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Angewandte Chemie International Edition, ISSN 1433-7851, 06/2017, Volume 56, Issue 25, pp. 7218 - 7222
A general and user‐friendly synthesis of β‐lactams is reported that makes use of Pd0‐catalyzed carbamoylation of C(sp3)−H bonds, and operates under... 
β-lactams | palladium | C−C coupling | C−H activation | carbonylation | C-C coupling | NITROGEN-HETEROCYCLES | ARYLATION | INDOLINES | CHEMISTRY, MULTIDISCIPLINARY | beta-lactams | C-H activation | INTRAMOLECULAR AMINATION | BONDS | GAMMA-LACTAMS | ALIPHATIC-AMINES | STEREOSELECTIVE-SYNTHESIS | Amino acids | Palladium | Carbon monoxide | Enantiomers | Chemical synthesis | Feasibility studies
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 10/2019, Volume 58, Issue 41, pp. 14625 - 14628
The intramolecular coupling of two C(sp3)−H bonds to forge a C(sp3)−C(sp3) bond is enabled by 1,4‐Pd shift from a trisubstituted aryl bromide. Contrary to most... 
palladium | C−H activation | domino reactions | heterocycles | Couplings | Carbonyl groups | Carbonyl compounds | Acidic oxides | Hydrogen bonds | Aniline | Aromatic compounds | Dehydrogenation | Palladium | Bonding | Carbonyls
Journal Article
Organic Letters, ISSN 1523-7060, 02/2018, Volume 20, Issue 3, pp. 772 - 775
An expedient synthesis of lycorine alkaloids is reported using a palladium(0)-catalyzed double C–X/C–H arylation as the key step. The selectivity of this... 
Journal Article
Organic Letters, ISSN 1523-7060, 03/2019, Volume 21, Issue 5, pp. 1434 - 1437
1,n-Metal shift is an elegant alternative approach enabling the functionalization of remote C H bonds from simple precursors. In this work, we report a novel... 
MIGRATION | PALLADIUM | 1,4-MIGRATION | RHODIUM | GAMMA-LACTAMS | CHEMISTRY, ORGANIC | ARYL | C(SP)-H | BOND | C-H ACTIVATION | OLEFIN
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 06/2017, Volume 56, Issue 25, p. 7218
A general and user-friendly synthesis of [beta]-lactams is reported that makes use of Pd.sub.0-catalyzed carbamoylation of C(sp.sub.3)-H bonds, and operates... 
Palladium | Carbon monoxide | Enantiomers
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 09/2018, Volume 57, Issue 37, pp. 12131 - 12135
The Pd0‐catalyzed C(sp3)‐H arylation of 2‐bromo‐N‐methylanilides leads to unstable benzazetidine intermediates that rearrange to benzoxazines through 4π... 
palladium | C−H activation | electrocyclic reactions | domino reactions | heterocycles | Nitrogen | Chemical reactions | Cascade chemical reactions | Benzoxazines | Intermediates
Journal Article
ORGANIC LETTERS, ISSN 1523-7060, 02/2018, Volume 20, Issue 3, pp. 772 - 775
An expedient synthesis of lycorine alkaloids is reported using a palladium(0)-catalyzed double C-X/C-H arylation as the key step. The selectivity of this... 
ACTIVATION | PALLADIUM-CATALYZED SYNTHESIS | ALPHA-ARYLATION | CHEMISTRY, ORGANIC | POLYCYCLIC COMPOUNDS | C(SP)-H | AMARYLLIDACEAE | C-H FUNCTIONALIZATION | DERIVATIVES | CYCLIZATION | ALKALOIDS
Journal Article
Angewandte Chemie, ISSN 0044-8249, 10/2019, Volume 131, Issue 41, pp. 14767 - 14770
The intramolecular coupling of two C(sp3)−H bonds to forge a C(sp3)−C(sp3) bond is enabled by 1,4‐Pd shift from a trisubstituted aryl bromide. Contrary to most... 
Heterocyclen | Palladium | Domino-Reaktionen | C-H-Aktivierung | Couplings | Carbonyl groups | Carbonyl compounds | Acidic oxides | Hydrogen bonds | Aniline | Dehydrogenation | Aromatic compounds | Bonding | Carbonyls
Journal Article
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, ISSN 1433-7851, 09/2018, Volume 57, Issue 37, pp. 12131 - 12135
The Pd-0-catalyzed C(sp(3))-H arylation of 2-bromo-N-methylanilides leads to unstable benzazetidine intermediates that rearrange to benzoxazines through 4 pi... 
NITROGEN-HETEROCYCLES | 2-SUBSTITUTED QUINAZOLINES | ONE-POT SYNTHESIS | ARYLATION | ALKYNES | CHEMISTRY, MULTIDISCIPLINARY | C-H activation | domino reactions | heterocycles | palladium | electrocyclic reactions | DERIVATIVES | ARYL CHLORIDES | BETA-LACTAMS | or physical chemistry | Chemical Physics | Catalysis | Physics | Chemical Sciences | Theoretical and
Journal Article
Angewandte Chemie, ISSN 0044-8249, 06/2017, Volume 129, Issue 25, p. 7324
A general and user-friendly synthesis of [beta]-lactams is reported that makes use of Pd.sub.0-catalyzed carbamoylation of C(sp.sub.3)-H bonds, and operates... 
Palladium | Carbon monoxide | Enantiomers
Journal Article
Angewandte Chemie, ISSN 0044-8249, 06/2017, Volume 129, Issue 25, pp. 7324 - 7328
A general and user‐friendly synthesis of β‐lactams is reported that makes use of Pd0‐catalyzed carbamoylation of C(sp3)−H bonds, and operates under... 
β-Lactame | Palladium | Carbonylierungen | C-C-Kupplungen | C-H-Aktivierung
Journal Article
Angewandte Chemie, ISSN 0044-8249, 09/2018, Volume 130, Issue 37, pp. 12307 - 12311
The Pd0‐catalyzed C(sp3)‐H arylation of 2‐bromo‐N‐methylanilides leads to unstable benzazetidine intermediates that rearrange to benzoxazines through 4π... 
Dominoreaktionen | Heterocyclen | Palladium | Elektrocyclische Reaktionen | C-H-Aktivierung | Nitrogen | Chemical reactions | Cascade chemical reactions | Benzoxazines | Intermediates
Journal Article
Angewandte Chemie, ISSN 0044-8249, 06/2017, Volume 129, Issue 25, pp. 7324 - 7328
A general and user‐friendly synthesis of β‐lactams is reported that makes use of Pd0‐catalyzed carbamoylation of C(sp3)−H bonds, and operates under... 
Feasibility studies | Amino acids | Palladium | Carbon monoxide | Enantiomers | Chemical synthesis
Journal Article
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