851, 08/2015, Volume 54, Issue 35, pp. 10267 - 10270
Journal Article
Chemical Communications : Chem Comm, ISSN 1359-7345, 01/2019, Volume 55, Issue 56, pp. 8087 - 8089
The first magnesium-based dithiolene, 2, was prepared by reaction of the lithium dithiolene radical, 1·, with 2-mesitylmagnesium bromide. Reaction of 2 with... 
Anions | Format | Toluene | Lithium | Magnesium | Lewis base | Carbenes | Crystallography | Structural analysis
Journal Article
Inorganic Chemistry, ISSN 0020-1669, 12/2011, Volume 50, Issue 24, pp. 12326 - 12337
This article highlights recent efforts of this laboratory in the stabilization of highly reactive, low-oxidation-state, main-group molecules using bulky... 
B=B DOUBLE-BOND | N-HETEROCYCLIC CARBENE | CRYSTALLINE CARBENE | STABLE SILYLENE | BORON | DIVALENT CARBON | COMPLEXES | SILICON | CHEMISTRY | GROUP ELEMENTS | CHEMISTRY, INORGANIC & NUCLEAR | Chemical bonds | Chemical properties | Carbenes | Analysis | Organometallic compounds
Journal Article
ISSN 1477-9226, 3/2019, Volume 48, Issue 11, pp. 3543 - 3546
The redox chemistry of the first stable anionic dithiolene radical 1&z.rad; was investigated by both reactivity and cyclic voltammetry studies. While... 
Journal Article
Dalton Transactions, ISSN 1477-9226, 01/2019, Volume 48, Issue 11, pp. 3543 - 3546
The redox chemistry of the first stable anionic dithiolene radical 1· was investigated by both reactivity and cyclic voltammetry studies. While one-electron... 
Organic chemistry | Aquatic plants | Oxidation | Dimers | Crystallography | Structural analysis
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 03/2009, Volume 131, Issue 9, pp. 3168 - 3169
Potassium graphite reduction of L:Ga(Mes)Cl2 [L: = :C{(i-Pr)NC(Me)}2, Mes = 2,4,6-Me3C6H2] (1) in hexane yields the organogallium dimer... 
Journal Article
ISSN 1477-9226, 5/2017, Volume 46, Issue 17, pp. 558 - 5512
While the 1 : 1 reaction of C4-trichlorosilyl-functionalized N-heterocyclic carbene (NHC) ( 2 ) with [(η 5 -C 5 H 4 Li) 2 Fe] 3 [TMEDA] 2 ( 3 ) gives... 
Journal Article
Ecology Letters, ISSN 1461-023X, 02/2012, Volume 15, Issue 2, pp. 164 - 175
Journal Article
Dalton Transactions, ISSN 1477-9226, 12/2011, Volume 41, Issue 2, pp. 337 - 345
While transition metals are well known for assuming the formal oxidation state of zero in various compounds main group elements have rarely engaged in this... 
ACTIVATION | DISILYNE RSISIR R | P-4 | CHEMISTRY | PI-SYSTEMS | BORYL-SUBSTITUTED DISILENES | SILICON TRIPLE BOND | GROUP ELEMENTS | RAY CRYSTAL-STRUCTURE | MOLECULES | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Dalton transactions (Cambridge, England : 2003), ISSN 1477-9226, 01/2012, Volume 41, Issue 2, pp. 337 - 345
While transition metals are well known for assuming the formal oxidation state of zero in various compounds main group elements have rarely engaged in this... 
Journal Article
Chemical Communications: Chem Comm, ISSN 1359-7345, 04/2016, Volume 52, Issue 33, pp. 5746 - 5748
Reaction of carbene-stabilized diphosphorus, L:P-P:L (5) (L: = :C{N(2,6-Pr super(i) sub(2)C sub(6)H sub(3))CH} sub(2)) with pyridine hydrochloride yields... 
Complexation | Pyridines | Synthesis | Computation | Analogue | Protonation | Cations | Carbenes
Journal Article
Chemical Communications, ISSN 1359-7345, 2009, Issue 35, pp. 5201 - 5213
Significant progress in the chemistry of main group compounds (group 13, 14, and 15) containing homonuclear multiple bonds has been made over the past three... 
ELECTRON PI-BOND | B=B DOUBLE-BOND | SI=SI DOUBLE-BOND | MOLECULAR-STRUCTURE | STABLE COMPOUND | GALLIUM TRIPLE BOND | TERPHENYL LIGANDS | DENSITY-FUNCTIONAL THEORY | GROUP ELEMENTS | CHEMISTRY, MULTIDISCIPLINARY | RAY CRYSTAL-STRUCTURE
Journal Article
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